Gas Sample Storage Chamber for High Spatial Resolution Sampling

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Solution Overview

Problem

Current gas handling approaches in gas analysis systems face challenges in achieving high horizontal spatial resolution and temporal resolution due to transient and rapidly varying atmospheric plumes, often resulting in sparse data sets and increased uncertainty in isotope ratio measurements, especially when sampling from moving vehicles.

Innovation Solution

A gas sample storage chamber with a long thin tube configuration is used to store samples at a high acquisition flow rate, allowing for later analysis at a significantly different flow rate, enabling enhanced data collection and reducing mixing, along with on-board triggering for mode switching and optional real-time analysis instruments to manage flow rates and improve data quality.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If gas is continuously acquired at high flow rate, then spatial resolution is improved, but temporal resolution and measurement accuracy deteriorate due to insufficient data points in concentration peaks

Engineering Contradiction:
Improvespatial resolutionVSAvoidisotope ratio measurement accuracy
Core Design Contradiction:
Manufacturing precisionVSMeasurement precision

Solution Approach 1:

The system segments the gas sampling process into two distinct phases: acquisition phase (high flow rate for spatial resolution) and analysis phase (low flow rate for measurement accuracy). The sample loop physically separates the continuous gas stream into discrete analyzable segments, allowing each phase to optimize for its specific requirement without compromise.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Gas is pre-acquired and stored in the sample loop at high flow rate before analysis begins. This preliminary action captures the transient plume structure and concentration peaks while the vehicle is moving, preserving spatial information. The stored sample is then analyzed at reduced flow rate to ensure sufficient data points are obtained for accurate isotope ratio measurements.

Inventive Principle:
Principle #10Preliminary action

2Productivity

If gas analysis is performed at high flow rate, then productivity is improved, but measurement accuracy deteriorates due to rapid flow causing mixing and insufficient data points

Engineering Contradiction:
Improveanalysis speedVSAvoidconcentration measurement accuracy
Core Design Contradiction:
ProductivityVSMeasurement precision

Solution Approach 1:

The system dynamically adjusts the flow rate based on the operational phase. During acquisition, high flow rate maximizes productivity and spatial sampling. During analysis, the flow rate is reduced to optimize measurement accuracy. The sample loop acts as a buffer that decouples these dynamic requirements, allowing the system to transition between states without compromise.

Inventive Principle:
Principle #15Dynamics

3Manufacturing precision

If sample gas is stored in a long thin tube, then spatial resolution is preserved, but device complexity increases

Engineering Contradiction:
Improvehorizontal spatial resolutionVSAvoidgas handling system complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The sample loop serves multiple functions: it acts as a storage vessel for transient plume samples, a flow rate converter between acquisition and analysis phases, and a mixing prevention mechanism through its long thin geometry. This multi-functionality reduces the need for separate components and simplifies the overall system architecture despite the added capability.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Data Source

PatentUS9310346B1Methods for rapid gas sampling with high horizontal spatial resolution in a manner suitable for subsequent constituent gas analysis
Publication Date: 2016.04.12 PICARRO INC
  • US9310346B1 patent drawing
  • US9310346B1 patent drawing
  • US9310346B1 patent drawing

AI summary

A gas sample storage chamber is used to continuously acquire a gas sample. After the sample has been acquired, the stored gas in the chamber can be analyzed. This analysis can provide a time history of the gas sample, since mixing and diffusion of the gas sample in the chamber can be made sufficiently negligible. The gas flow rate for analysis differs significantly from the acquisition flow rate.