GaN Layer for EUV Mirror Substrate Protection

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

EUV mirrors in microlithographic projection exposure apparatuses face radiation-induced structural alterations and impaired reflection properties due to the lack of suitable light-transmissive refractive materials, leading to geometric changes and aging effects in metallic and amorphous mirror substrates.

Innovation Solution

Incorporating a layer of gallium nitride (GaN), aluminum nitride (AlN), or aluminum gallium nitride (AlGaN) between the mirror substrate and the reflection layer stack, which acts as both a polishing and protection layer, utilizing nitrogen ion-assisted vapor deposition to maintain amorphous structure and high radiation resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If additional polishing layers (e.g., amorphous silicon) are applied to improve polishing precision, then manufacturing precision is improved, but the layer construction becomes more complex and susceptible to radiation-induced structural alterations

Engineering Contradiction:
Improvepolishing precisionVSAvoidlayer construction complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention extracts and eliminates the need for additional polishing layers by endowing the protection layer with polishing capabilities. The protection layer is configured with specific physical properties (amorphous structure, controlled thickness, appropriate material composition) that enable it to serve dual functions: protecting the mirror substrate from radiation and providing a polishable surface, thereby removing the need for separate polishing layers.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The protection layer is designed to perform multiple functions simultaneously: it protects the mirror substrate from EUV radiation, provides a surface suitable for polishing to achieve required optical precision, and maintains structural stability under radiation loading. This multi-functionality eliminates the need for separate polishing layers and simplifies the overall layer construction.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Reliability

If protection layers are added to protect mirror substrate from radiation, then reliability is improved, but manufacturing complexity increases

Engineering Contradiction:
Improveradiation resistanceVSAvoidlayer construction complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention merges the protection function and polishing function into a single integrated layer. The protection layer is designed with specific characteristics (amorphous structure, controlled thickness, appropriate material composition) that enable it to simultaneously provide radiation protection and serve as a polishing surface, thereby combining multiple functions into one layer and reducing overall structural complexity.

Inventive Principle:
Principle #5Merging (Combining)

3Manufacturing precision

If multiple layers are used to achieve precise polishing, then manufacturing precision is improved, but the number of layers increases and structural stability under radiation decreases

Engineering Contradiction:
Improvepolishing precisionVSAvoidlayer construction stability
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The invention extracts and eliminates the need for additional polishing layers by endowing the protection layer with polishing capabilities. The protection layer is configured with specific physical properties (amorphous structure, controlled thickness, appropriate material composition) that enable it to serve dual functions: protecting the mirror substrate from radiation and providing a polishable surface, thereby removing the need for separate polishing layers.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The protection layer is designed to perform multiple functions simultaneously: it protects the mirror substrate from EUV radiation, provides a surface suitable for polishing to achieve required optical precision, and maintains structural stability under radiation loading. This multi-functionality eliminates the need for separate polishing layers and simplifies the overall layer construction.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The gallium nitride layer effectively prevents radiation-induced structural changes, maintains reflection properties, and reduces thermal expansion differences, allowing for precise polishing and protection of the mirror substrate, potentially eliminating the need for additional polishing layers.

Implementation Method 1

the use of protection layers (for short: SPL="Substrate Protection Layer") has proved to be expedient, which can be produced from a material that absorbs the EUV light to a comparatively great extent

Methodology Applied
Scientific EffectAbsorption (EM radiation): Absorption (EM radiation)

Implementation Method 2

mirrors are used as optical components for the imaging process. Such EUV mirrors have a mirror substrate and a reflection layer stack—constructed from a multiplicity of layer packets—for reflecting the electromagnetic radiation impinging on the optical effective surface

Methodology Applied
Scientific EffectReflection: Reflection

Implementation Method 3

utilizing nitrogen ion-assisted vapor deposition to maintain amorphous structure and high radiation resistance

Methodology Applied
Scientific EffectVapor deposition: Physical Vapour Deposition

Data Source

PatentUS10310382B2Mirror, in particular for a microlithographic projection exposure apparatus
Publication Date: 2019.06.04 CARL ZEISS SMT GMBH
  • US10310382B2 patent drawing
  • US10310382B2 patent drawing
  • US10310382B2 patent drawing

AI summary

A mirror (10, 20, 30, 40), more particularly for a microlithographic projection exposure apparatus, has an optical effective surface (10a, 20a, 30a, 40a), a mirror substrate (11, 21, 31, 41) and a reflection layer stack (14, 24, 34, 44) for reflecting electromagnetic radiation impinging on the optical effective surface (10a, 20a, 30a, 40a), wherein a layer (13, 23, 33, 43) composed of a group III nitride is arranged between the mirror substrate (11, 21, 31, 41) and the reflection layer stack (14, 24, 34, 44), wherein the group III nitride is selected from the group containing gallium nitride (GaN), aluminum nitride (AlN) and aluminum gallium nitride (AlGaN).