Fuel Cell Gas Diffusion Layer with Segmented Hydrophilic Channels

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Solution Overview

Problem

Conventional gas diffusion layers in fuel cells face challenges with water management, leading to flooding at the cathode and water deficit at the anode, which affects gas transfer and overall power generation performance.

Innovation Solution

A gas diffusion layer with a manufacturing method that forms channel layers with varying hydrophilicity/hydrophobicity within the gas diffusion medium, using a coating mask and vacuum system to enhance adhesion and conductivity, and a heating apparatus for sintering, allowing for improved water management and gas transfer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional gas diffusion layer is used, then the structure is simple and manufacturing is easy, but water management is poor leading to flooding at cathode and water deficit at anode

Engineering Contradiction:
Improvewater managementVSAvoidlayer structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The gas diffusion layer is segmented into multiple functional layers: a hydrophobic first gas diffusion layer and a hydrophilic second gas diffusion layer. This segmentation allows different regions to perform different water management functions, with the hydrophobic layer preventing flooding and the hydrophilic layer ensuring adequate water supply, thereby resolving the water management contradiction without requiring complex external systems.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the gas diffusion layer are assigned different hydrophobicity properties. The first gas diffusion layer is hydrophobic to prevent water accumulation and flooding, while the second gas diffusion layer is hydrophilic to facilitate water transport and prevent water deficit. This local differentiation of properties enables effective water management across different functional zones of the fuel cell.

Inventive Principle:
Principle #3Local quality

2Reliability

If the gas diffusion layer uses uniform hydrophobicity, then manufacturing is simpler, but gas transfer and water management performance deteriorate

Engineering Contradiction:
Improvegas transferVSAvoidlayer uniformity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The gas diffusion layer employs local quality differentiation by incorporating a hydrophobic first layer and a hydrophilic second layer with distinct properties in specific regions. This allows optimized gas transfer in each layer while maintaining manufacturing feasibility through a layered construction approach that can be implemented using standard coating and assembly processes.

Inventive Principle:
Principle #3Local quality

3Reliability

If a multi-layer structure with channel layers is created, then water management and conductivity improve, but manufacturing complexity increases

Engineering Contradiction:
Improvepower generation performanceVSAvoidmanufacturing process
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The manufacturing process is segmented into distinct steps: forming the hydrophobic first gas diffusion layer, creating channel structures within it, and then forming the hydrophilic second gas diffusion layer. This segmentation of the manufacturing process into manageable stages reduces overall complexity while enabling the creation of a multi-functional layered structure with improved power generation performance.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The channel layers are formed within the first gas diffusion layer before the second gas diffusion layer is applied. This preliminary action of creating the channel structure in advance simplifies the overall manufacturing process, as the channels are already in place to guide water and gas flow when the second layer is added, eliminating the need for complex post-assembly modifications.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively addresses flooding and water deficit issues, enhancing power-generating performance and prolonging the service life of fuel cells by improving both in-plane and through-plane conductivity and adhesion of the gas diffusion layer.

Implementation Method 1

the micro porous layer slurry is made to penetrate into the gas diffusion medium under vacuum suction

Methodology Applied
Scientific EffectVacuum suction: Vacuum

Implementation Method 2

the solution in the slurry is removed through heating and evaporation, so as to from a micro porous layer and a plurality of channel layers

Methodology Applied
Scientific EffectHeating and evaporation: Evaporation

Implementation Method 3

a heating apparatus for heating and sintering the micro porous layer slurry while the micro porous layer slurry is coated

Methodology Applied
Scientific EffectSintering: Sintering

Data Source

PatentUS8263207B2Gas diffusion layer, manufacturing apparatus and manufacturing method thereof
Publication Date: 2012.09.11 IND TECH RES INST
  • US8263207B2 patent drawing
  • US8263207B2 patent drawing
  • US8263207B2 patent drawing

AI summary

A gas diffusion layer, a manufacturing apparatus and a manufacturing method thereof are provided. The gas diffusion layer having different hydrophilic/hydrophobic structure and channel therein can be manufactured quickly and easily by using a coating mask. The gas diffusion layer is used in various fuel cells to enhance the ability of water management and to solve the problem of flooding at the cathode, the problem of water deficit at the anode, and the problem of gas transfer. The gas diffusion layer includes a gas diffusion medium having a first property and a micro porous layer having a second property. The micro porous layer is formed on one surface of the gas diffusion medium. The micro porous layer has a plurality of channel layers penetrating the gas diffusion medium. One of the first property and the second property is hydrophilic, and the other is hydrophobic.