Gas Sensor Using Ionic Liquid and Surface Plasmon Resonance

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Solution Overview

Problem

Infrared light absorption type gas sensors require a large optical system, while surface plasmon resonance sensors struggle to measure gases with small molecular weights like CO2 due to their size constraints and refractive index proportionality.

Innovation Solution

A gas sensor configuration featuring a metal layer with a prism and a gas-absorbing liquid that changes dielectric constant, allowing detection through surface plasmon resonance phenomena without a light absorption path, enabling the measurement of gases with small molecular weights.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If an infrared light absorption type gas sensor is used, then gas detection capability is achieved, but the optical system size increases

Engineering Contradiction:
Improvegas detection capabilityVSAvoidoptical system size
Core Design Contradiction:
Measurement precisionVSVolume of stationary object

Solution Approach 1:

The invention extracts and eliminates the light absorption path component from the optical system by adopting surface plasmon resonance detection. This removes the need for long optical paths and complex light absorption structures, thereby reducing the overall sensor size while maintaining gas detection capability through a different physical mechanism.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the detection parameter from light absorption intensity to surface plasmon resonance characteristics. By measuring changes in resonance conditions rather than light absorption, the system achieves gas detection without requiring a large light absorption path, thus resolving the size constraint.

Inventive Principle:
Principle #35Parameter changes

2Volume of stationary object

If a surface plasmon resonance gas sensor is used to reduce size, then optical system size is reduced, but detection of gases with small molecular weight such as CO2 becomes difficult

Engineering Contradiction:
Improvesensor sizeVSAvoiddetection capability for small molecular weight gases
Core Design Contradiction:
Volume of stationary objectVSMeasurement precision

Solution Approach 1:

The invention introduces a gas-absorbing liquid as an intermediary between the target gas and the surface plasmon resonance sensor. The liquid selectively absorbs gases with small molecular weights like CO2, concentrating them and enhancing their effect on the dielectric constant, thereby enabling detection of these gases despite the sensor's small size.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the detection approach by measuring dielectric constant changes in the gas-absorbing liquid rather than directly measuring the gas properties. This parameter transformation allows the sensor to detect gases with small molecular weights that would otherwise be difficult to detect with conventional surface plasmon resonance methods.

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If surface plasmon resonance is used for gas detection, then sensor size is reduced, but the ability to measure gases with small molecular weight is lost

Engineering Contradiction:
Improvesensor configurationVSAvoiddetection range for different gas types
Core Design Contradiction:
Device complexityVSAdaptability or versatility

Solution Approach 1:

The gas-absorbing liquid serves as a mediator that bridges the gap between the simple surface plasmon resonance sensor and the diverse range of detectable gases. By selecting different absorbing liquids with specific affinities, the sensor can be adapted to detect various gas types including those with small molecular weights, thereby enhancing versatility without increasing device complexity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention creates a universal detection platform where the same surface plasmon resonance sensor structure can detect multiple gas types by simply changing the gas-absorbing liquid. This multi-functional approach allows a single compact device to serve multiple detection purposes, improving adaptability while maintaining simple device architecture.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration reduces sensor size and enables effective detection of gases with small molecular weights by measuring changes in light intensity due to surface plasmon resonance, overcoming previous size and measurement limitations.

Implementation Method 1

a detector configured to detect the gas based on a change in light intensity of the exit light by a surface plasmon resonance phenomenon that occurs in the metal layer

Methodology Applied
Scientific EffectSurface plasmon resonance: Resonance

Implementation Method 2

a gas absorbing liquid provided on a surface of the metal layer, and capable of absorbing the gas

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentEP2803974B1Gas sensor
Publication Date: 2020.04.15 OMRON CORP
  • EP2803974B1 patent drawingFigure 1
  • EP2803974B1 patent drawingFigure 2A~2B
  • EP2803974B1 patent drawingFigure 3

AI summary

A gas sensor is proposed, which can detect a gas by a novel configuration while reduction in size is achieved. The gas sensor (1) does not need a light absorption path as in a prior art so that the size can be reduced correspondingly. Further, in the gas sensor (1), a gas is absorbed in an ionic liquid (IL), and a dielectric constant of the ionic liquid (IL) that changes by absorbing the gas can be measured according to a change in light intensity that occurs by a surface plasmon resonance phenomenon in a metal layer (7). Thus, the gas sensor (1) including the novel configuration that can detect a gas based on the change in the light intensity can be realized.