Gas Barrier Layer Composition for Retort Packaging
Find Innovative SolutionsGenerate Solutions
Solution Overview
Problem
Conventional gas barrier layered products for packaging materials face challenges in maintaining high oxygen barrier properties under severe conditions, such as high temperature and humidity, and flexibility after retorting, especially when exposed to hot water.
Innovation Solution
A layered product with a gas barrier layer formed from a composition including a hydrolyzed condensate of a compound with a hydrolyzable characteristic group and a polymer with neutralized functional groups, using a divalent or higher valent ion of a metal element with higher electronegativity than calcium, and incorporating silicon atoms bonded to hydrolyzable groups and amino organic groups to enhance flexibility and hot-water resistance.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Illumination intensity
If a vinyl alcohol polymer layer is used as a gas barrier layer, then transparency and ease of disposal are improved, but gas barrier properties deteriorate under high humidity conditions
Solution Approach 1:
The patent uses a composite structure combining a vinyl alcohol polymer layer with a metal compound layer (such as aluminum oxide or silicon oxide). This composite approach allows the vinyl alcohol polymer to provide transparency while the metal compound layer maintains gas barrier properties under high humidity conditions by forming a stable, non-hygroscopic barrier that prevents oxygen permeation even when the polymer absorbs moisture.
2Reliability
If metal foil or metal vapor deposition layer is used as gas barrier layer, then gas barrier properties are improved, but visibility of contents and ease of disposal are worsened
Solution Approach 1:
The patent applies a thin metal compound layer (such as aluminum oxide or silicon oxide) specifically as the gas barrier layer, rather than using thick metal foil. This thin layer provides sufficient oxygen barrier properties while maintaining transparency, allowing consumers to see the contents through the packaging. The metal compound is deposited in a controlled manner to achieve the optimal thickness for both barrier performance and visibility.
3Reliability
If metal compound layer is used as gas barrier layer, then gas barrier properties are improved, but flexibility and resistance to impact are worsened due to cracks under deformation
Solution Approach 1:
The patent changes the physical and chemical parameters of the metal compound layer by using amorphous metal compounds (such as aluminum oxide or silicon oxide) deposited in a controlled manner. This creates a more flexible, crack-resistant layer compared to crystalline structures. The amorphous structure can better accommodate deformation without forming cracks, maintaining both flexibility and gas barrier properties under impact and bending conditions.
4Ease of manufacture
If conventional gas barrier materials are used for retort foods, then basic packaging function is achieved, but strength against bag-breakage and oxygen barrier properties after sterilization are insufficient
Solution Approach 1:
The patent applies a preliminary heat treatment or cross-linking process to the vinyl alcohol polymer layer before final packaging use. This preliminary action pre-densifies the polymer structure and strengthens the metal compound layer adhesion, so that when the packaging undergoes retort sterilization, the layer maintains its integrity and gas barrier properties without breaking or delaminating during the high-temperature steam sterilization process.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The solution maintains high oxygen barrier properties and flexibility, even under severe conditions and after retorting, with improved hot-water resistance and ease of production.
Implementation Method 1
a gas barrier layer which comprises a composition of: a hydrolyzed condensation of a compound (L) comprising a specific compound A
Implementation Method 2
a gas barrier layer which comprises a composition of: a hydrolyzed condensation of a compound (L) comprising a specific compound A
Implementation Method 3
the -COO- group in the polymer is neutralized by this treatment
Implementation Method 4
a gas barrier layer composed of polyacrylic acid and a crosslinking component
Implementation Method 5
The above-mentioned vinyl alcohol polymer is crystallized and densified by hydrogen bonding between hydroxyl groups in the molecule to exert gas barrier properties
Implementation Method 6
an organic group having amino group does not make much difference in flexibility
Data Source
AI summary
The layered product of the present invention has a base, and a gas barrier layer stacked on the base. The gas barrier layer is formed of a composition that includes a hydrolyzed condensate of a compound (L) containing a hydrolyzable characteristic group, and a neutralized product of a polymer (P) containing at least one functional group selected from the group consisting of carboxyl group and carboxylic acid anhydride group. The compound (L) includes a compound (L1) and a compound (L2). The compound (L1) and the compound (L2) each contains a silicon atom to which the hydrolyzable characteristic group is bonded. The compound (L1) contains an organic group having amino group. The compound (L2) does not contain an organic group having amino group. At least part of the -COO- group in the at least one functional group contained in the polymer (P) is neutralized with a divalent or higher valent ion (E) of a metal element that has a higher electronegativity than calcium.


