Gas-Injected Wafer Chemistry for Faster Single-Step Cleaning

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Solution Overview

Problem

Existing methods for cleaning semiconductor wafers are inefficient and time-consuming, with single-wafer processing taking around four minutes using the SCROD method.

Innovation Solution

A gas-injected chemistry system that dispenses a gas-enriched chemical mixture, such as ozonated HF, in a single step, reducing processing time to fifty seconds by integrating a gas generator, mixing tank, sample chamber, and controller to control gas concentration and mixture properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If sequential repetitive cleaning steps (ozonated water then diluted HF) are used, then cleaning effectiveness is achieved, but processing time increases to four minutes

Engineering Contradiction:
Improvecleaning effectivenessVSAvoidprocessing time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The patent combines multiple cleaning chemicals (ozonated water and diluted HF) into a single mixed chemical solution that is dispensed onto the wafer in one step, eliminating the need for sequential repetitive cleaning steps while maintaining cleaning effectiveness

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The system pre-mixes the cleaning chemicals in a mixing tank before dispensing, so that the oxidation and etching agents are already combined and ready to act simultaneously on the wafer surface, reducing the total processing time

Inventive Principle:
Principle #10Preliminary action

2Manufacturing precision

If gas concentration in chemical mixture is increased to improve cleaning performance, then cleaning effectiveness improves, but system complexity increases due to need for precise control

Engineering Contradiction:
Improvecleaning performanceVSAvoidsystem complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The system incorporates a gas sensor that continuously monitors the concentration of gas in the chemical mixture and provides feedback to a controller, which automatically adjusts gas flow to maintain the desired concentration, simplifying operation while ensuring precise cleaning performance

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The system dynamically adjusts the gas concentration parameter in the chemical mixture based on process requirements and sensor feedback, allowing optimization of cleaning performance without manual intervention or complex manual control mechanisms

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system significantly reduces processing time from four minutes to fifty seconds while effectively cleaning semiconductor wafers, and can also be used for etching processes.

Implementation Method 1

a gas generator configured to generate a gas

Methodology Applied
Scientific EffectOzone generation: Ozone

Implementation Method 2

a mixing tank configured to contain a gas-enriched chemical mixture

Methodology Applied
Scientific EffectGas dissolution: Absorption (physical)

Implementation Method 3

oxidation (via the ozonated water) and etching (via the diluted HF)

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS20250269335A1Gas Injected Chemistry for Single Wafer Processing
Publication Date: 2025.08.28 SEMICONDUCTOR OZONE SOLUTIONS LLC
  • US20250269335A1 patent drawing
  • US20250269335A1 patent drawing
  • US20250269335A1 patent drawing

AI summary

The present disclosure relates to systems and methods for gas injected chemistry for single wafer processing. An example method includes generating, by a gas generator, a gas. The method also includes mixing, in a mixing tank, a gas-enriched chemical mixture comprising the gas and a chemical mixture. The method also includes dispensing, via a sample chamber, a dispensed volume of the gas-enriched chemical mixture onto the substrate. The method also includes returning a spent volume of the gas-enriched chemical mixture to the mixing tank.