Amine-Based Germanium Compound for OLED Charge Injection

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Solution Overview

Problem

Current organic light-emitting devices face limitations in achieving high efficiency and stability due to challenges in hole mobility and exciton diffusion, particularly in the use of silicon-based compounds as electron or hole injectors.

Innovation Solution

An amine-based compound represented by Formula 1, which includes a germanium atom, is introduced to facilitate faster electron or hole injection and reduce mobility disturbances, enhancing the efficiency of organic light-emitting devices by forming an organic layer between electrodes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If silicon-based compounds are used as electron or hole injectors, then device structure can be simplified, but hole mobility and exciton diffusion are limited reducing efficiency

Engineering Contradiction:
Improvedevice structureVSAvoidinjection efficiency
Core Design Contradiction:
Device complexityVSProductivity

Solution Approach 1:

The patent changes the chemical composition parameter by replacing silicon-based compounds with amine-based compounds containing germanium atoms. This parameter change enables faster electron or hole injection and reduces mobility disturbances, resolving the contradiction between structural simplicity and injection efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material design by creating amine-based compounds with specific germanium atom incorporation and defined molecular structures (Formula 1). These composite materials achieve both structural organization and enhanced charge injection properties, overcoming the limitations of conventional silicon-based compounds

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If conventional organic materials are used in emission layer, then manufacturing process is established, but efficiency and stability are limited

Engineering Contradiction:
Improvemanufacturing processVSAvoiddevice stability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent modifies the chemical composition parameters of the organic layer by incorporating amine-based compounds with germanium atoms in specific molecular configurations (Formula 1). This parameter change enhances device efficiency and stability while maintaining compatibility with established manufacturing processes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The amine-based compound with germanium atom serves as an intermediary material between conventional organic materials and electrodes. It facilitates improved charge injection and transport while maintaining processability, acting as a bridge that enhances performance without requiring complete process redesign

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The amine-based compound with a germanium atom improves the efficiency of organic light-emitting devices by facilitating high-speed electron or hole injection and reducing hole mobility disturbances, leading to enhanced performance and stability.

Implementation Method 1

An amine-based compound represented by Formula 1, which includes a germanium atom, is introduced to facilitate faster electron or hole injection

Methodology Applied
Scientific EffectCharge carrier injection: Conduction (electrical)

Implementation Method 2

The holes and the electrons may be recombined in the emission layer to produce excitons. These excitons may change from an excited state to a ground state, thereby generating light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS10519174B2Amine-based compound and organic light-emitting device including the same
Publication Date: 2019.12.31 SAMSUNG DISPLAY CO LTD
  • US10519174B2 patent drawing
  • US10519174B2 patent drawing
  • US10519174B2 patent drawing

AI summary

An amine-based compound and an organic light-emitting device including the same, the amine-based compound being represented by Formula 1, below: