Gas-solid separating method and system for simple substance sulphur in sulphur-containing exhaust

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current methods for treating sulphur-containing exhausts, such as the Claus process, result in waste of sulphur resources and secondary pollution due to unutilized simple substance sulphur particles, necessitating a more efficient gas-solid separating method and system to enhance sulphur recovery and reduce environmental harm.

Innovation Solution

A method involving rapid cooling of sulphur-containing exhaust to condense sulphur vapor into solid particles, followed by low-temperature washing with a heavy liquid solvent, separation, and recycling of solvents to recover sulphur, utilizing a system comprising quick cooling, low-temperature washing, light and heavy liquid phase separation, and solvent recycling to achieve high sulphur recovery efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If the Claus method is used to oxidize H2S to simple substance sulphur, then sulphur production is achieved, but simple substance sulphur particles remain in the exhaust causing resource waste and secondary pollution

Engineering Contradiction:
Improvesulphur productionVSAvoidsecondary pollution
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The patent changes the temperature parameter by rapidly cooling the exhaust gas to below 25°C, causing sulphur vapor to condense into solid particles that can be separated. This parameter change transforms the harmful sulphur vapor into separable solid particles, resolving the contradiction between sulphur production and secondary pollution.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes phase transition by cooling sulphur vapor to condense it into solid particles. This phase change from gas to solid enables effective separation of sulphur from the exhaust gas, eliminating the harmful effects of sulphur vapor while maintaining sulphur production.

Inventive Principle:
Principle #36Phase transitions

2Manufacturing precision

If rapid cooling is performed to condense sulphur vapor into solid particles, then sulphur separating efficiency is improved, but energy consumption increases

Engineering Contradiction:
Improvesulphur separating efficiencyVSAvoidenergy consumption
Core Design Contradiction:
Manufacturing precisionVSUse of energy by moving object

Solution Approach 1:

The patent employs self-service by using the exhaust gas itself as the cooling medium. The exhaust gas cools down other portions of the exhaust stream, reducing the need for external cooling energy input while achieving the required temperature for sulphur condensation and separation.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent merges the cooling function with the existing exhaust gas flow system. By integrating the rapid cooling process into the natural exhaust flow and using the exhaust gas itself for cooling, the system reduces additional energy requirements while maintaining high sulphur separation efficiency.

Inventive Principle:
Principle #5Merging (Combining)

3Manufacturing precision

If heavy liquid phase solvent is used for washing and separating sulphur particles, then separation efficiency is improved, but solvent recycling complexity increases

Engineering Contradiction:
Improveseparation efficiencyVSAvoidsolvent recycling complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent replaces complex mechanical separation systems with a chemical solution approach. By using heavy liquid phase solvent that selectively dissolves sulphur particles, the system achieves efficient separation through chemical affinity rather than complex mechanical means, simplifying the overall recycling process.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The heavy liquid phase solvent acts as an intermediary substance that facilitates the separation of sulphur particles from exhaust gas. The solvent temporarily holds sulphur in solution, enabling easy separation and subsequent recycling of both the solvent and sulphur, thereby reducing system complexity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method achieves sulphur recovery efficiencies of 90% or higher, reduces energy consumption, and minimizes environmental pollution by effectively purifying exhaust gases and recycling sulphur resources.

Implementation Method 1

rapidly cooling the sulphur-containing exhaust to a temperature below 25° C. so that the simple substance sulphur vapor in the sulphur-containing exhaust is condensed into simple substance sulphur solid particles

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 2

the dust is dissolved in the light liquid phase in the extraction tank, the light liquid is discharged, and the simple substance sulphur particles are dissolved in the heavy liquid phase in the extraction tank

Methodology Applied
Scientific EffectDifferential solubility: Solvation

Implementation Method 3

heating it to 50-90° C. by irradiation, collecting simple substance sulphur particles, and evaporating to produce a heavy gas phase solvent

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 4

cooling the heavy gas phase solvent to a temperature below 25° C. so that the heavy gas phase solvent is converted into a heavy liquid phase solvent

Methodology Applied
Scientific EffectCondensation: Condensation

Data Source

PatentUS20200299134A1Gas-solid separating method and system for simple substance sulphur in sulphur-containing exhaust
Publication Date: 2020.09.24 KUNMING UNIV OF SCI & TECH
  • US20200299134A1 patent drawing

AI summary

The present invention discloses a gas-solid separating method and a gas-solid separating system for simple substance sulphur in sulphur-containing exhaust. The gas-solid separating method for simple substance sulphur in sulphur-containing exhaust comprises the following steps: first, cooling sulphur-containing exhaust at an extremely high speed; then, separating dust; finally, recycling a heavy liquid phase solvent and simple substance sulphur; according to the method disclosed by the present invention, the separating efficiency of the simple substance sulphur is up to 90 percent or above; moreover, the exhaust is further purified, and an environment pollution accident is avoided; in a separating process of the simple substance sulphur, the heavy liquid phase solvent of the simple substance sulphur evaporates to form a gas phase solvent which can be recycled as the liquid phase solvent for reusing through cooling, so that the sulphur removing cost is reduced. The system comprises a quick cooling system, a low-temperature washing and purifying system, a light liquid phase and heavy liquid phase separating system, a washing liquid recycling system and a simple substance sulphur recycling system. The system disclosed by the present invention has the advantages of stability and high efficiency in sulphur-containing exhaust treatment, high simple substance sulphur separating efficiency, energy conservation and environmental protection.