GaN Substrate Meltback Prevention via Insulation Barrier

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Solution Overview

Problem

The challenge lies in manufacturing large area gallium nitride (GaN) substrates due to high nitrogen vapor pressure requirements, difficulty in producing GaN single crystals, and issues with silicon diffusion causing meltback and tensile stress when growing GaN on silicon substrates, which limits device production and increases costs.

Innovation Solution

A method involving the formation of a buffer layer on a silicon substrate using MOCVD, followed by an insulation layer pattern on the rim to prevent meltback, and growing the GaN layer using HVPE, allowing for the detachment of the GaN layer from the silicon substrate, thereby preventing silicon diffusion and stress.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Area of stationary object

If a GaN layer is grown on a large area silicon substrate, then the substrate area and productivity are improved, but silicon diffusion causes meltback and tensile stress leading to cracks

Engineering Contradiction:
Improvesubstrate areaVSAvoidcrack-free quality
Core Design Contradiction:
Area of stationary objectVSReliability

Solution Approach 1:

An insulation layer pattern is introduced as an intermediary between the silicon substrate and the GaN layer. This insulation layer prevents direct contact between silicon and GaN, thereby blocking silicon diffusion that would otherwise cause meltback and tensile stress in the GaN layer, eliminating the root cause of cracking while enabling large area substrate use

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The insulation layer pattern is formed on the silicon substrate before the GaN layer is grown. This preliminary protective measure is in place during the entire GaN growth process, preventing silicon diffusion and subsequent meltback from occurring in the first place, rather than attempting to fix cracks after they form

Inventive Principle:
Principle #10Preliminary action

2Ease of manufacture

If silicon and GaN directly contact each other, then the manufacturing process is simplified, but meltback occurs due to silicon diffusion

Engineering Contradiction:
Improveprocess simplicityVSAvoidmeltback
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

The insulation layer pattern serves as a mediator that physically separates silicon and GaN, preventing direct contact. This additional layer blocks the harmful silicon diffusion process that causes meltback, while the overall process remains relatively simple through standard semiconductor fabrication techniques

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If a sapphire substrate is used to grow GaN layer, then the GaN layer quality is improved, but the substrate cost and availability for large area are worsened

Engineering Contradiction:
ImproveGaN layer qualityVSAvoidsubstrate cost and availability
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The invention replaces expensive sapphire substrates with cheaper silicon substrates. The silicon substrate serves as a cost-effective heterogeneous substrate that can be easily obtained in large areas, sacrificing the ideal crystal match of sapphire but gaining significant cost and availability advantages through the use of standard silicon wafers

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The insulation layer pattern acts as an intermediary that enables the use of silicon substrates by preventing the harmful interactions between silicon and GaN. This mediator allows the inexpensive silicon substrate to perform a role traditionally filled only by expensive sapphire substrates

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the production of high-quality, large area GaN substrates by preventing meltback and stress, allowing for the efficient growth of GaN layers on silicon substrates without cracking, thus overcoming the limitations of existing technologies.

Implementation Method 1

forming a buffer layer on a silicon substrate

Methodology Applied
Scientific EffectChemical Vapour Deposition: Chemical Vapour Deposition

Implementation Method 2

growing a GaN layer on the buffer layer

Methodology Applied
Scientific EffectEpitaxy: Epitaxy

Implementation Method 3

growing a GaN layer on the buffer layer by using a hydride vapor phase epitaxy (HVPE) method

Methodology Applied
Scientific EffectVapor Phase Deposition: Physical Vapour Deposition

Implementation Method 4

forming an insulation layer pattern on a rim of a top surface of the buffer layer... preventing silicon diffusion

Methodology Applied
Scientific EffectDiffusion Barrier: Diffusion Barrier

Data Source

PatentUS8969178B2Method of manufacturing large area gallium nitride substrate
Publication Date: 2015.03.03 SAMSUNG ELECTRONICS CO LTD
  • US8969178B2 patent drawing
  • US8969178B2 patent drawing
  • US8969178B2 patent drawing

AI summary

A method of manufacturing a large area gallium nitride (GaN) substrate includes forming a buffer layer on a silicon substrate, forming an insulation layer pattern on a rim of a top surface of the buffer layer, growing a GaN layer on the buffer layer, and removing the insulation layer pattern and a portion of the GaN layer and the silicon substrate.