Gas Sensor Segmentation for Trace Ammonia Detection

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Solution Overview

Problem

Existing gas sensor devices face challenges in accurately detecting trace gases like ammonia due to high sensitivity films, such as CuBr, which experience fluctuations in initial resistance values, making it difficult to distinguish between gas presence and background fluctuations without using blank gas, and are hard to configure for multiple gases.

Innovation Solution

A gas sensor device with a sensor film whose resistance increases with gas adsorption, featuring three electrodes and a protective film covering the sensor surface between two electrodes, allowing for simultaneous measurement of resistances to accurately determine gas presence and concentration without blank gas, using a resistance ratio formula for precise calculations.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If a high sensitivity sensor film (e.g., CuBr) is used to detect trace gases, then the sensitivity of gas detection is improved, but the initial resistance values fluctuate making it difficult to distinguish gas presence from background fluctuations

Engineering Contradiction:
Improvegas detection sensitivityVSAvoidinitial resistance stability
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The sensor surface is divided into multiple regions with different protective film configurations. Some regions have protective films that prevent gas adsorption (serving as reference), while other regions have exposed sensor surfaces that allow gas adsorption (serving as sensing regions). This segmentation allows simultaneous measurement of both reference and sensing signals, enabling distinction between background fluctuations and actual gas presence.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the sensor film are given different local properties: some regions are covered with protective films (making them gas-impermeable and stable), while other regions are exposed (making them gas-permeable and sensitive). This local differentiation allows the same sensor film to simultaneously provide stable reference signals and sensitive detection signals.

Inventive Principle:
Principle #3Local quality

2Reliability

If a protective film covers the sensor surface to stabilize resistance, then background fluctuations are reduced, but the sensor cannot detect gas in covered regions

Engineering Contradiction:
Improveresistance stabilityVSAvoidgas detection capability
Core Design Contradiction:
ReliabilityVSMeasurement precision

Solution Approach 1:

The sensor surface is segmented into covered regions (with protective films for stability) and exposed regions (without protective films for gas detection). By measuring resistance changes in both regions and comparing them, the system achieves both stability and detection capability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The protective film is applied selectively to certain regions of the sensor surface, creating local quality differences. Covered regions provide stable baseline resistance values, while exposed regions provide gas-sensitive resistance changes. The combination enables reliable gas detection.

Inventive Principle:
Principle #3Local quality

3Productivity

If three electrodes are used with partial exposure for simultaneous resistance measurement, then gas presence can be determined without blank gas, but the device complexity increases

Engineering Contradiction:
Improvemeasurement efficiencyVSAvoidelectrode configuration
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The electrode configuration is segmented into three electrodes where at least one protective film is positioned between two electrodes. This allows measurement of resistance across different regions (covered and exposed) simultaneously, enabling gas detection without requiring separate blank gas measurements.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The three-electrode configuration with selective protective film placement serves multiple functions: it provides reference resistance measurement from covered regions, sensing resistance measurement from exposed regions, and enables calculation of resistance ratios for gas detection. This multi-functional design eliminates the need for separate blank gas measurement steps.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables high-accuracy sensing and quantification of trace gases like ammonia, even with sensitive films, by minimizing background fluctuations and eliminating the need for blank gas, facilitating precise gas detection and concentration measurement.

Implementation Method 1

a sensor film (13) whose resistance increases with an increase in an amount of gas adsorbed on a sensor surface (13A)

Methodology Applied
Scientific EffectGas adsorption: Adsorption

Data Source

PatentUS10495595B2Gas sensor device, gas measurement method, and gas measurement device
Publication Date: 2019.12.03 FUJITSU LTD
  • US10495595B2 patent drawing
  • US10495595B2 patent drawing
  • US10495595B2 patent drawing

AI summary

A gas sensor device includes: a sensor film including a sensor surface and a resistance which increases with an increase in an amount of gas adsorbed on the sensor surface; a first electrode, a second electrode, and a third electrode that are electrically coupled to the sensor film; and a protective film that covers the sensor surface in a region between the first electrode and the second electrode, wherein the sensor surface is exposed in a region near the third electrode.