Miniaturized Gas Sensor With Selective Membrane for Humidity Correction

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Solution Overview

Problem

Conventional miniaturized gas sensors lack sufficient sensitivity to measure air pollutant concentrations in outdoor environments, particularly for gases like NO2 and O3, which are present at low ppb levels. Additionally, these sensors are prone to interference from ambient temperature and relative humidity changes, leading to inaccurate measurements.

Innovation Solution

The proposed solution involves an apparatus and method for measuring gas concentration using a sensing unit with a first selective water vapour-permeable membrane and two working electrodes. The first electrode detects changes in ambient relative humidity, while the second electrode detects a superimposed signal from both humidity changes and gas molecule reactions. The processing unit isolates the gas-related signal by subtracting humidity and baseline terms, enabling accurate gas concentration measurement.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Volume of moving object

If conventional miniaturized gas sensors are used, then device size is reduced, but measurement precision deteriorates due to insufficient sensitivity for ppb-level gas concentrations

Engineering Contradiction:
Improvesensor sizeVSAvoidgas concentration measurement precision
Core Design Contradiction:
Volume of moving objectVSMeasurement precision

Solution Approach 1:

The sensor is segmented into multiple functional components: a selective water vapour-permeable membrane that separates water molecules from gas molecules, a working electrode that detects electrochemical signals, and a reference electrode that provides baseline correction. This segmentation allows the small sensor to independently measure and correct for humidity interference, thereby maintaining ppb-level measurement precision while keeping the device miniaturized.

Inventive Principle:
Principle #1Segmentation

2Adaptability or versatility

If electrochemical sensors operate in outdoor environments, then adaptability improves, but measurement precision deteriorates due to temperature and humidity interference

Engineering Contradiction:
Improveoutdoor environment adaptabilityVSAvoidgas concentration measurement precision
Core Design Contradiction:
Adaptability or versatilityVSMeasurement precision

Solution Approach 1:

A selective water vapour-permeable membrane is introduced as an intermediary component between the outdoor environment and the sensor electrodes. This membrane selectively allows water molecules to pass through while blocking gas molecules, thereby mediating the interference from ambient humidity and temperature. The membrane enables the sensor to adapt to outdoor conditions while maintaining measurement precision by isolating the electrochemical detection from humidity fluctuations.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Measurement precision

If correction algorithms are applied to temperature and humidity interference, then measurement precision improves, but device complexity increases

Engineering Contradiction:
Improvegas concentration measurement precisionVSAvoidcorrection algorithm complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The sensor implements self-service correction by incorporating a reference electrode that automatically measures baseline drift caused by temperature and humidity changes. The working electrode signal is then corrected by subtracting the reference electrode signal, providing real-time compensation without requiring external correction algorithms or additional processing complexity. This self-correcting mechanism maintains measurement precision while keeping the device simple.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively corrects for temperature and relative humidity-induced interferences, allowing for precise measurement of gas concentrations at ppb levels. The method provides a wide range of applicability and improves the accuracy of gas concentration measurements in outdoor environments.

Implementation Method 1

The first selective water vapour-permeable membrane may be configured to allow the first working electrode to be in contact with ambient water molecules but not with gas molecules to be measured

Methodology Applied
Scientific EffectSelective permeation: Semipermeable Membrane

Implementation Method 2

the first working electrode may be configured to generate an electrical signal caused by change in ambient relative humidity

Methodology Applied
Scientific EffectElectrochemical redox reaction: Redox Reactions

Implementation Method 3

the second working electrode may be configured to generate a superimposed electrical signal caused by both the change in ambient relative humidity and reaction of the gas molecules to be measured

Methodology Applied
Scientific EffectElectrochemical redox reaction: Redox Reactions

Data Source

PatentUS12265053B2Apparatus, method and sensor for measuring gas concentration
Publication Date: 2025.04.01 OUYANG BIN
  • US12265053B2 patent drawing
  • US12265053B2 patent drawing
  • US12265053B2 patent drawing

AI summary

An apparatus, method and sensor for measuring gas concentration. The apparatus includes a sensing unit and a processing unit. The sensing unit includes a first selective water vapour-permeable membrane, a first working electrode and a second working electrode. The first selective water vapour-permeable membrane allows the first working electrode to be in contact with water molecules while to prevent this first working electrode from being in contact with the gas molecules to be measured. The first working electrode generates an electrical signal caused by change in relative humidity, the second working electrode generates a superimposed electrical signal caused by the change in relative humidity and the gas molecules to be measured, and the processing unit acquires concentration of the gas based on the electrical signal and the superimposed electrical signal.