Gas Separation Membrane with Chemically Bonded Resin Layers

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Solution Overview

Problem

Existing gas separation membranes face challenges in achieving high mechanical strength and high transmission rates due to insufficient adhesion between layers, leading to peeling issues and reduced gas permeability.

Innovation Solution

A gas separation membrane configuration featuring a porous layer with a first resin layer containing organopolysiloxane and a second resin layer also containing organopolysiloxane, where the first resin layer has higher porosity than the second resin layer, and the second resin layer is chemically bonded to the first resin layer, enhancing adhesion and gas permeability without the need for increased thickness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If a plasma-polymerized film is deposited on a thin film to form a composite membrane, then gas selectivity is improved, but adhesion between films becomes insufficient causing peeling

Engineering Contradiction:
Improvegas selectivityVSAvoidadhesion between films
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent introduces an intermediary layer between the thin film and the plasma-polymerized film to improve adhesion. This intermediary layer acts as a mediator that chemically bonds to both the thin film substrate and the plasma-polymerized coating, preventing peeling while maintaining gas selectivity. The intermediary layer resolves the adhesion problem without compromising the gas separation function.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a multi-layer composite membrane structure consisting of a thin film, an intermediary adhesion layer, and a plasma-polymerized film. By combining different materials with complementary properties, the composite structure achieves both strong interlayer adhesion and high gas selectivity, overcoming the limitations of simple binary composites.

Inventive Principle:
Principle #40Composite materials

2Strength

If the thickness of the thin film is increased to seal pores of the porous support, then mechanical strength is improved, but gas transmission rate decreases requiring more energy

Engineering Contradiction:
Improvemechanical strengthVSAvoidenergy for gas separation
Core Design Contradiction:
StrengthVSUse of energy by moving object

Solution Approach 1:

The patent applies local quality by creating regions of different thickness and porosity within the membrane structure. The thin film provides localized pore sealing for mechanical integrity, while the porous support layer maintains overall structural strength. This localized differentiation allows the membrane to achieve both mechanical strength and high gas transmission without requiring uniform thickness increase throughout the entire membrane.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent utilizes porous materials in the support layer to maintain mechanical strength while allowing high gas permeability. The porous structure provides structural rigidity through its framework while the interconnected pores facilitate efficient gas transport, reducing the energy required for gas separation compared to dense non-porous structures.

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The configuration improves mechanical strength and gas permeability, allowing the membrane to function effectively even when bent or folded, with reduced energy input for separation and enhanced selective separation properties for carbon dioxide.

Implementation Method 1

the second resin layer is chemically bonded to the first resin layer

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Implementation Method 2

a porous layer, a first resin layer provided at a surface on one side of the porous layer

Methodology Applied
Scientific EffectPermeation: Permeation

Data Source

PatentUS20240091717A1Gas separation membrane and method of producing gas separation membrane
Publication Date: 2024.03.21 SEIKO EPSON CORP
  • US20240091717A1 patent drawing
  • US20240091717A1 patent drawing
  • US20240091717A1 patent drawing

AI summary

A gas separation membrane includes a porous layer, a first resin layer provided at a surface on one side of the porous layer, the first resin layer including an organopolysiloxane, and a second resin layer provided at a surface of the first resin layer on a side opposite to that of the porous layer, the second resin layer including an organopolysiloxane. The first resin layer has a porosity greater than that of the second resin layer. The second resin layer is chemically bonded to the first resin layer.