Getter Surface Preparation Using Caustic Fluids

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Solution Overview

Problem

The efficient integration of getter materials into the manufacturing process of Microelectromechanical Systems (MEMS) is challenging due to compatibility issues with subsequent manufacturing steps, chemical reactivity, and the need for complex and costly protection methods, which lead to ineffective gas sorption and increased manufacturing complexity.

Innovation Solution

Chemical treatments with caustic fluids, such as acidic or basic solutions, are used to enhance the properties and activation of getter materials without isolating them, allowing for improved gas sorption capabilities while maintaining structural integrity, and eliminating the need for temporary protective layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If getter materials are integrated into MEMS manufacturing process, then gas sorption capability is improved, but compatibility issues with subsequent manufacturing steps and chemical reactivity cause deterioration of manufacturing complexity and reliability

Engineering Contradiction:
Improvegas sorption capabilityVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The getter material is deposited on the support substrate before subsequent manufacturing steps, and temporary protective layers are applied in advance to protect the getter from chemical attacks during bonding and other processes. This preliminary protection enables the getter to maintain its gas sorption capability while surviving the manufacturing process.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

Temporary protective layers act as intermediary barriers between the getter material and harsh chemical environments during manufacturing. These protective layers prevent direct contact between caustic chemicals and the getter, allowing the getter to retain its structural integrity and gas sorption properties through subsequent processing steps.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If temporary protective layers are used to protect getter materials, then chemical reactivity damage is reduced, but manufacturing complexity and cost increase

Engineering Contradiction:
Improvestructural integrityVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

Temporary protective layers are applied to protect the getter material during critical manufacturing steps, then deliberately removed or discarded after serving their protective function. This approach allows the getter to survive harsh processing conditions without requiring permanent protective structures, thereby reducing overall device complexity.

Inventive Principle:
Principle #34Discarding and recovering

3Manufacturing precision

If getter materials are exposed to caustic chemicals during support treatment, then support cleaning is improved, but getter material structural integrity deteriorates

Engineering Contradiction:
Improvesupport cleaning qualityVSAvoidgetter material structural integrity
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

Temporary protective layers serve as intermediary barriers that prevent direct contact between caustic cleaning chemicals and the getter material. This allows the support substrate to be thoroughly cleaned while the getter material remains protected, maintaining both cleaning quality and getter integrity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

Different regions of the substrate are treated differently - the support substrate receives aggressive caustic cleaning to remove contaminants, while the getter material regions are protected by temporary layers. This localized differential treatment enables thorough cleaning without damaging the getter material.

Inventive Principle:
Principle #3Local quality

4Reliability

If getter materials are protected during manufacturing, then gas sorption effectiveness is maintained, but manufacturing cost increases

Engineering Contradiction:
Improvegas sorption effectivenessVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

Inexpensive temporary protective layers are applied to protect the getter material during manufacturing, then discarded after serving their protective purpose. These cheap, disposable protective layers prevent damage to the expensive getter material, reducing overall manufacturing costs while maintaining gas sorption effectiveness.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the gas sorption capabilities of getter materials, reduces manufacturing complexity, and extends their effectiveness as process getters during high-temperature operations, resulting in more reliable and cost-effective MEMS production.

Implementation Method 1

treating the support having the deposit of the non-evaporable getter material with a caustic solution

Methodology Applied
Scientific EffectChemical cleaning:

Implementation Method 2

treating the getter material with a fluid to remove contaminants

Methodology Applied
Scientific EffectChemical activation:

Implementation Method 3

getter materials have been used to selectively sorb gasses

Methodology Applied
Scientific EffectGas sorption: Sorption

Implementation Method 4

getter materials are capable of reversibly sorbing hydrogen and substantially irreversibly sorbing gasses

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS7871660B2Preparation of getter surfaces using caustic chemicals
Publication Date: 2011.01.18 SAES GETTERS SPA
  • US7871660B2 patent drawing
  • US7871660B2 patent drawing
  • US7871660B2 patent drawing

AI summary

A technique for manufacturing a device that includes a deposit of getter material on a support involves treating the support on which the getter material is formed with a caustic fluid. An aspect of the technique is that it may clean and/or chemically activate the getter material without substantial damage to the getter material. The getter material may be formed on an internal wall of the device.