Gas-Solid Phase Chemistry for Non-Volatile Substance Detection

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Solution Overview

Problem

Detection systems face challenges in identifying non-volatile substances like inorganic oxidizer salts used in homemade explosives, as they require extreme temperature ramping and expensive trap materials, leading to increased analysis time and exposure risks.

Innovation Solution

The use of vaporized clustering agents in gas-solid phase chemistry to increase the volatility of non-volatile substances, allowing for their detection without extreme temperature ramping and reducing exposure to dangerous chemicals, by chemically modifying them to make them more volatile for analysis.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If extreme temperature ramping is used to vaporize non-volatile substances, then detection capability is improved, but analysis time increases significantly and power consumption increases

Engineering Contradiction:
Improvedetection capabilityVSAvoidanalysis time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

A clustering agent is introduced as an intermediary substance that interacts with non-volatile analytes through gas-solid phase chemistry. The clustering agent forms volatile clusters with the analyte molecules, enabling them to be vaporized at lower temperatures without requiring extreme temperature ramping, thus reducing analysis time while maintaining detection capability

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the volatility parameter of non-volatile substances by introducing clustering agents. The clustering agents modify the physical-chemical properties of the analytes, transforming them from non-volatile to volatile state, which allows detection without extreme heating while reducing analysis time and power consumption

Inventive Principle:
Principle #35Parameter changes

2Reliability

If extreme temperature ramping is used to vaporize non-volatile substances, then detection capability is improved, but power consumption increases

Engineering Contradiction:
Improvedetection capabilityVSAvoidpower consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The clustering agent serves as a mediator that enables vaporization of non-volatile substances through chemical interaction rather than extreme thermal energy input. This reduces the power consumption of the thermal desorber while maintaining detection capability through the formation of volatile analyte-clustering agent clusters

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention replaces the mechanical/thermal approach (extreme temperature ramping) with a chemical approach (gas-solid phase chemistry involving clustering agents). This substitution reduces the energy input required for vaporization, thereby lowering power consumption while maintaining detection effectiveness

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Reliability

If high temperatures are used for detection, then non-volatile substances can be vaporized, but expensive trap materials stable at high temperatures are required

Engineering Contradiction:
Improvedetection capabilityVSAvoidcost of trap material
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The invention changes the temperature parameter by introducing clustering agents that enable vaporization at lower temperatures. This allows the use of less expensive trap materials that are stable at moderate temperatures rather than requiring costly high-temperature stable materials, while maintaining detection capability through enhanced volatility of analyte clusters

Inventive Principle:
Principle #35Parameter changes

4Reliability

If conventional detection methods are used for non-volatile substances, then detection is possible, but substances with low volatility cannot be vaporized within the detection system

Engineering Contradiction:
Improvedetection capabilityVSAvoiddetection range
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The clustering agent acts as an intermediary that bridges the gap between non-volatile analytes and the vaporization requirement of detection systems. By forming volatile clusters with analyte molecules, it extends the detection range to include substances with very low volatility that would otherwise be undetectable, thereby improving both reliability and adaptability

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the volatility parameter of detectable substances through chemical interaction with clustering agents. This expands the detection range to encompass non-volatile and low-volatility substances by transforming them into volatile cluster forms, enhancing system versatility without sacrificing detection reliability

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the detection of non-volatile substances efficiently, reducing analysis time and exposure risks while minimizing the use of expensive materials and power consumption, effectively identifying potentially harmful substances.

Implementation Method 1

introducing a vaporized clustering agent into the desorber, wherein the clustering agent increases the volatility of the substance of interest

Methodology Applied
Scientific EffectGas-solid phase chemistry:

Implementation Method 2

the clustering agent increases the volatility of the substance of interest

Methodology Applied
Scientific EffectVolatility enhancement:

Implementation Method 3

vaporizing the substance of interest

Methodology Applied
Scientific EffectVaporization:

Implementation Method 4

inserting the trap into a thermal desorber; vaporizing the substance of interest

Methodology Applied
Scientific EffectThermal desorption: Desorption

Data Source

PatentUS10386340B2Detection of substances of interest using gas-solid phase chemistry
Publication Date: 2019.08.20 RAPISCAN SYST INC (US)
  • US10386340B2 patent drawing
  • US10386340B2 patent drawing
  • US10386340B2 patent drawing

AI summary

The present disclosure is directed to methods and systems for detecting a chemical substance. The methods and systems include using gas-solid phase chemistry to chemically and/or physically modify a substance of interest so that the substance can be vaporized and detected through an analysis of the substance.