Gas Sensor Protective Layer Segmentation for Thermal Shock

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Solution Overview

Problem

Gas sensors with protective layers face a trade-off between water resistance and rapid heat-up performance, as the protective layers increase heat capacity and constraint force, leading to poor heat-up performance and potential detachment due to environmental vibrations.

Innovation Solution

A three-layer porous protective layer structure is applied to the gas sensor element, with a first layer for adhesion, a second layer for thermal insulation, and a third layer for strength and water resistance, optimizing porosity and thickness to balance thermal shock resistance and heat-up performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a protective layer is provided to improve thermal shock resistance, then water resistance is improved, but heat capacity increases and rapid heat-up performance deteriorates

Engineering Contradiction:
Improvewater resistanceVSAvoidrapid heat-up performance
Core Design Contradiction:
ReliabilityVSSpeed

Solution Approach 1:

The protective layer is divided into three distinct layers with different properties: a first layer for adhesion, a second layer with high porosity (30-70%) for thermal insulation, and a third layer with lower porosity (10-40%) for strength and water resistance. This segmentation allows each layer to optimize its function while collectively resolving the contradiction between water resistance and heat-up performance.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the protective layer structure have different porosity values and thicknesses tailored to their specific functions. The second layer has high porosity for thermal insulation, while the third layer has lower porosity for mechanical strength and water resistance. This local differentiation of properties enables simultaneous achievement of water resistance and rapid heat-up performance.

Inventive Principle:
Principle #3Local quality

2Reliability

If a protective layer is provided to improve thermal shock resistance, then water resistance is improved, but the sensor element becomes more susceptible to detachment due to environmental vibrations

Engineering Contradiction:
Improvewater resistanceVSAvoidadhesion stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The protective layer is segmented into three functional layers, with the first layer specifically designed for adhesion to the sensor element surface. This separate adhesion layer ensures strong bonding that resists detachment from environmental vibrations, while the subsequent layers provide water resistance and thermal insulation properties.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The protective layer structure uses composite materials with different porosity and mechanical properties arranged in a specific sequence. The combination of materials with varying characteristics creates a multi-functional protective structure that simultaneously provides adhesion, water resistance, and thermal insulation, preventing both detachment and water ingress.

Inventive Principle:
Principle #40Composite materials

3Reliability

If a protective layer is provided to prevent water-induced cracking, then thermal shock resistance is improved, but force of constraint on the sensor element increases

Engineering Contradiction:
Improvethermal shock resistanceVSAvoidforce of constraint
Core Design Contradiction:
ReliabilityVSForce

Solution Approach 1:

The protective layer structure applies different mechanical properties to different layers: the first layer provides adhesion with appropriate constraint, while the second and third layers with their specific porosity values provide thermal insulation and water resistance with reduced constraint force. This local differentiation of mechanical properties prevents excessive constraint force while maintaining thermal shock resistance.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves both excellent water resistance and rapid heat-up performance by securing adhesion and reducing thermal conductivity, while maintaining overall strength and preventing water ingress, thus enhancing the sensor's operational reliability.

Implementation Method 1

a second leading-end protective layer disposed to cover the end portion and four side surfaces of the element base including the two main surfaces on which the first leading-end protective layer is disposed; the second leading-end protective layer has a porosity of 30% to 70%

Methodology Applied
Scientific EffectThermal insulation: Thermal Insulation

Implementation Method 2

a third leading-end protective layer disposed to cover the second leading-end protective layer, and having a lower porosity than the second leading-end protective layer, the third leading-end protective layer has a porosity of 10% to 40%

Methodology Applied
Scientific EffectPorosity: Porosity

Implementation Method 3

heat capacity of the sensor element as a whole increases, and force of constraint on the sensor element increases. This leads to poor rapid heat-up performance

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Data Source

PatentUS20210389270A1Sensor element of gas sensor
Publication Date: 2021.12.16 NGK INSULATORS LTD
  • US20210389270A1 patent drawing
  • US20210389270A1 patent drawing
  • US20210389270A1 patent drawing

AI summary

A sensor element includes a porous leading-end protective layer disposed around an outer periphery of an element base in a predetermined range from an end portion on a side where a sensing part is disposed, the protective layer includes: a first layer disposed on two main surfaces of the element base; a second layer disposed to cover the end portion and four side surfaces of the element base including the two main surfaces on which the first layer is disposed; and a layer disposed to cover the second layer, the second layer has a porosity of 30% to 70% and a thickness of 6 to 30 times a thickness of the first layer, and the third layer has a porosity of 10% to 40% and a thickness of 2 to 15 times the thickness of the first layer.