3D Gate Stack Formation via Sacrificial Layer Etching

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Solution Overview

Problem

The challenge in semiconductor manufacturing is to increase the integration density of memory devices beyond the limits of planar structures, which requires innovative methods for forming gate structures in semiconductor devices.

Innovation Solution

A method involving the formation of alternately stacked mold insulating and sacrificial layers, crystallization of metal oxide films, and precise etching processes to create vertical structures and conductive layers, enabling the fabrication of advanced gate dielectric and electrode layers in semiconductor devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If planar structure scaling is continued to increase integration density, then manufacturing complexity and process defects increase beyond acceptable limits

Engineering Contradiction:
Improveintegration densityVSAvoidprocess defects
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The patent transitions from planar (2D) memory cell structures to three-dimensional (3D) stacked structures with vertical channel holes and gate electrodes. This dimensional change allows continued scaling and increased integration density without the manufacturing precision degradation that occurs when planar structures are scaled below certain dimensions.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Reliability

If amorphous metal oxide film is used as gate dielectric and crystallized through heat treatment, then dielectric quality improves but surface layer defects are generated

Engineering Contradiction:
Improvedielectric qualityVSAvoidsurface layer defects
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent extracts or removes the defective surface layer of the crystallized metal oxide film through selective etching processes. This eliminates the surface defects generated during crystallization while preserving the high-quality bulk dielectric layer, thus maintaining reliability without the harmful surface defects.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent employs controlled heat treatment parameters to crystallize the amorphous metal oxide film, followed by selective etching parameters that target only the surface layer. By optimizing these process parameters, the bulk dielectric achieves high crystallinity and quality while the surface defects are removed.

Inventive Principle:
Principle #35Parameter changes

3Shape

If vertical structures are formed through mold structures with sacrificial layers, then 3D gate structures are achieved but process complexity increases

Engineering Contradiction:
Improvevertical structureVSAvoidprocess complexity
Core Design Contradiction:
ShapeVSDevice complexity

Solution Approach 1:

The patent forms complete mold structures with alternately stacked mold insulating layers and sacrificial layers before forming the vertical channel holes. This preliminary structuring provides precise templates that guide the formation of vertical gates, simplifying the overall process despite the initial complexity of mold formation.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The sacrificial layers act as intermediaries during the formation process. They are deposited between the mold insulating layers to define the vertical channel holes, and are subsequently removed to create the final gate structure. This intermediary approach enables precise 3D structure formation through sequential processing steps.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces process defects and facilitates vertical scaling, enhancing the integration density and performance of semiconductor devices by forming efficient gate structures.

Implementation Method 1

crystallizing the metal oxide film

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Implementation Method 2

heat-treating the amorphous metal oxide film until the amorphous metal oxide film crystallizes

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Data Source

PatentUS10276589B2Method of manufacturing semiconductor device
Publication Date: 2019.04.30 SAMSUNG ELECTRONICS CO LTD
  • US10276589B2 patent drawing
  • US10276589B2 patent drawing
  • US10276589B2 patent drawing

AI summary

A method of manufacturing a semiconductor device includes forming a mold structure including alternately stacked mold insulating and sacrificial layers on a substrate, forming a vertical structure through the mold structure, forming side openings by removing the sacrificial, forming a preliminary dielectric layer in the side openings, forming a dielectric layer by heat-treating the preliminary dielectric layer, removing a surface layer of the dielectric layer, forming a first conductive layer covering the dielectric layer in the side openings, and forming a second conductive layer covering the first conductive layer and filling the side openings.