Germane Argon Plasma Ion Source Productivity

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Solution Overview

Problem

The formation of germanium and argon ion beams with sufficient beam current without the use of halogen gases has been challenging in semiconductor device manufacturing, particularly in ion implantation processes.

Innovation Solution

Introducing germane and argon into an ion source to form a plasma, allowing for the generation of germanium and argon ion beams with improved beam current, where the flow rates of argon and germane are optimized to enhance ionization efficiency, and no halogen gases are used.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of stationary object

If germane is used as the main dopant gas without halogen gases, then the ion source life is extended, but the beam current of germanium ion beam is insufficient

Engineering Contradiction:
Improveion source lifeVSAvoidbeam current
Core Design Contradiction:
Duration of action of stationary objectVSProductivity

Solution Approach 1:

The patent introduces argon gas as an intermediary substance to mediate between germane and the ion source. The argon gas facilitates the ionization process and enhances beam current extraction without requiring halogen gases, thus extending ion source life while maintaining productivity. The argon acts as a carrier gas that improves the efficiency of germanium ion beam formation from germane.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If argon is used as the main gas for ion beam generation, then the beam current of argon ion beam is improved, but the ionization efficiency decreases without proper second gas addition

Engineering Contradiction:
Improvebeam currentVSAvoidionization efficiency
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent optimizes the flow rate parameters of both argon and germane gases to achieve optimal ionization efficiency. By carefully controlling the ratio and absolute flow rates of these gases, the system maximizes the ionization of argon while using germane to enhance the overall plasma density and beam current extraction efficiency.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If traditional GeF4 is used as dopant gas, then sufficient beam current is achieved, but halogen-induced etching reduces ion source life

Engineering Contradiction:
Improvebeam currentVSAvoidion source life
Core Design Contradiction:
ProductivityVSDuration of action of stationary object

Solution Approach 1:

The patent creates an inert atmospheric environment within the ion source by using germane and argon gases instead of halogen-containing gases like GeF4. This inert environment prevents halogen-induced etching of the ion source components, thereby extending ion source life while maintaining sufficient beam current through optimized gas flow parameters and plasma generation.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method increases the beam current of both germanium and argon ion beams, improving the efficiency of the ion source and extending the life of the ion source by eliminating halogen-induced etching, while being potentially less expensive than traditional methods.

Implementation Method 1

ionizing the germane and argon to form a plasma

Methodology Applied
Scientific EffectIonization: Ionisation

Implementation Method 2

ionizing the germane and argon to form a plasma

Methodology Applied
Scientific EffectPlasma: Plasma

Data Source

PatentUS11450504B2GeH<sub>4</sub>/Ar plasma chemistry for ion implant productivity enhancement
Publication Date: 2022.09.20 APPLIED MATERIALS INC
  • US11450504B2 patent drawing
  • US11450504B2 patent drawing
  • US11450504B2 patent drawing

AI summary

A method for improving the beam current for certain ion beams, and particularly germanium and argon, is disclosed. The use of argon as a second gas has been shown to improve the ionization of germane, allowing the formation of a germanium ion beam of sufficient beam current without the use of a halogen. Additionally, the use of germane as a second gas has been shown to improve the beam current of an argon ion beam.