Gate Stack Cap Layer Diffusion for Threshold Voltage Control

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Solution Overview

Problem

The semiconductor industry faces challenges in manufacturing low-cost, high-performance, and low-power integrated circuits due to increased complexity from scaling down semiconductor IC dimensions, which affects the control of threshold voltage in transistors.

Innovation Solution

A method of forming a gate stack in semiconductor devices involves treating intermediate structures with silicon-containing or aluminum-containing gases in a non-plasma ambient at elevated temperatures to diffuse silicon or aluminum atoms into cap layers, preventing oxidation and controlling threshold voltage, thereby improving the electrical performance of transistors.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If silicon or aluminum atoms are diffused into cap layers using non-plasma gas treatment at elevated temperatures, then oxidation is prevented and threshold voltage control is improved, but manufacturing process complexity increases

Engineering Contradiction:
Improvethreshold voltage controlVSAvoidmanufacturing process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by treating the cap layer with silicon-containing or aluminum-containing gases at elevated temperatures (typically 200-450°C) in a non-plasma ambient. This thermal treatment diffuses silicon or aluminum atoms into the cap layer, modifying its compositional parameters to prevent oxidation and control threshold voltage without requiring plasma processing

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses silicon-containing gases (such as silane) or aluminum-containing gases as intermediary substances to deliver silicon or aluminum atoms to the cap layer. These gas-phase intermediaries enable atomic diffusion into the cap layer structure, achieving oxidation prevention and threshold voltage control through a non-plasma intermediary process

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If scaling down semiconductor IC dimensions is continued to improve production efficiency and lower costs, then production efficiency increases and costs decrease, but process complexity increases

Engineering Contradiction:
Improveproduction efficiencyVSAvoidprocess complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent replaces plasma-based processing (a complex mechanical/physical system requiring vacuum chambers, RF power sources, and plasma generation equipment) with a non-plasma gas treatment process. This substitution uses simpler thermal diffusion in a non-plasma ambient, reducing equipment complexity and process steps while maintaining effectiveness at scaled dimensions

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent extracts the essential function of plasma treatment (atom diffusion into the cap layer) and separates it from the complex plasma generation mechanism. By using non-plasma gas treatment, the invention removes the need for plasma-related equipment and process controls, retaining only the essential atomic diffusion function at scaled dimensions

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the control of threshold voltage and prevents unwanted increases, leading to improved electrical performance and reduced complexity in transistor manufacturing.

Implementation Method 1

treating intermediate structures with silicon-containing or aluminum-containing gases in a non-plasma ambient at elevated temperatures to diffuse silicon or aluminum atoms into cap layers

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

preventing oxidation and controlling threshold voltage

Methodology Applied
Scientific EffectOxidation prevention: Oxidation

Data Source

PatentUS11855164B2Semiconductor device and fabrication method thereof
Publication Date: 2023.12.26 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US11855164B2 patent drawing
  • US11855164B2 patent drawing
  • US11855164B2 patent drawing

AI summary

A semiconductor device includes a substrate, a semiconductor fin extending from the substrate, a gate dielectric layer over the semiconductor fin, a metal nitride layer comprising a first portion over the gate dielectric layer and a second portion over the first portion, and a fill layer over the metal nitride layer. The second portion has an aluminum concentration greater than an aluminum concentration of the first portion.