Germanium-on-Insulator Substrate Fabrication via Layer Segmentation

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Solution Overview

Problem

The integration of germanium (Ge) on silicon (Si) substrates for high-performance photo-detectors is hindered by low thermal budget constraints, lattice mismatch, and high defect densities, leading to degraded electrical and optical properties due to unintentional doping and misfit dislocations.

Innovation Solution

A method involving doping a germanium layer with different dopants to form electrodes, bonding with a dielectric material, and removing defective layers to create a high-quality germanium-on-insulator substrate, which reduces misfit dislocations and improves the purity and quality of the germanium structure for p-i-n Ge photo-detectors.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If germanium is integrated on silicon substrates for photo-detectors, then absorption coefficient in telecommunication wavelength is improved, but misfit dislocations and defect densities increase due to lattice mismatch

Engineering Contradiction:
Improveabsorption coefficientVSAvoidmisfit dislocations
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The germanium layer is segmented into multiple thin layers (first germanium layer, second germanium layer, third germanium layer) with an intrinsic germanium layer in between. This segmentation reduces the thickness of each individual germanium layer on the silicon substrate, thereby reducing misfit dislocations while maintaining the overall absorption coefficient for telecommunication wavelengths.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

An intrinsic germanium layer is introduced as an intermediary between the silicon substrate and the doped germanium layers. This intrinsic layer acts as a buffer that reduces the direct lattice mismatch between silicon and doped germanium, minimizing misfit dislocations and defect densities while allowing the doped layers to maintain their photo-detection functionality.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If doping is performed to form p-i-n structure, then photo-detector functionality is improved, but unintentional doping occurs due to dopant diffusion, degrading electrical and optical properties

Engineering Contradiction:
Improvephoto-detector functionalityVSAvoidelectrical and optical properties
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The doped regions are segmented into separate first and third germanium layers, with an undoped intrinsic germanium layer in between. This spatial segmentation prevents dopant diffusion from contaminating the intrinsic region, maintaining the electrical and optical properties necessary for photo-detector functionality while still enabling p-i-n structure formation.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The intrinsic germanium layer serves as a physical barrier and intermediary that prevents dopant diffusion between the p-type and n-type doped regions. This intermediary layer maintains the integrity of the intrinsic region, preventing unintentional doping that would otherwise degrade the electrical and optical properties of the photo-detector.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If thermal processing is applied to reduce defects, then misfit dislocations are reduced, but thermal budget constraints are violated, limiting CMOS integration

Engineering Contradiction:
Improvedefect densityVSAvoidthermal budget
Core Design Contradiction:
Manufacturing precisionVSTemperature

Solution Approach 1:

The germanium layers are grown with controlled thicknesses and structures that pre-minimize misfit dislocations before any thermal processing. By segmenting the germanium layers and using an intrinsic buffer layer, the structure is designed to reduce defects inherently, allowing subsequent low-temperature processing that respects CMOS thermal budget constraints.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The thickness parameters of individual germanium layers are optimized to be below the critical thickness for misfit dislocation formation. By changing the thickness parameter of each layer rather than using a single thick layer, the structure achieves low defect density without requiring high-temperature thermal processing, thus maintaining compatibility with CMOS thermal budget constraints.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the fabrication of high-quality germanium-on-insulator substrates that significantly reduce dark current in p-i-n Ge photo-detectors, enhancing their performance and integration in CMOS environments.

Implementation Method 1

doping a first portion of a germanium layer with a first dopant to form a first electrode

Methodology Applied
Scientific EffectDoping: Dopants

Implementation Method 2

doping the third portion of the germanium layer with a second dopant to form a second electrode

Methodology Applied
Scientific EffectDoping: Dopants

Implementation Method 3

bonding a second semiconductor substrate to the layer of dielectric material

Methodology Applied
Scientific EffectBonding: Chemical Bonding

Data Source

PatentUS10418273B2Method of manufacturing a germanium-on-insulator substrate
Publication Date: 2019.09.17 NANYANG TECH UNIV
  • US10418273B2 patent drawing
  • US10418273B2 patent drawing
  • US10418273B2 patent drawing

AI summary

A method of manufacturing a germanium-on-insulator substrate is disclosed, comprising: (i) doping a first portion of a germanium layer with a first dopant to form a first electrode, the germanium layer arranged with a first semiconductor substrate; (ii) forming at least one layer of dielectric material adjacent to the first electrode to obtain a combined substrate; (iii) bonding a second semiconductor substrate to the layer of dielectric material and removing the first semiconductor substrate from the combined substrate to expose a second portion of the germanium layer with misfit dislocations; (iv) removing the second portion of the germanium layer to enable removal of the misfit dislocations and to expose a third portion of the germanium layer; and (v) doping the third portion of the germanium layer with a second dopant to form a second electrode. The electrodes are separated from each other by the germanium layer, and the first dopant is different to the second dopant.