Gate Controlled Atomic Switch Electrochemical Training

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Solution Overview

Problem

Current technologies have not successfully implemented an atomic transistor with an independent gate electrode to control and switch the conductance between source and drain electrodes on an atomic scale, especially at room temperature and under ambient conditions, due to challenges in establishing and controlling atomic contacts with predictable conductance values.

Innovation Solution

An electrochemically produced atomic point contact is trained through cycles of deposition and dissolution, using a control potential to switch the contact between predefined conductance states, allowing for specific opening and closing of the contact between source and drain electrodes, enabling operation as an atomic switch or transistor at room temperature and ambient conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If mechanical stretching or galvanic deposition is used to create atomic contacts, then atomic-scale contacts can be established, but the conductance values cannot be predetermined or adjusted to specific values

Engineering Contradiction:
Improveconductance value precisionVSAvoidcontact fabrication complexity
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent applies preliminary action by training the atomic contact through repeated cycles of deposition and dissolution before actual use. This training process conditions the contact to switch between specific predefined conductance states (e.g., 1G0 and 3G0), enabling predictable and reproducible conductance values that can be predetermined for specific applications.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent utilizes parameter changes by controlling the electrochemical deposition and dissolution potentials to precisely adjust the conductance state of the atomic contact. By varying the applied potential during training cycles, the contact can be switched between different conductance levels, allowing predetermined conductance values to be achieved and maintained.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If macroscopic electrodes are moved to open and close atomic contacts, then atomic contacts can be established, but the device complexity and mechanical wear increase

Engineering Contradiction:
Improvecontact switching reliabilityVSAvoidelectrode mechanism complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent replaces the mechanical system of moving macroscopic electrodes with an electrochemical system. Instead of mechanically opening and closing contacts, the invention uses electrochemical deposition and dissolution processes controlled by potential application to create and remove atomic contacts. This substitution eliminates mechanical wear and reduces device complexity while maintaining reliable switching.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The atomic contact serves itself by being created and destroyed through electrochemical reactions at the electrode surfaces. The contact forms spontaneously when deposition potential is applied and dissolves when dissolution potential is applied, without requiring external mechanical manipulation. This self-service mechanism simplifies the overall device structure.

Inventive Principle:
Principle #25Self-service

3Manufacturing precision

If single atom position switching is used, then atomic-scale switching is achieved, but operation is limited to low temperatures and ultra high vacuum conditions

Engineering Contradiction:
Improveatomic position control precisionVSAvoidoperating condition flexibility
Core Design Contradiction:
Manufacturing precisionVSAdaptability or versatility

Solution Approach 1:

The patent changes the operating parameters from mechanical position control to electrochemical potential control. By applying deposition and dissolution potentials, the atomic contact can be created and destroyed under ambient conditions (room temperature and atmospheric pressure), eliminating the need for low temperature and ultra high vacuum environments required by single atom position switching methods.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the mechanical atom-positioning method with an electrochemical approach. Instead of physically moving a single atom between positions using mechanical forces, the invention uses electrochemical deposition to create atomic contacts and dissolution to remove them, enabling operation under versatile ambient conditions rather than restricted cryogenic vacuum conditions.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Length of moving object

If atomic contacts are used for switching, then miniaturization is achieved, but the conductance ratio between on and off states is insufficient

Engineering Contradiction:
Improvecomponent dimensionVSAvoidswitching state distinction
Core Design Contradiction:
Length of moving objectVSReliability

Solution Approach 1:

The training process serves as preliminary action that conditions the atomic contact to exhibit stable switching between distinct conductance states. Through repeated deposition and dissolution cycles, the contact is prepared to reliably switch between predefined conductance levels (e.g., 1G0 and 3G0), ensuring a sufficient conductance ratio for reliable switching operation in miniaturized devices.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves a conductance ratio of over 1000:1 between on and off states, with high reproducibility and accuracy, enabling the fabrication of atomic switches and transistors with pre-selectable conductance values, suitable for atomic logic switches and electronics.

Implementation Method 1

an electrochemically produced atomic point contact is trained through cycles of deposition and dissolution

Methodology Applied
Scientific EffectElectrochemical deposition: Electrodeposition

Implementation Method 2

cycles of deposition and dissolution, using a control potential to switch the contact between predefined conductance states

Methodology Applied
Scientific EffectElectrochemical dissolution: Electrolysis

Data Source

PatentUS7960217B2Gate controlled atomic switch
Publication Date: 2011.06.14 PAPST LICENSING GMBH CO
  • US7960217B2 patent drawing
  • US7960217B2 patent drawing
  • US7960217B2 patent drawing

AI summary

The invention relates to a method for producing a switch element. The invention is characterised in that the switch element comprises three electrodes that are located in an electrolyte, two of which (source electrode and drain electrode) are interconnected by a bridge consisting of one or more atoms that can be reversibly opened and closed. The opening and closing of said contact between the source and drain electrodes can be controlled by the potential that is applied to the third electrode (gate electrode). The switch element is produced by the repeated application of potential cycles between the gate electrode and the source or drain electrode. The potential is increased and reduced during the potential cycles until the conductance between the source and drain electrode can be switched back and forth between two conductances, as a result of said change in potential in the gate electrode, as a reproducible function of the voltage of the gate electrode.