Gate Dielectric Fluorine Gradient for Reliable GAA Transistors

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Solution Overview

Problem

The semiconductor industry faces challenges in processing and manufacturing complex integrated circuits (ICs) due to the scaling down process, which increases complexity and requires improved manufacturing methods.

Innovation Solution

A method for manufacturing semiconductor devices involves forming nanostructure channels using alternating semiconductor layers with different etch selectivity and oxidation rates, followed by a series of etching and deposition processes to create gate-all-around transistors, and incorporating fluorination and dipole processes to enhance the gate dielectric layers for improved performance and reliability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If geometry size is decreased to increase functional density, then production efficiency and cost are improved, but processing complexity increases

Engineering Contradiction:
Improveproduction efficiencyVSAvoidprocessing complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent segments the gate structure into multiple components including gate dielectric layers, gate electrode layers, and gate spacer layers formed through sequential deposition and etching processes. This segmentation allows each layer to be optimized independently for specific functions while maintaining overall device performance at scaled dimensions

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent implements a gate-all-around structure where gate dielectric layers and gate electrode layers are nested within gate spacer layers, which are in turn nested within the semiconductor body structure. This nested configuration enables three-dimensional control of the channel while managing processing complexity through systematic layer integration

Inventive Principle:
Principle #7Nested doll (Nesting)

2Manufacturing precision

If alternating semiconductor layers with different etch selectivity are used to form nanostructure channels, then manufacturing precision is improved, but device complexity increases

Engineering Contradiction:
Improvenanostructure channel formation precisionVSAvoidlayer structure complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent employs alternating semiconductor layers with different etch selectivity and oxidation rates at specific locations within the structure. This local differentiation enables selective removal and modification of particular layers during processing, achieving precise nanostructure channel formation without requiring complex global structure modifications

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent utilizes changes in material parameters such as etch selectivity and oxidation rate across different semiconductor layers to enable selective processing. By incorporating layers with varying compositional parameters, the manufacturing process can precisely control channel formation through selective etching and oxidation steps

Inventive Principle:
Principle #35Parameter changes

3Reliability

If fluorination and dipole processes are incorporated to enhance gate dielectric layers, then reliability is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvegate dielectric performanceVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent incorporates fluorination and dipole processes as preliminary treatments to the gate dielectric layers before final device assembly. These preliminary actions pre-condition the dielectric layers with improved electrical properties, reducing the need for subsequent corrective processes and simplifying overall manufacturing

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent applies fluorination and dipole processes that modify the physical and chemical parameters of the gate dielectric layers, such as dielectric constant and charge characteristics. These parameter changes enhance device reliability by improving electrical performance and stability without requiring fundamental structural redesigns

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enhances the manufacturing process by reducing the k-value of dielectric spacers, passivating oxygen vacancies, and adjusting threshold voltages, resulting in improved performance and reliability of the semiconductor devices.

Implementation Method 1

performing a fluorination process to incorporate fluorine into the first gate dielectric layer

Methodology Applied
Scientific EffectFluorination:

Implementation Method 2

passivating oxygen vacancies

Methodology Applied
Scientific EffectPassivation:

Implementation Method 3

followed by a series of etching and deposition processes to create gate-all-around transistors

Methodology Applied
Scientific EffectEtching:

Implementation Method 4

followed by a series of etching and deposition processes to create gate-all-around transistors

Methodology Applied
Scientific EffectDeposition: Deposition (physical)

Data Source

PatentUS20250374646A1Semiconductor device structure and methods of forming the same
Publication Date: 2025.12.04 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US20250374646A1 patent drawing
  • US20250374646A1 patent drawing
  • US20250374646A1 patent drawing

AI summary

A semiconductor device structure and methods of forming the same are described. The structure includes a first gate dielectric layer disposed over a substrate, the first gate dielectric layer includes an inner surface and an outer surface opposite the inner surface, and the first gate dielectric layer includes a fluorine concentration that decreases from the inner surface towards the outer surface. The structure further includes a second gate dielectric layer disposed on the first gate dielectric layer, the first and second gate dielectric layers have a combined thickness, and a thickness of the first gate dielectric layer ranges from about 30 percent to about 80 percent of the combined thickness. The structure further includes a gate electrode layer disposed over the second gate dielectric layer and a spacer disposed adjacent the first gate dielectric layer.