High-Voltage Gate Dielectric Formation Without Mask Layer Removal

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Solution Overview

Problem

High-voltage transistors face issues with breakdown voltage and surface defects due to the use of phosphoric acid in removing nitrogen-containing mask layers during gate dielectric formation, compromising device performance and yield.

Innovation Solution

Forming a semiconductor structure where the nitrogen-containing mask layer is converted into part of the gate dielectric layer, eliminating the need for its removal, thereby enhancing the thickness and reducing surface defects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If phosphoric acid is used to remove nitrogen-containing mask layer, then mask layer removal is achieved, but surface defects are generated and device yield decreases

Engineering Contradiction:
Improvemask layer removalVSAvoiddevice yield
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent extracts and removes the nitrogen-containing mask layer entirely from the process by using a deposition technique that does not require mask layer formation, thereby eliminating the need for mask layer removal and avoiding surface defects caused by phosphoric acid

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent converts the potentially harmful effect of nitrogen-containing materials by using nitrogen-free deposition techniques, transforming what could be a source of surface defects into a beneficial clean interface that improves device yield

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Ease of manufacture

If phosphoric acid removal process is used, then mask layer is removed, but breakdown voltage decreases due to surface defects

Engineering Contradiction:
Improvemask layer removalVSAvoidbreakdown voltage
Core Design Contradiction:
Ease of manufactureVSStrength

Solution Approach 1:

The patent extracts the problematic phosphoric acid removal step from the manufacturing process by adopting a deposition-based approach that forms the gate dielectric layer without requiring mask layer removal, thereby preserving surface quality and maintaining high breakdown voltage

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent converts the potential harm of surface defects into a benefit by using clean deposition techniques that create a defect-free interface, ensuring both ease of manufacture and high breakdown voltage performance

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Ease of manufacture

If mask layer removal is performed, then patterning is completed, but gate dielectric thickness is reduced

Engineering Contradiction:
Improvepatterning completionVSAvoidgate dielectric thickness
Core Design Contradiction:
Ease of manufactureVSLength of stationary object

Solution Approach 1:

The patent extracts the mask layer removal step entirely by using a deposition process that directly forms the gate dielectric layer with the desired thickness and pattern, eliminating the thickness reduction that occurs during conventional mask removal processes

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent performs the patterning action preliminarily through deposition techniques that directly create the final gate dielectric structure with correct thickness and pattern, avoiding subsequent removal steps that would reduce thickness

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed method increases the breakdown voltage and extends the lifetime of high-voltage transistors by improving device performance and production yield.

Implementation Method 1

depositing a first dielectric layer over the substrate; forming a patterned mask layer over the first dielectric layer; patterning the first dielectric layer into a first sublayer of a gate dielectric layer; converting at least part of the patterned mask layer into a second sublayer of the gate dielectric layer

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Data Source

PatentUS12520521B2Method of forming high voltage transistor and structure resulting therefrom
Publication Date: 2026.01.06 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US12520521B2 patent drawing
  • US12520521B2 patent drawing
  • US12520521B2 patent drawing

AI summary

A method includes: forming a barrier layer in a substrate; depositing a first dielectric layer over the substrate; forming a patterned mask layer over the first dielectric layer; patterning the first dielectric layer into a first sublayer of a gate dielectric layer; converting at least part of the patterned mask layer into a second sublayer of the gate dielectric layer; depositing a second dielectric layer adjacent to the first and second sublayers to serve as a third sublayer of the gate dielectric layer; and depositing a gate electrode over the gate dielectric layer.