Gelled Acid Matrix Stimulation for Permeability

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Solution Overview

Problem

Current matrix acidizing techniques for increasing permeability in subterranean formations rely primarily on chemical reactions with acids, lacking effective mechanical disruption methods to enhance fluid flow, which limits their efficiency in creating conductive channels.

Innovation Solution

Injecting a treatment fluid with a gelling agent selected from specific chemical formulas into a wellbore at pressures below fracturing pressure, forming voids and increasing viscosity to enhance acid penetration and self-diversion into the formation, thereby creating more effective fluid flow channels.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If matrix acidizing is used to increase permeability in low permeability formations, then chemical reactions occur between acid and formation, but mechanical disruption is insufficient to create effective conductive channels

Engineering Contradiction:
Improvepermeability increaseVSAvoidmechanical disruption capability
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent combines chemical acidizing with mechanical disruption by injecting gelled acid that undergoes in-situ gelation to provide mechanical force for creating conductive channels, merging the benefits of both chemical and mechanical stimulation methods

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent changes the physical state parameter of the acidizing fluid by using gelling agents that transform the fluid from liquid to gel state in-situ, enabling mechanical disruption capability while maintaining chemical reactivity

Inventive Principle:
Principle #35Parameter changes

2Productivity

If hydraulic fracturing is used to create fissures in the formation, then mechanical disruption and permeability increase are achieved, but proppants and complex equipment are required

Engineering Contradiction:
Improvepermeability increaseVSAvoidequipment and proppant requirements
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent extracts the essential mechanical disruption function from hydraulic fracturing by using in-situ gelation to provide mechanical force without requiring proppants or complex fracturing equipment, retaining only the necessary mechanical action

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent replaces the complex mechanical system of hydraulic fracturing (pumps, proppants, high-pressure equipment) with a chemical-based mechanical system where gelling agents provide mechanical disruption through in-situ gelation and expansion

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Reliability

If acidizing fluid is injected at pressure below breakdown pressure, then formation integrity is maintained, but permeability increase is limited without mechanical disruptions

Engineering Contradiction:
Improveformation integrityVSAvoidpermeability increase
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent changes the rheological parameters of the acidizing fluid in-situ by inducing gelation, which provides mechanical disruption capability at lower injection pressures while maintaining formation integrity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies preliminary action by injecting the gelled acid that undergoes in-situ gelation to prepare mechanical disruption before the acid reacts with the formation, enabling both integrity maintenance and permeability enhancement

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively increases permeability by creating conductive channels through both chemical reactions and mechanical disruptions, improving hydrocarbon flow without fracturing the formation, thus enhancing oil production.

Implementation Method 1

a treatment fluid having a first viscosity and including an aqueous acid and a gelling agent

Methodology Applied
Scientific EffectGelation: Gel

Implementation Method 2

increase in permeability is affected primarily by the chemical reaction of the acid within the formation

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS11708525B2Method of acidizing a subterranean formation comprising a gelling agent
Publication Date: 2023.07.25 SPECIALTY OPERATIONS FRANCE
  • US11708525B2 patent drawing
  • US11708525B2 patent drawing
  • US11708525B2 patent drawing

AI summary

Methods of acidizing a subterranean formation penetrated by a wellbore that include the steps of (a) injecting into the wellbore at a pressure below subterranean formation fracturing pressure a treatment fluid having a first viscosity and including an aqueous acid and a gelling agent selected from the group consisting of Formulas I-XI and combinations thereof; (b) forming at least one void in the subterranean formation with the treatment fluid; and (c) allowing the treatment fluid to attain a second viscosity that is greater than the first viscosity.