GaN Nanowire Gas Sensor with UV Light Activation

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Solution Overview

Problem

Conventional gas sensors lack selectivity and require high operating temperatures, making them unsuitable for real-world applications, especially in detecting explosives and volatile organic compounds, due to their non-selective nature and complex operation requirements.

Innovation Solution

A single package gas sensor design incorporating a semiconductor nanostructure, such as GaN nanowires, functionalized with metal or metal-oxide nanoparticles like TiO2, which enables light-assisted sensing of target analytes with enhanced selectivity and sensitivity at room temperature.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional metal-oxide based thin film sensors are used, then they can detect harmful gases, but they lack selectivity and require high working temperatures

Engineering Contradiction:
ImproveselectivityVSAvoidworking temperature
Core Design Contradiction:
Measurement precisionVSTemperature

Solution Approach 1:

The patent uses composite materials by combining semiconductor nanowires with metal or metal-oxide nanoparticles to form hybrid sensors. This composite structure enables both high selectivity through the nanoparticle-functionalized surface and low-temperature operation through the semiconductor nanowire core, resolving the contradiction between selectivity and operating temperature requirements

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies local quality by functionalizing specific regions of the nanowire surface with metal or metal-oxide nanoparticles. This localized functionalization creates selective sensing sites with specific chemical affinities for target analytes, while the bulk nanowire material provides the conductive pathway, enabling selectivity without requiring high temperatures across the entire sensor

Inventive Principle:
Principle #3Local quality

2Measurement precision

If conventional metal-oxide based thin film sensors are used, then they can detect harmful gases, but they require high working temperatures which increases power consumption

Engineering Contradiction:
Improvedetection capabilityVSAvoidpower consumption
Core Design Contradiction:
Measurement precisionVSUse of energy by moving object

Solution Approach 1:

The hybrid composite structure of semiconductor nanowires with metal/metal-oxide nanoparticles enables detection capability at room temperature or low temperatures, eliminating the need for high-power heating elements required by conventional metal-oxide sensors, thus reducing power consumption while maintaining detection capability

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent replaces the thermal activation mechanism (heating) with optical activation (light irradiation) to enable sensing. The semiconductor nanowires exhibit photoconductive properties where light generates charge carriers that enhance the sensing response, substituting the energy-intensive thermal system with a low-power optical system

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Reliability

If conventional metal-oxide based thin film sensors are used, then they can detect harmful gases, but they lack selectivity for different species

Engineering Contradiction:
Improvereal-life applicabilityVSAvoidselectivity
Core Design Contradiction:
ReliabilityVSMeasurement precision

Solution Approach 1:

The hybrid composite of semiconductor nanowires with selectively functional metal/metal-oxide nanoparticles provides both reliability for real-life applications and high selectivity. The nanoparticle surface chemistry can be tuned to specifically interact with target analytes while the nanowire provides stable electrical transduction, ensuring reliable and selective detection in complex real-world environments

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

By functionalizing the nanowire surface with specific metal or metal-oxide nanoparticles that have selective affinity for target analytes, the sensor achieves species-specific detection. Different nanoparticle materials can be selected or combined to target different analytes, providing reliable selectivity for real-life applications involving complex gas mixtures

Inventive Principle:
Principle #3Local quality

4Measurement precision

If nanowire structures are used, then sensitivity is enhanced due to high surface to volume ratio, but device complexity increases

Engineering Contradiction:
ImprovesensitivityVSAvoidstructure complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The nanowire structures self-assemble or self-align during fabrication processes, and their high surface-to-volume ratio inherently provides the desired sensitivity without requiring additional complex structures. The nanoscale dimensions automatically maximize surface area exposure to analytes, providing sensitivity enhancement as an intrinsic property rather than requiring additional complex components

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides highly selective and sensitive detection of aromatic compounds and explosives at low temperatures, reducing power consumption and system complexity, while maintaining reliability and usability in explosive or corrosive environments.

Implementation Method 1

enables light-assisted sensing of a target analyte

Methodology Applied
Scientific EffectPhotoconductivity: Photoconductivity

Implementation Method 2

at least one ultraviolet (UV) light emitting diode (LED) disposed on the substrate

Methodology Applied
Scientific EffectPhotoelectric Effect: Photoelectric Effect

Implementation Method 3

at least one of metal or metal-oxide nanoparticles functionalizing the outer surface of the nanostructure

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS10983102B2Single package optically-activated gas sensors
Publication Date: 2021.04.20 N5 SENSORS INC
  • US10983102B2 patent drawing
  • US10983102B2 patent drawing
  • US10983102B2 patent drawing

AI summary

Systems and methods provide for manufacturing and assembling a single package gas sensor. The method includes: disposing a substrate in a housing; disposing at least one gas sensor die on the substrate; disposing at least one ultraviolet (UV) light emitting diode (LED) on the substrate; and attaching a lid to the housing, wherein the lid includes at least one gas ingress point.