Germanium Polymer High Refractive Index Film

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Solution Overview

Problem

Current high refractive-index polymers and films face limitations such as toxicity, corrosive gas generation, refractive index caps at 1.7, difficulty in controlling film thickness, and high production costs, especially when using silicon or germanium semiconductors.

Innovation Solution

A high refractive-index composition comprising a polymer with germanium (Ge) elements in the main chain and reactive groups as side chains, allowing for a simple coating process to produce films with uniform thickness, high chemical stability, and controlled physical properties like transparency and heat resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If halogen elements are used in high refractive-index polymers, then refractive index is improved, but toxicity and corrosive gas generation increase

Engineering Contradiction:
Improverefractive indexVSAvoidtoxicity and corrosive gas generation
Core Design Contradiction:
Illumination intensityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters by replacing halogen elements with germanium elements in the polymer structure. This substitution maintains the high refractive index property (achieving 1.8 or higher) while eliminating the harmful effects of toxicity and corrosive gas generation associated with halogen-containing polymers.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops composite polymer materials containing germanium elements in the main chain or side chains. These composite materials achieve high refractive indices through the germanium content while maintaining chemical stability and avoiding the harmful properties of traditional halogen-based high refractive index polymers.

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If metal oxide particles are put inside polymer matrix to increase refractive index, then refractive index is improved, but film uniformity and thickness control become difficult

Engineering Contradiction:
Improverefractive indexVSAvoidfilm thickness control and uniformity
Core Design Contradiction:
Illumination intensityVSManufacturing precision

Solution Approach 1:

The patent changes the approach from using dispersed metal oxide particles to incorporating germanium elements directly into the polymer molecular structure. This fundamental parameter change allows for uniform distribution of refractive index enhancement throughout the polymer matrix, enabling precise control of film thickness and uniformity without the limitations imposed by particle-based approaches.

Inventive Principle:
Principle #35Parameter changes

3Illumination intensity

If inorganic particles are used to form thin films, then refractive index is improved, but film formation difficulty and molding ease worsen

Engineering Contradiction:
Improverefractive indexVSAvoidfilm formation and molding ease
Core Design Contradiction:
Illumination intensityVSEase of manufacture

Solution Approach 1:

The patent transitions from using inorganic particles to using organic polymer materials containing germanium elements. This parameter change enables the material to be processed using conventional polymer processing techniques, significantly improving ease of film formation and molding while maintaining the desired high refractive index properties.

Inventive Principle:
Principle #35Parameter changes

4Illumination intensity

If Ge-containing organic compounds are used, then refractive index is improved, but refractive index limit remains at 1.8 or less

Engineering Contradiction:
Improverefractive indexVSAvoidrefractive index range
Core Design Contradiction:
Illumination intensityVSAdaptability or versatility

Solution Approach 1:

The patent systematically varies the germanium content and structural configuration in the polymer to achieve refractive indices of 1.8 or higher. By controlling parameters such as germanium substitution ratio, polymer architecture, and side chain composition, the patent overcomes the previous 1.8 refractive index limit while maintaining chemical stability and processability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables the production of high refractive-index films with refractive indices above 1.8, offering easy thickness control and cost-effective manufacturing, while ensuring chemical stability and improved physical properties.

Implementation Method 1

a polymer including a polymerized unit containing a germanium (Ge) element as a main chain and at least two or more reactive groups as a side chain

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Data Source

PatentUS11866584B2High-refractive-index composition, high-refractive-index film, and method for manufacturing high-refractive-index film
Publication Date: 2024.01.09 LG CHEM LTD
  • US11866584B2 patent drawing
  • US11866584B2 patent drawing
  • US11866584B2 patent drawing

AI summary

The present application relates to a high refractive-index composition, a high refractive-index film and a method for producing a high refractive-index film. The present application provides a composition that a high refractive-index film can be produced with a simple coating process and low cost, and a high refractive-index film having a uniform thickness and easy thickness control or molding, as well as having high chemical stability and easy control of physical properties such as transparency or heat resistance, can be produced, a high refractive-index film using the same and a method for producing a high refractive-index film.