Gel-Forming Battery Electrolyte for High-Temperature Ignition Suppression

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Solution Overview

Problem

Rechargeable lithium batteries face issues with increased resistance, ignition, and explosion at high temperatures, which can lead to a cascade of ignition and explosion in battery modules or packs, posing a significant safety risk.

Innovation Solution

An electrolyte composition for rechargeable lithium batteries incorporating a non-aqueous organic solvent, a lithium salt, a first additive with an epoxy group that facilitates gelling at around 100°C, and a second nitrile-based additive that enhances gelling at higher temperatures, effectively increasing viscosity and reducing ionic conductivity to prevent ignition and explosion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional electrolytes are used in rechargeable lithium batteries, then good electrochemical performance is achieved, but the risk of ignition and explosion increases at high temperatures

Engineering Contradiction:
Improvesafety of battery cellVSAvoidignition and explosion risk
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent applies preliminary action by forming a protective gel layer on the electrode surfaces before thermal runaway can occur. The gel electrolyte containing epoxy and nitrile groups pre-establishes a stable interface that prevents subsequent ignition and explosion, addressing the safety issue before it arises rather than reacting to it after thermal runaway begins.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent converts the harmful thermal energy that would cause ignition into a beneficial gelation process. When temperature increases, the epoxy and nitrile groups undergo exothermic reactions that form a gel structure, which actually helps contain and stabilize the thermal energy rather than allowing it to propagate as explosion, thus converting a potentially harmful thermal event into a protective mechanism.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Reliability

If electrolyte viscosity is increased to suppress ignition, then safety is improved, but ionic conductivity decreases

Engineering Contradiction:
Improvesafety of battery cellVSAvoidionic conductivity
Core Design Contradiction:
ReliabilityVSPower

Solution Approach 1:

The patent applies local quality by creating different viscosity regions within the electrolyte system. The gel electrolyte forms a structured network with higher viscosity at the electrode interfaces where safety is most critical, while maintaining lower viscosity in the bulk electrolyte region to preserve ionic conductivity. This spatial differentiation of properties allows simultaneous optimization of both safety and power performance.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent utilizes parameter changes by incorporating temperature-responsive gelating agents that alter the electrolyte's physical state based on thermal conditions. At normal operating temperatures, the electrolyte maintains low viscosity for high ionic conductivity. When temperature rises during thermal runaway, the epoxy and nitrile groups undergo phase transition to form gel structures, increasing viscosity locally to suppress ignition while the overall system maintains sufficient ionic conductivity through the gel network.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The combined additives suppress or reduce the risk of ignition and explosion at high temperatures, preventing temperature increases even if ignition occurs in adjacent cells, thereby enhancing safety and stability of lithium battery cells.

Implementation Method 1

a first additive with an epoxy group that facilitates gelling at around 100°C

Methodology Applied
Scientific EffectGelling: Gel

Implementation Method 2

a second nitrile-based additive that enhances gelling at higher temperatures, effectively increasing viscosity

Methodology Applied
Scientific EffectGelling: Gel

Data Source

PatentUS20240413398A1Electrolyte for rechargeable lithium battery and rechargeable lithium battery including the same
Publication Date: 2024.12.12 SAMSUNG SDI CO LTD
  • US20240413398A1 patent drawing
  • US20240413398A1 patent drawing
  • US20240413398A1 patent drawing

AI summary

The present disclosure relates to an electrolyte for a rechargeable lithium battery and a rechargeable lithium battery including the same. According to the present embodiments, an electrolyte for a rechargeable lithium battery includes a non-aqueous organic solvent; a lithium salt; a first additive represented by Chemical Formula 1; and a second additive, being a nitrile-based additive: