Gas Sensing Element Adhesion via Siloxane Matrix

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional hydrogen gas detection sheets lack substantial adhesion to measurement targets, leading to decreased workability and inaccurate measurements due to gaps between the detection layer and the target, and the presence of an unnecessary adhesive layer can hinder hydrogen gas detection.

Innovation Solution

A pressure-sensitive adhesive gas detection element with a chemochromic composition including palladium oxide or palladium salts dispersed in a siloxane polymer matrix, which is crosslinked by a peroxide initiator, providing improved adhesion and accurate detection of hydrogen gas without the need for additional adhesives.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If an adhesive layer is added to the hydrogen gas detection sheet to improve adhesion, then the adhesion to measurement targets is improved, but the structure becomes complicated and the adhesive layer hampers hydrogen gas detection

Engineering Contradiction:
ImproveadhesionVSAvoidstructure complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent combines the adhesive layer and hydrogen gas detection layer into a single integrated layer. The siloxane polymer matrix serves dual functions: providing pressure-sensitive adhesive properties for bonding to measurement targets and serving as the medium in which palladium oxide particles detect hydrogen gas through color change. This eliminates the need for separate adhesive and detection layers while maintaining both adhesion and detection capabilities.

Inventive Principle:
Principle #5Merging (Combining)

2Strength

If an adhesive layer is added to the hydrogen gas detection sheet to improve adhesion, then the adhesion to measurement targets is improved, but the adhesion accuracy is reduced due to gaps and interference

Engineering Contradiction:
ImproveadhesionVSAvoiddetection accuracy
Core Design Contradiction:
StrengthVSMeasurement precision

Solution Approach 1:

The patent merges the adhesive and detection functions into one layer, eliminating the interface between separate layers that would create gaps. The integrated structure ensures direct contact between the palladium oxide particles and hydrogen gas while maintaining strong adhesion to the measurement target, thereby improving both adhesion strength and detection accuracy simultaneously.

Inventive Principle:
Principle #5Merging (Combining)

3Strength

If auxiliary tape and adhesive are used to fix the hydrogen gas detection sheet, then the adhesion is improved, but the workability at the site is decreased

Engineering Contradiction:
ImproveadhesionVSAvoidworkability
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The patent extracts the auxiliary adhesive tape from the system by incorporating adhesive functionality directly into the detection sheet itself. The siloxane polymer matrix provides inherent pressure-sensitive adhesive properties, allowing the detection sheet to be applied directly to measurement targets without requiring separate fixing materials, thereby significantly improving workability and ease of application.

Inventive Principle:
Principle #2Taking out (Extraction)

4Quantity of substance

If the concentration of measurement target gas is low, then the detection sensitivity is challenged, but the color change becomes insufficient and hard to determine

Engineering Contradiction:
Improvegas concentrationVSAvoidcolor change visibility
Core Design Contradiction:
Quantity of substanceVSMeasurement precision

Solution Approach 1:

The patent utilizes the color change property of palladium oxide particles when exposed to hydrogen gas. The siloxane polymer matrix provides a suitable medium that allows the color change to be visually detectable. For low concentration detection, the intimate contact between the detection layer and measurement target ensures maximum exposure of palladium oxide particles to trace hydrogen gas, enhancing the visibility of color changes even at low concentrations.

Inventive Principle:
Principle #32Color changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enhances the adhesion of the gas detection layer to measurement targets, reducing the complexity and improving the accuracy of hydrogen gas detection, while allowing for efficient and passive gas level monitoring.

Implementation Method 1

a siloxane polymer matrix of a siloxane crosslinked by free radical transfer reaction

Methodology Applied
Scientific EffectFree radical transfer reaction:

Implementation Method 2

chemochromic composition including a palladium oxide, palladium hydroxide, or palladium salts

Methodology Applied
Scientific EffectChemochromic composition:

Implementation Method 3

which is crosslinked by a peroxide initiator

Methodology Applied
Scientific EffectPeroxide initiator:

Data Source

PatentUS10996174B2Gas sensing element
Publication Date: 2021.05.04 NITTO DENKO CORP
  • US10996174B2 patent drawing
  • US10996174B2 patent drawing
  • US10996174B2 patent drawing

AI summary

A gas sensing element includes a gas detection layer including a pigment, the gas detection layer including a first surface; and a backing material disposed on the first surface of the gas detection layer. When reducing gas causes the gas sensing element to change in color, a color change ΔL* of the gas sensing element is greater than or equal to 5.