Gas Sensor Electrode Cracking Mitigation via Graded Insulation

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Solution Overview

Problem

The existing gas sensor elements with composite layers suffer from cracking or breaking of the electrode at the boundary between the solid electrolyte body and the insulation member due to step-like level differences, leading to reliability issues.

Innovation Solution

A gas sensor element with a composite ceramic layer featuring a plate-like insulation portion and a plate-like electrolyte portion, where the electrolyte portion is thinner than the insulation portion, and a conductor layer extends continuously over a protruding portion of the insulation surface, mitigating the level difference and reducing the risk of cracking.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the electrode extends continuously on both the solid electrolyte body and the insulation member, then the electrode provides continuous conductivity, but the step-like level difference at the boundary causes cracking or breaking of the electrode

Engineering Contradiction:
Improveelectrode integrityVSAvoidstep-like level difference
Core Design Contradiction:
ReliabilityVSShape

Solution Approach 1:

The patent introduces an intermediate layer between the solid electrolyte body and the insulation member. This intermediate layer has a thickness that gradually transitions from the thickness of the solid electrolyte body to the thickness of the insulation member, effectively adding a dimensional gradient that eliminates the abrupt step-like level difference. This gradual transition in the thickness dimension prevents cracking while maintaining continuous electrode conductivity.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Solution Approach 2:

The patent changes the thickness parameter of the intermediate layer to create a gradual transition zone. By controlling the thickness of the intermediate layer to be between the thicknesses of the solid electrolyte body and the insulation member, the patent transforms the abrupt geometric discontinuity into a continuous gradient, thereby preventing electrode cracking at the boundary.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If the electrolyte portion is made thinner than the insulation portion, then the overall structure is optimized, but the level difference between surfaces creates stress concentration at the boundary

Engineering Contradiction:
Improvesensor response timeVSAvoidboundary strength
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The patent introduces an intermediate layer with graded thickness that transitions from the thinner electrolyte portion to the thicker insulation portion. This creates a dimensional bridge that distributes stress gradually across the transition zone rather than concentrating it at a sharp boundary, thereby maintaining boundary strength while preserving the optimized thin electrolyte structure for fast response.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Solution Approach 2:

The intermediate layer acts as a cushioning layer that absorbs and distributes mechanical stress before it can concentrate at the boundary between the electrolyte and insulation portions. By placing this stress-distributing layer in advance at the interface, the patent prevents stress concentration and potential cracking while maintaining the thin electrolyte design.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

3Reliability

If a protruding portion is added to the insulation surface, then the level difference is mitigated and electrode cracking is prevented, but the manufacturing process becomes more complex

Engineering Contradiction:
Improveelectrode continuityVSAvoidmanufacturing process simplicity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent merges the intermediate layer with either the solid electrolyte body or the insulation member, creating an integrated composite structure. This integration reduces the number of separate components and assembly steps, thereby simplifying the manufacturing process while still providing the stress-distributing function that prevents electrode cracking.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent creates a composite ceramic layer that combines the electrolyte portion and the insulation portion with an intermediate transition zone. This composite structure is manufactured as an integrated unit using co-firing or sintering processes, which simplifies production compared to assembling separate parts, while the intermediate layer within the composite provides the necessary stress distribution to prevent cracking.

Inventive Principle:
Principle #40Composite materials

Data Source

PatentUS10145816B2Gas sensor element, gas sensor, and method of manufacturing gas sensor element
Publication Date: 2018.12.04 NITERRA CO LTD
  • US10145816B2 patent drawing
  • US10145816B2 patent drawing
  • US10145816B2 patent drawing

AI summary

A gas sensor element (10) includes a composite ceramic layer (111) having an insulation portion (112) and an electrolyte portion (131) disposed within a through hole (112h), and a first conductor layer (150) extending in a continuous manner on a first insulation main surface (113) as well as on a first electrolyte main surface (133). The electrolyte portion (131) is thinner than the insulation portion (112), and the first electrolyte main surface (133) is located on a thickness-direction inward side DTN. The insulation portion (112) has, on a first insulation main surface side, a protruding portion (122) overlying the first electrolyte main surface (133). The thickness of the protruding portion (122) reduces toward the inward side DR1 of the through hole (112h). The first conductor layer (150) extends in a continuous manner on a protrusion surface (122s) as well as on the first electrolyte main surface (133).