Continuous Gas Diffusion Electrode Production via Non-Solvent Phase Separation

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Solution Overview

Problem

Current methods for producing gas diffusion electrodes are costly and inefficient, particularly in achieving high-quality, thin electrodes with optimal porosity and catalytic performance, as they rely on batch manufacturing processes.

Innovation Solution

A continuous process using electrically non-conducting reinforcement webs, such as polypropylene or polyphenylene sulfide, with a thickness of less than 149 micrometers, where the web is adapted and treated with non-solvents to achieve porosity and catalytic performance, allowing for robust and thin gas diffusion electrodes with reduced production costs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If batch manufacturing is used to produce gas diffusion electrodes, then production flexibility is maintained, but production efficiency and cost-effectiveness deteriorate

Engineering Contradiction:
Improveproduction efficiencyVSAvoidprocess complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent implements a continuous manufacturing process where the gas diffusion electrode is produced in a single continuous operation rather than batch processing. The web material is continuously formed, coated with catalyst layers, and processed through the entire manufacturing sequence without interruption, significantly improving production efficiency while maintaining process control

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The continuous manufacturing process is divided into distinct functional zones or modules that process different aspects of the electrode production simultaneously. Each module handles a specific task (web formation, coating, drying, etc.) in sequence, allowing the overall process to be efficient while remaining manageable and controllable

Inventive Principle:
Principle #1Segmentation

2Manufacturing precision

If conventional manufacturing methods are used, then production simplicity is maintained, but electrode thickness and quality deteriorate

Engineering Contradiction:
Improveelectrode qualityVSAvoidproduction simplicity
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent precisely controls critical parameters such as web thickness (less than 149 micrometers), coating concentrations, drying temperatures, and porosity levels to achieve optimal electrode quality. By maintaining tight parameter control throughout the continuous process, high-quality thin electrodes are produced consistently

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The manufacturing process applies different properties to different regions of the electrode. The web structure provides mechanical support while remaining porous, the catalyst layers are selectively applied to specific zones, and the porosity distribution is optimized locally to enhance both quality and performance

Inventive Principle:
Principle #3Local quality

3Reliability

If porosity is increased to improve gas diffusion, then catalytic performance may be compromised

Engineering Contradiction:
Improvecatalytic performanceVSAvoidporosity
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The electrode structure is designed with spatially varying properties: the web provides structural support with controlled porosity, while catalyst layers are applied in specific zones where they are most needed. This local differentiation allows high porosity in gas diffusion regions while maintaining catalytic activity in reaction zones

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The electrode is constructed as a composite structure combining a porous web material with catalyst particles and binding agents. This composite approach allows the web to provide porosity for gas diffusion while the catalyst layers provide the necessary catalytic function, with each component optimized for its specific role

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the production of high-quality, thin gas diffusion electrodes with improved porosity and catalytic performance while significantly reducing production costs through a continuous process, maintaining the stability and efficiency of the electrodes.

Implementation Method 1

The resulting coherent structure is heated and the resulting coherent structure to a temperature above the decomposition temperature of the silver carbonate but below the softening point of the polymer to thereby form silver and liberate carbon dioxide gas which diffuses through a structure to render in substantially porous

Methodology Applied
Scientific EffectPhase separation: Phase Change

Implementation Method 2

heating and the resulting coherent structure to a temperature above the decomposition temperature of the silver carbonate but below the softening point of the polymer to thereby form silver and liberate carbon dioxide gas

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Implementation Method 3

liberate carbon dioxide gas which diffuses through a structure to render in substantially porous

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS11424457B2Method for producing a gas diffusion electrode and gas diffusion electrode
Publication Date: 2022.08.23 SIEMENS ENERGY GLOBAL GMBH & CO KG
  • US11424457B2 patent drawing
  • US11424457B2 patent drawing

AI summary

Various embodiments include a method for producing a gas diffusion electrode, the method comprising: providing a raw electrode layer comprising an electrically non-conducting web; adapting a thickness of the raw electrode layer; and applying a non-solvent to the raw electrode layer.