Gas Sensor Composite Catalyst for Hydrogen Detection

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Solution Overview

Problem

Current hydrogen sensors face challenges with low sensitivity, high power consumption, and instability, particularly in detecting hydrogen gas concentrations within the explosive range, and lack commercialization due to these limitations.

Innovation Solution

A gas sensor featuring a thermoelectric layer with metal nanowires and a catalyst layer with a composite structure of metal particles bonded to a carbon structure, which generates heat upon reacting with target gases, creating a temperature difference and potential difference for efficient hydrogen detection.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If a semiconductor type sensor is used for hydrogen detection, then the sensor has low power consumption and compact size, but the sensitivity is low due to low reactivity with hydrogen gas

Engineering Contradiction:
Improvepower consumptionVSAvoidsensitivity
Core Design Contradiction:
Use of energy by moving objectVSMeasurement precision

Solution Approach 1:

The patent uses a composite catalyst layer combining metal particles (platinum, palladium, or rhodium) with carbon structures (graphene, carbon nanotubes, or fullerenes). This composite structure enhances hydrogen reactivity and sensor sensitivity while maintaining low power consumption, as the carbon structure provides high surface area and the metal particles catalyze hydrogen oxidation reactions.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent creates localized catalytic regions by depositing metal particles specifically on the carbon structure surface. This local concentration of catalytic activity at the catalyst layer enhances hydrogen detection sensitivity without requiring the entire sensor structure to be reactive, thus maintaining energy efficiency.

Inventive Principle:
Principle #3Local quality

2Measurement precision

If a catalyst layer is added to improve sensitivity, then the detection capability is enhanced, but the device complexity and manufacturing cost increase

Engineering Contradiction:
Improvedetection capabilityVSAvoidstructure complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent employs porous carbon structures (graphene, carbon nanotubes, or fullerenes) as the catalyst support. These porous materials provide extremely high surface area-to-volume ratios, allowing catalytic metal particles to be distributed efficiently. This enhances detection capability while keeping the physical thickness and overall structural complexity of the catalyst layer minimal.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The carbon structure acts as an intermediary between the metal particles and the hydrogen gas. It provides a stable support framework that facilitates hydrogen diffusion and reaction while the metal particles provide catalytic activity. This intermediary role enhances detection capability without requiring direct contact between all components, simplifying the overall structure.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Measurement precision

If metal particles are used as catalyst, then the catalytic activity is high, but the manufacturing cost increases due to expensive materials

Engineering Contradiction:
Improvecatalytic activityVSAvoidmanufacturing cost
Core Design Contradiction:
Measurement precisionVSEase of manufacture

Solution Approach 1:

The patent concentrates expensive metal particles (platinum, palladium, or rhodium) only on the surface of the carbon structure where catalytic activity is needed, rather than using bulk metal. This localized application minimizes the total amount of expensive material required while maintaining high catalytic activity for hydrogen detection.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent creates a composite catalyst layer where inexpensive carbon structures (graphene, carbon nanotubes, or fullerenes) serve as the primary matrix, with small amounts of expensive metal particles dispersed on the surface. This composite approach leverages the high surface area and structural stability of carbon materials to reduce the quantity of expensive metals needed, thereby lowering manufacturing costs while maintaining catalytic performance.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The gas sensor achieves improved thermoelectric efficiency, stability, and sensitivity, enabling fast and accurate hydrogen detection with low power consumption, suitable for wide-range applications including IoT, while maintaining cost-effectiveness.

Implementation Method 1

the catalyst layer may react with target gas, in which heat may be generated in the catalyst layer after the catalyst layer reacts with the target gas

Methodology Applied
Scientific EffectExothermic reaction: Exothermic Reaction

Implementation Method 2

the temperature difference between the first and second areas may cause a potential difference between the first area and the second area

Methodology Applied
Scientific EffectThermoelectric effect: Seebeck Effect

Data Source

PatentUS11573196B2Gas sensor comprising composite structure including graphene and metal particle bonded to each other and method for manufacturing same
Publication Date: 2023.02.07 IND UNIV COOP FOUND HANYANG UNIV ERICA CAMPUS
  • US11573196B2 patent drawing
  • US11573196B2 patent drawing
  • US11573196B2 patent drawing

AI summary

Disclosed is a gas sensor. The gas sensor comprises: a substrate; a thermoelectric layer which is disposed on the substrate and has a metal nanowire; a first electrode and a second electrode disposed to be spaced apart from each other on the thermoelectric layer; and a catalyst layer which is disposed on the first electrode and has a composite structure in which a metal particle is bonded to a carbon structure.