3D Geometric Catalysts for CO2 Electrolysis

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Solution Overview

Problem

Current methods for capturing and reducing CO2 levels are inefficient and do not effectively convert CO2 into usable materials, requiring significant energy and resources, and lack the capability to generate useful by-products like H2 and O2.

Innovation Solution

A catalytic system utilizing high-density glass interposers with vias and pillars to increase the active surface area, mimicking the capillary effect of plants, which facilitates the conversion of CO2 into CO, H2, and O2 through electrolysis, using materials like copper, palladium, and tin, and incorporating renewable energy sources.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional plate catalysts are used for CO2 conversion, then the device structure is simple, but the catalytic surface area is insufficient leading to low conversion efficiency

Engineering Contradiction:
ImproveCO2 conversion efficiencyVSAvoidcatalytic surface area
Core Design Contradiction:
ProductivityVSArea of stationary object

Solution Approach 1:

The patent transitions from conventional 2D plate catalysts to 3D geometric constructs including pillars, cones, pyramids, and dendritic structures. This dimensional transformation dramatically increases the catalytic surface area available for CO2 conversion while maintaining a compact device footprint, directly resolving the contradiction between conversion efficiency and surface area limitation.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Solution Approach 2:

The invention incorporates porous structures and high-surface-area geometric constructs that provide extensive catalytic interfaces within a limited volume. These porous and multi-faceted structures enable significantly higher CO2 contact area compared to dense plate catalysts, thereby improving conversion efficiency without proportionally increasing device size.

Inventive Principle:
Principle #31Porous materials

2Productivity

If high surface area catalysts are implemented, then CO2 conversion efficiency improves, but the device complexity and manufacturing difficulty increase

Engineering Contradiction:
ImproveCO2 conversion efficiencyVSAvoidgeometric construct complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The complex 3D catalytic structures are segmented into standardized geometric units (pillars, cones, pyramids, dendritic branches) that can be independently fabricated and then assembled. This segmentation approach allows for modular manufacturing, reducing overall device complexity while maintaining the high surface area benefits of three-dimensional structures.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The geometric constructs are designed to serve multiple functions: providing catalytic surface area, facilitating mass transport, and enabling structural support. This multi-functionality reduces the need for separate components, thereby managing device complexity while achieving high CO2 conversion efficiency through integrated design.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Loss of energy

If conventional electrolysis systems are used, then the system structure is simple, but energy consumption is high and useful by-products are not effectively generated

Engineering Contradiction:
Improveenergy input requirementVSAvoiduseful by-product generation
Core Design Contradiction:
Loss of energyVSProductivity

Solution Approach 1:

The patent modifies key electrolysis parameters including using advanced catalyst materials, optimizing geometric construct dimensions, and adjusting operational conditions to reduce overpotential. These parameter changes lower the energy input requirement while simultaneously enhancing the selectivity and productivity for useful by-products such as carbon monoxide, formate, and hydrogen.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The system converts the harmful CO2 byproduct into valuable resources including syngas (CO), hydrogen, and other chemical feedstocks. This transformation approach turns the energy-consuming CO2 reduction process into a beneficial resource generation system, addressing both energy efficiency and productive output simultaneously.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system achieves efficient CO2 sequestration and conversion into valuable products with reduced energy input, increasing the catalytic surface area by up to 1400% and enabling the generation of renewable fuels and energy with minimal power requirements.

Implementation Method 1

An anode generates oxygen

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Implementation Method 2

a CO2 cathode generating hydrogen and a CO precursor from the carrier medium

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Implementation Method 3

A capillary action is produced for CO2 sequestration across the catalytic cathode surface

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Data Source

PatentUS11466374B1CO2 capture and sequestration system utilizing high density geometric constructs
Publication Date: 2022.10.11 CEC SOLUTIONS LLC
  • US11466374B1 patent drawing
  • US11466374B1 patent drawing
  • US11466374B1 patent drawing

AI summary

A catalytic system for CO2 capture and sequestration. The system includes a reduction cell for separating a carrier medium having an anode generating oxygen, a cathode generating hydrogen, and a CO precursor from the carrier medium. In addition, the system includes a power supply for providing electrical power to the anode and the cathode. An electrolysis process occurs where oxygen, hydrogen, CO precursors are produced. The anode and the cathode include a plurality of geometrical constructs to increase an active surface area of a catalytic surface of the anode and cathode to increase an efficiency of the electrolysis process. The geometrical constructs may include vias and pillars. In one embodiment, a capillary action is produced for CO2 sequestration across the catalytic surface having a plurality of vias.