Contaminated Gas Liquefaction Using Expansion and Slurry Separation

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Solution Overview

Problem

Existing methods for liquefying contaminated hydrocarbon-containing gas streams, such as natural gas, are complex and costly, making them unsuitable for small-scale operations and requiring significant equipment and chemicals.

Innovation Solution

A method involving cooling, expansion, separation, and recycling of gas streams to produce a liquefied hydrocarbon product with a simpler design, reducing operational and capital expenditures, and being robust against trace contaminants, which includes steps like cooling in a heat exchanger, expansion in an expander, separation, and recycling of gas streams to achieve liquefaction without grid connection.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional methods are used to liquefy contaminated hydrocarbon-containing gas streams, then the liquefaction process can be achieved, but the process becomes complex and requires expensive equipment

Engineering Contradiction:
Improveliquefaction process qualityVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention extracts and removes contaminants (CO2, H2S, water) from the hydrocarbon-containing gas stream through specific separation units before liquefaction. This extraction approach simplifies the overall process by eliminating the need for complex contaminant management systems while ensuring clean liquefaction of the hydrocarbon component.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The process is segmented into distinct functional units: a heat exchanger for cooling, an expander for pressure reduction and temperature drop, and separators for phase separation. This segmentation allows each unit to perform a specific function efficiently, reducing overall system complexity compared to integrated conventional systems.

Inventive Principle:
Principle #1Segmentation

2Reliability

If conventional methods are used to treat contaminated gas streams, then contaminants can be removed, but a lot of expensive equipment and chemicals are required

Engineering Contradiction:
Improvecontaminant removal effectivenessVSAvoidequipment quantity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The system uses the energy contained in the gas stream itself and the physical properties of the components to achieve contaminant removal. The expansion process naturally causes temperature drop and phase separation, eliminating the need for external cooling systems and complex chemical treatment processes.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The invention utilizes phase transitions of hydrocarbons and contaminants during expansion and cooling. Different components transition to different phases (gas, liquid, solid) at different temperatures and pressures, enabling automatic separation without requiring complex chemical treatment equipment.

Inventive Principle:
Principle #36Phase transitions

3Manufacturing precision

If conventional liquefaction methods are applied, then hydrocarbon gas can be liquefied, but the process is not suitable for small scale operations

Engineering Contradiction:
Improveliquefaction capabilityVSAvoidscale adaptability
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The system is designed with dynamic parameters that can be adjusted for different scale operations. The expander and heat exchanger can be sized and configured to match the specific production requirements, allowing the same basic process design to serve both small-scale and larger operations efficiently.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method results in a cost-effective and flexible process for small-scale operations, producing a liquid hydrocarbon stream with unique composition, and is robust against contaminants, reducing utility and chemical requirements, and allowing for remote operation.

Implementation Method 1

cooling the contaminated hydrocarbon-containing gas stream in a first heat exchanger thereby obtaining a cooled contaminated hydrocarbon-containing stream

Methodology Applied
Scientific EffectHeat transfer: Heat Exchanger

Implementation Method 2

cooling the cooled contaminated hydrocarbon-containing stream in an expander thereby obtaining a partially liquefied stream

Methodology Applied
Scientific EffectAdiabatic cooling: Adiabatic Cooling

Implementation Method 3

separating the partially liquefied stream in a separator thereby obtaining a gaseous stream and a liquid stream

Methodology Applied
Scientific EffectPhase separation: Phase Change

Implementation Method 4

expanding the liquid stream obtained in step (d) thereby obtaining a multiphase stream, the multiphase stream containing at least a vapour phase, a liquid phase and a solid phase

Methodology Applied
Scientific EffectPressure reduction: Depressurisation

Implementation Method 5

separating the multiphase stream in a separator thereby obtaining a gaseous stream and a slurry stream

Methodology Applied
Scientific EffectPhase separation: Phase Change

Implementation Method 6

separating the slurry stream in a solid/liquid separator thereby obtaining a liquid hydrocarbon stream and a concentrated slurry stream

Methodology Applied
Scientific EffectDensity separation: Sedimentation

Implementation Method 7

passing the gaseous stream obtained in step (d) through the first heat exchanger thereby obtaining a heated gaseous stream

Methodology Applied
Scientific EffectHeat transfer: Heat Exchanger

Implementation Method 8

compressing the heated gaseous stream thereby obtaining a compressed gas stream

Methodology Applied
Scientific EffectMechanical compression: Compression

Data Source

PatentUS10151528B2Method of liquefying a contaminated hydrocarbon-containing gas stream
Publication Date: 2018.12.11 SHELL USA INC
  • US10151528B2 patent drawing

AI summary

A method of liquefying a contaminated hydrocarbon-containing gas stream includes cooling the stream in a first heat exchanger and cooling the cooled stream in an expander to obtain a partially liquefied stream. The method further includes separating the partially liquefied stream in a separator to obtain a gaseous stream and a liquid stream. The liquid stream is expanded to obtain a multiphase stream containing at least a vapour phase, a liquid phase and a solid phase. The multiphase stream is separated in a separator to obtain a gaseous stream and a slurry stream. The slurry stream is separated in a solid/liquid separator to obtain a liquid hydrocarbon stream and a concentrated slurry stream. The gaseous stream is passed through the first heat exchanger to obtain a heated gaseous stream. The heated gaseous stream is compressed and combined with the contaminated hydrocarbon-containing gas stream.