Gas Engine Lubricant Composition Oxidation Resistance

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Solution Overview

Problem

Lubricants for stationary gas engines face challenges in maintaining oxidation resistance and preventing deposit formation, particularly at high temperatures, despite advancements in base oil classifications from Group I to Group IV.

Innovation Solution

A lubricating composition combining at least 50% mineral base oil with 5% polyol esters, specifically those with 6 -OH groups, enhances oxidation resistance and detergency while minimizing deposit formation at high temperatures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If group II base oils are used to improve oxidation resistance, then oxidation resistance is improved, but high temperature deposits (varnishes) are formed

Engineering Contradiction:
Improveoxidation resistanceVSAvoidhigh temperature deposits
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention changes the chemical composition parameters of the base oil by combining group II base oil with polyol esters (5-30% by weight). This parameter change allows the lubricant to maintain the oxidation resistance of group II base oil while the polyol ester component suppresses deposit formation, resolving the contradiction between oxidation resistance and deposit control.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite lubricant system by combining group II base oil with polyol ester additives. This composite approach leverages the oxidation resistance of group II base oil while incorporating the deposit-control properties of polyol esters, thereby simultaneously achieving both oxidation resistance and reduced deposit formation.

Inventive Principle:
Principle #40Composite materials

2Object-generated harmful factors

If group III or group IV base oils are used to reduce deposits, then deposit formation is reduced, but oxidation resistance deteriorates

Engineering Contradiction:
Improvedeposit formationVSAvoidoxidation resistance
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The invention modifies the base oil composition by adding polyol esters (5-30% by weight) to group II base oil. This parameter change enables the lubricant to achieve the low deposit-forming characteristics of group III/IV oils while maintaining the superior oxidation resistance of group II base oil, thus resolving the contradiction between deposit control and oxidation resistance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention develops a composite lubricant formulation combining group II base oil with polyol ester additives. This composite structure provides the oxidation resistance of group II base oil while the polyol ester component contributes the anti-deposit properties typically associated with higher-grade base oils, thereby simultaneously achieving both properties.

Inventive Principle:
Principle #40Composite materials

3Stability of the object's composition

If mineral base oil is used to maintain stability, then storage stability is maintained, but oxidation resistance is limited

Engineering Contradiction:
Improvestorage stabilityVSAvoidoxidation resistance
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The invention enhances the oxidation resistance of mineral base oil by incorporating polyol esters (5-30% by weight). This compositional parameter change allows the lubricant to maintain the storage stability of mineral base oil while significantly improving its oxidation resistance, particularly against nitroxidation in gas engine environments.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite lubricant system combining mineral base oil with polyol ester additives. This composite formulation preserves the storage stability characteristics of mineral base oil while the polyol ester component provides enhanced oxidation resistance, resolving the contradiction between storage stability and oxidation resistance.

Inventive Principle:
Principle #40Composite materials

Data Source

PatentEP3481927B1Lubricant composition for a gas engine
Publication Date: 2023.12.27 TOTALENERGIES ONETECH
  • EP3481927B1 patent drawing

AI summary

The invention relates to the use of a lubricant composition comprising at least one mineral base oil and at least one ester selected from among the polyol esters, for lubricating a gas engine.