Gear Oil Composition Using Diglycerol Ester for Friction and Stability

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Solution Overview

Problem

Current gear oils face challenges with friction reduction, water entrainment, foaming, and thermal stability, particularly in industrial, automotive, and marine applications, where existing additives often fall short in providing sufficient performance.

Innovation Solution

A gear oil composition incorporating a diglycerol C12 to C24 saturated fatty ester as a friction-reducing additive, comprising at least 10 wt% monoester and 20 wt% diester, which significantly reduces the kinetic coefficient of friction and enhances stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If conventional friction reducing additives (esters, phosphonates, organomolybdenum compounds) are used in gear oils, then friction reduction is achieved, but water entrainment, foaming, and insufficient thermal stability occur

Engineering Contradiction:
ImprovefrictionVSAvoidthermal stability
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent changes the chemical structure parameters of the friction reducing additive by using diglycerol esters with specific chain lengths (C12-C24) and specific ester compositions (at least 10 wt% monoester and 20 wt% diester), which fundamentally alters the additive's interaction with water and its thermal decomposition behavior, thereby resolving the contradiction between friction reduction and thermal stability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention employs a composite ester structure where diglycerol forms both monoester and diester linkages with fatty acid chains, creating a multifunctional additive that simultaneously provides friction reduction, water demulsibility, and thermal stability that single-structure additives cannot achieve

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The gear oil composition effectively reduces friction by up to 40% and improves thermal stability, while minimizing water entrainment and foaming, making it suitable for demanding applications like wind turbines and heavy machinery.

Implementation Method 1

A gear oil composition incorporating a diglycerol C12 to C24 saturated fatty ester as a friction-reducing additive, which significantly reduces the kinetic coefficient of friction

Methodology Applied
Scientific EffectLubrication: Lubrication

Implementation Method 2

these materials can have drawbacks such as water entrainment/ emulsification and/or foaming

Methodology Applied
Scientific EffectSurfactant: Surfactant

Data Source

PatentEP3052598B1Gear oil composition
Publication Date: 2022.12.28 CARGILL BIOINDUSTRIAL UK LTD

AI summary

The present invention relates to a gear oil composition containing a base stock and at least 0.01 wt% of a friction reducing additive which comprises a glycerol and/or polyglycerol C12 to C24 saturated fatty ester. The gear oil composition is suitable for use in gear boxes in automotive, industrial and marine applications.