Gas Sensor Fibrous Ceramic Coating Mechanical Robustness

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Solution Overview

Problem

Conventional gas sensors, particularly heat tone sensors with Pellistor elements, lack mechanical robustness, leading to potential damage under high mechanical loads, which can compromise their ability to reliably detect combustible gases in industrial environments.

Innovation Solution

Incorporating a fibrous material, such as glass fibers, into the ceramic coating of the heating coil in the gas sensor, which enhances mechanical stability and resistance to high temperatures without affecting sensitivity, and using a platinum or platinum alloy heating coil with a catalyst and support nanoparticles to maintain detection efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the measuring element (Pellistor bead) is made from a platinum wire coated with ceramic, then the sensor achieves broad-band detection capability and low energy consumption, but the measuring element lacks mechanical robustness and may be damaged under high mechanical loads

Engineering Contradiction:
Improvedetection reliabilityVSAvoidmechanical strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent applies composite materials by combining ceramic coating with fibrous reinforcement materials (such as glass fibers, aluminum oxide fibers, or zirconium oxide fibers) to create a mechanically stronger Pellistor bead. This composite structure maintains the catalytic properties of the ceramic while adding tensile strength and fracture resistance from the fibrous reinforcement, directly resolving the contradiction between detection reliability and mechanical strength.

Inventive Principle:
Principle #40Composite materials

2Strength

If a swinging suspension is used to protect the gas sensor from mechanical shocks, then the Pellistor bead is protected against mechanical effects, but the device complexity increases and hermetic sealing becomes difficult

Engineering Contradiction:
Improvemechanical protectionVSAvoidsensor construction complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent extracts the mechanical protection function from the overall sensor construction by incorporating shock-absorbing and vibration-dampening materials directly into the Pellistor bead itself. This eliminates the need for separate swinging suspension mechanisms, reducing device complexity while maintaining mechanical protection. The protection is now an intrinsic property of the measuring element rather than an extrinsic mechanical system.

Inventive Principle:
Principle #2Taking out (Extraction)

3Strength

If additional support wires are used to protect the measuring element, then the Pellistor bead is protected against mechanical effects, but undesired heat removal occurs through the support wires

Engineering Contradiction:
Improvemechanical supportVSAvoidheat loss
Core Design Contradiction:
StrengthVSLoss of energy

Solution Approach 1:

The patent uses composite materials with thermally insulating fibrous reinforcements (such as glass fibers or ceramic fibers) that provide mechanical support while minimizing thermal conduction. These fibers have low thermal conductivity compared to metal support wires, thereby reducing heat loss from the heated Pellistor bead while still providing the necessary mechanical strength and structural support.

Inventive Principle:
Principle #40Composite materials

4Strength

If the ceramic is made denser to improve mechanical strength, then the Pellistor bead becomes more robust, but gas diffusion to the catalytic surface is hindered

Engineering Contradiction:
Improveceramic strengthVSAvoidgas diffusion
Core Design Contradiction:
StrengthVSQuantity of substance

Solution Approach 1:

The patent applies local quality by creating a heterogeneous ceramic structure with varying density and porosity in different regions. The outer shell or surface regions maintain higher density for mechanical strength, while the inner regions or pathways toward the catalytic surface retain higher porosity to facilitate gas diffusion. This spatial variation in material properties allows simultaneous optimization of both mechanical strength and gas transport.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The addition of fibrous materials significantly improves the mechanical robustness of the gas sensor while preserving sensitivity to combustible gases, allowing for reliable detection without compromising porosity or catalytic activity, even under mechanical stress.

Implementation Method 1

the measuring element has a heating coil, which is coated with a catalytically active or inactive ceramic

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Implementation Method 2

Combustible substances possibly present in a gas mixture present in the surrounding area are catalytically reacted here at the measuring element. An oxidation reaction now takes place, which ultimately leads to a heat tone signal

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 3

An oxidation reaction now takes place, which ultimately leads to a heat tone signal

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS11035700B2Gas sensor, measuring element for a gas sensor and method for preparing a measuring element
Publication Date: 2021.06.15 DRAGER SAFETY AG & CO KAAA
  • US11035700B2 patent drawing
  • US11035700B2 patent drawing
  • US11035700B2 patent drawing

AI summary

A gas sensor 100 includes a housing 110 and with a measuring element 10. The measuring element 10 has a heating coil 20, which is coated with a catalytically active or inactive ceramic 30. The ceramic 30 contains a fibrous material. The fibrous material may be, for example, a glass fiber material.