Gas Distribution Assembly for Low-Vapor-Pressure Precursor Control

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Solution Overview

Problem

Existing semiconductor manufacturing processes lack control over the flow rate of low-vapor-pressure precursors into processing chambers, leading to variations within and between processes due to uncontrolled delivery methods.

Innovation Solution

A gas distribution assembly with a flow ratio controller and mass flow meters is used to split and measure the flow of carrier gas, allowing precise control of precursor flow rates by adjusting the ratio of carrier gas portions, ensuring consistent delivery of low-vapor-pressure precursors into semiconductor processing chambers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If vapor draw or bubbling methods are used to deliver low-vapor-pressure precursors, then the precursor can be delivered into the chamber, but the flow rate becomes unmetered and uncontrolled

Engineering Contradiction:
Improveease of precursor deliveryVSAvoidprecursor flow rate control
Core Design Contradiction:
Ease of operationVSManufacturing precision

Solution Approach 1:

A carrier gas is introduced as an intermediary substance to transport the low-vapor-pressure precursor from the ampoule into the chamber. The carrier gas dissolves or carries the precursor through the liquid phase, enabling controlled delivery that neither pure vapor draw nor direct liquid injection can achieve alone

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention replaces traditional mechanical flow control methods with gas-phase concentration detection and absorption techniques. By measuring the concentration of precursor in the gas phase and using absorption measurements, the system achieves precise flow rate control without direct mechanical metering of the liquid precursor

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Manufacturing precision

If direct liquid injection is used to meter flow rates, then precise flow control is achieved, but the method is limited to liquid precursors and requires impurity-free liquids

Engineering Contradiction:
Improveflow rate meteringVSAvoidapplicability to different precursor types
Core Design Contradiction:
Manufacturing precisionVSAdaptability or versatility

Solution Approach 1:

The invention changes the physical state parameter of the precursor from liquid to gas phase for measurement and control purposes. By evaporating or volatilizing the precursor and measuring its concentration in the gas phase, the system can control flow rates of precursors that would be difficult or impossible to meter directly as liquids, including those with impurities

Inventive Principle:
Principle #35Parameter changes

3Measurement precision

If gas-phase concentration detection with absorption techniques is used, then flow rate measurement capability is provided, but additional measurements are required and it is not suitable for high volume manufacturing

Engineering Contradiction:
Improveprecursor flow measurementVSAvoidmeasurement system complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The invention merges the carrier gas delivery function with the measurement function into a single integrated system. The carrier gas that transports the precursor also serves as the medium for concentration detection and absorption measurements, eliminating the need for separate measurement systems and reducing overall device complexity

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution enables precise control and measurement of precursor flow rates, enhancing process uniformity and repeatability by quantifying the contribution of the precursor to the total gas flow, thereby improving the consistency of semiconductor manufacturing processes.

Implementation Method 1

measuring a total gas flow after combining the first portion, the precursor gas, and the second portion

Methodology Applied
Scientific EffectMass flow measurement:

Implementation Method 2

splitting the carrier gas into a first portion and a second portion

Methodology Applied
Scientific EffectGas flow splitting:

Data Source

PatentUS20230124304A1Controlled delivery of low-vapor-pressure precursor into a chamber
Publication Date: 2023.04.20 APPLIED MATERIALS INC
  • US20230124304A1 patent drawing
  • US20230124304A1 patent drawing
  • US20230124304A1 patent drawing

AI summary

Embodiments include a gas distribution assembly for a semiconductor processing chamber. In an embodiment, the gas distribution assembly comprises a flow ratio controller (FRC). In an embodiment, a first line from the FRC goes to an ampoule, and a second line from the FRC goes to a main line. In an embodiment, a third line from the ampoule goes to the main line. In an embodiment, a mass flow meter is coupled to the main line.