Gas Barrier Layer Composition for Retort Packaging

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Solution Overview

Problem

Conventional gas barrier layered products for packaging materials face challenges in maintaining high oxygen barrier properties under severe conditions, such as high temperature and humidity, and flexibility after retorting, especially when exposed to hot water.

Innovation Solution

A layered product with a gas barrier layer formed from a composition including a hydrolyzed condensate of a compound with a hydrolyzable characteristic group and a polymer with neutralized functional groups, using a divalent or higher valent ion of a metal element with higher electronegativity than calcium, and incorporating silicon atoms bonded to hydrolyzable groups and amino organic groups to enhance flexibility and hot-water resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If a vinyl alcohol polymer layer is used as a gas barrier layer, then transparency and ease of disposal are improved, but gas barrier properties deteriorate under high humidity conditions

Engineering Contradiction:
ImprovetransparencyVSAvoidgas barrier properties under high humidity
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent uses a composite structure combining a vinyl alcohol polymer layer with a metal compound layer (such as aluminum oxide or silicon oxide). This composite approach allows the vinyl alcohol polymer to provide transparency while the metal compound layer maintains gas barrier properties under high humidity conditions by forming a stable, non-hygroscopic barrier that prevents oxygen permeation even when the polymer absorbs moisture.

Inventive Principle:
Principle #40Composite materials

2Reliability

If metal foil or metal vapor deposition layer is used as gas barrier layer, then gas barrier properties are improved, but visibility of contents and ease of disposal are worsened

Engineering Contradiction:
Improvegas barrier propertiesVSAvoidvisibility of contents
Core Design Contradiction:
ReliabilityVSIllumination intensity

Solution Approach 1:

The patent applies a thin metal compound layer (such as aluminum oxide or silicon oxide) specifically as the gas barrier layer, rather than using thick metal foil. This thin layer provides sufficient oxygen barrier properties while maintaining transparency, allowing consumers to see the contents through the packaging. The metal compound is deposited in a controlled manner to achieve the optimal thickness for both barrier performance and visibility.

Inventive Principle:
Principle #3Local quality

3Reliability

If metal compound layer is used as gas barrier layer, then gas barrier properties are improved, but flexibility and resistance to impact are worsened due to cracks under deformation

Engineering Contradiction:
Improvegas barrier propertiesVSAvoidflexibility and impact resistance
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent changes the physical and chemical parameters of the metal compound layer by using amorphous metal compounds (such as aluminum oxide or silicon oxide) deposited in a controlled manner. This creates a more flexible, crack-resistant layer compared to crystalline structures. The amorphous structure can better accommodate deformation without forming cracks, maintaining both flexibility and gas barrier properties under impact and bending conditions.

Inventive Principle:
Principle #35Parameter changes

4Ease of manufacture

If conventional gas barrier materials are used for retort foods, then basic packaging function is achieved, but strength against bag-breakage and oxygen barrier properties after sterilization are insufficient

Engineering Contradiction:
Improvebasic packaging functionVSAvoidstrength against bag-breakage and oxygen barrier properties after sterilization
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent applies a preliminary heat treatment or cross-linking process to the vinyl alcohol polymer layer before final packaging use. This preliminary action pre-densifies the polymer structure and strengthens the metal compound layer adhesion, so that when the packaging undergoes retort sterilization, the layer maintains its integrity and gas barrier properties without breaking or delaminating during the high-temperature steam sterilization process.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution maintains high oxygen barrier properties and flexibility, even under severe conditions and after retorting, with improved hot-water resistance and ease of production.

Implementation Method 1

a gas barrier layer which comprises a composition of: a hydrolyzed condensation of a compound (L) comprising a specific compound A

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 2

a gas barrier layer which comprises a composition of: a hydrolyzed condensation of a compound (L) comprising a specific compound A

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 3

the -COO- group in the polymer is neutralized by this treatment

Methodology Applied
Scientific EffectNeutralization reaction:

Implementation Method 4

a gas barrier layer composed of polyacrylic acid and a crosslinking component

Methodology Applied
Scientific EffectCrosslinking:

Implementation Method 5

The above-mentioned vinyl alcohol polymer is crystallized and densified by hydrogen bonding between hydroxyl groups in the molecule to exert gas barrier properties

Methodology Applied
Scientific EffectHydrogen bonding:

Implementation Method 6

an organic group having amino group does not make much difference in flexibility

Methodology Applied
Scientific EffectCoordination bonding:

Data Source

PatentEP2487035B1Laminate, packaging material using same, molded article, and method for producing the laminate
Publication Date: 2019.11.06 KURARAY CO LTD
  • EP2487035B1 patent drawing
  • EP2487035B1 patent drawing
  • EP2487035B1 patent drawing

AI summary

The layered product of the present invention has a base, and a gas barrier layer stacked on the base. The gas barrier layer is formed of a composition that includes a hydrolyzed condensate of a compound (L) containing a hydrolyzable characteristic group, and a neutralized product of a polymer (P) containing at least one functional group selected from the group consisting of carboxyl group and carboxylic acid anhydride group. The compound (L) includes a compound (L1) and a compound (L2). The compound (L1) and the compound (L2) each contains a silicon atom to which the hydrolyzable characteristic group is bonded. The compound (L1) contains an organic group having amino group. The compound (L2) does not contain an organic group having amino group. At least part of the -COO- group in the at least one functional group contained in the polymer (P) is neutralized with a divalent or higher valent ion (E) of a metal element that has a higher electronegativity than calcium.