Gas Generator Composition Using Triazine Fuel and Zeolite Absorbent

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Solution Overview

Problem

Gas generators for airbag apparatuses face challenges in maintaining high ignition ability over long periods, especially under severe temperature conditions, due to moisture-induced deterioration of gas generating agents with low combustion temperatures.

Innovation Solution

A gas generating composition comprising a fuel selected from triazine and guanidine compounds, an oxidizing agent combination of basic metal nitrates and carbonates, and an absorbent, such as synthetic zeolite, is used to maintain ignition ability and reduce combustion temperature, with the absorbent capturing moisture to prevent deterioration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Weight of stationary object

If a gas generating agent with low combustion temperature is used, then the size and weight of the gas generator can be reduced, but the ignition ability deteriorates under severe temperature conditions

Engineering Contradiction:
Improveweight of gas generatorVSAvoidignition ability
Core Design Contradiction:
Weight of stationary objectVSReliability

Solution Approach 1:

The patent uses a composite gas generating agent comprising melamine cyanurate (triazine compound) and nitroguanidine (guanidine compound) as fuels, combined with basic metal nitrate and basic metal carbonate as oxidizing agents. This composite formulation achieves low combustion temperature while maintaining reliable ignition ability under severe temperature conditions from -45°C to +85°C.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If the gas generator operates under severe temperature conditions, then adaptability to environmental changes is improved, but the ignition ability deteriorates over time

Engineering Contradiction:
Improveadaptability to temperature conditionsVSAvoidignition ability
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent optimizes the compositional parameters of the gas generating agent, specifically the ratio of melamine cyanurate to nitroguanidine and the combination of basic metal nitrate with basic metal carbonate. These parameter changes enable the agent to maintain consistent ignition ability across a wide temperature range from -45°C to +85°C over extended operational periods.

Inventive Principle:
Principle #35Parameter changes

3Temperature

If basic metal nitrate is used as oxidizing agent, then combustion temperature is reduced, but moisture-induced deterioration increases

Engineering Contradiction:
Improvecombustion temperatureVSAvoidmoisture-induced deterioration
Core Design Contradiction:
TemperatureVSObject-affected harmful factors

Solution Approach 1:

The patent combines basic metal nitrate with basic metal carbonate in a specific formulation. This composite oxidizing agent system reduces combustion temperature while the basic metal carbonate component provides protection against moisture-induced deterioration, maintaining agent stability in humid environments.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition ensures high ignition ability even after long-term exposure to severe conditions, reducing the size and weight of the gas generator while preventing moisture-induced degradation.

Implementation Method 1

an absorbent... capturing moisture to prevent deterioration

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

the gas generating agent thermally decomposes when it is exposed to high temperature under the presence of moisture

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Implementation Method 3

a gas generating agent including (a) fuel... (b) an oxidizing agent... low combustion temperature

Methodology Applied
Scientific EffectCombustion: Combustion

Data Source

PatentEP2910536B1Gas-generating-agent composition and gas generator using same
Publication Date: 2021.04.07 DAICEL CORP
  • EP2910536B1 patent drawingFigure 1~2
  • EP2910536B1 patent drawingFigure 3~4
  • EP2910536B1 patent drawingFigure 5

AI summary

Provided is a gas generating composition that maintains stable ignition performance for a long period. A gas generating composition includes: a gas generating agent including (a) fuel selected from a triazine compound and a guanidine compound, (b) an oxidizing agent including a combination of (b-1) basic metal nitrate and (b-2) basic metal carbonate, and (c) a binder; and (d) an absorbent. The gas generating agent and the absorbent may not be integrally molded or may be integrally molded.