Graphene Field Effect Transistor Gas Sensor for Low Concentration Detection

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Solution Overview

Problem

Current methods for detecting gas components at extremely low concentrations, such as parts per billion (ppb) or parts per trillion (ppt), are limited by the need for large, expensive equipment and struggle with accuracy due to interference from impurities and device-specific variations, making it difficult to achieve real-time, portable, and selective detection.

Innovation Solution

A molecular detection apparatus that includes a collection unit, a concentration adjusting unit to generate multiple gas samples with varying concentrations, and a detection unit with multiple cells using graphene field effect transistors (GFETs) and organic probes to output detection signals based on concentration changes, allowing for the discrimination of target molecules despite impurities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If large equipment such as gas chromatography or mass spectrometer is used to detect gas components at extremely low concentrations, then detection sensitivity is improved, but device weight and volume increase significantly

Engineering Contradiction:
Improvedetection sensitivityVSAvoiddevice weight
Core Design Contradiction:
Measurement precisionVSWeight of moving object

Solution Approach 1:

The patent divides the detection system into multiple independent detection units, each equipped with a detection element having a conductive layer with specific surface modifications. This segmentation allows the system to achieve high detection sensitivity through multiple parallel detection channels while keeping each unit compact and lightweight, avoiding the need for a single large complex instrument.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent replaces traditional mechanical separation systems (gas chromatography) and large mass spectrometers with electrochemical detection elements that use surface-modified conductive layers. These detection elements directly interact with target gas molecules through selective adsorption and electrochemical reactions, eliminating the need for complex mechanical separation apparatus and reducing overall device size and weight.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Measurement precision

If traditional detection elements with surface-modified conductive layers are used, then detection capability is improved, but detection accuracy deteriorates due to interference from impurities and device variations

Engineering Contradiction:
Improvedetection capabilityVSAvoiddetection accuracy
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent employs multiple detection units with different surface modifications, each targeting specific gas components. By segmenting the detection function across multiple specialized sensors, the system can distinguish target gases from impurities based on their respective detection patterns, thereby improving detection accuracy despite the presence of interfering substances.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent changes the surface modification parameters of the conductive layers in different detection units to create selective responses to different gas molecules. By varying surface chemistry parameters (different organic substances for different targets), the system achieves selective detection capability that distinguishes target gases from impurities, improving reliability.

Inventive Principle:
Principle #35Parameter changes

3Speed

If gas obtained from air is directly introduced into the detection unit, then detection speed is improved, but detection accuracy deteriorates due to impurity interference and single-point concentration measurement

Engineering Contradiction:
Improvedetection speedVSAvoiddetection accuracy
Core Design Contradiction:
SpeedVSMeasurement precision

Solution Approach 1:

The patent segments the gas sample into multiple parallel detection channels, each with specialized detection elements. This allows simultaneous detection of multiple gas components in real-time without sequential processing, maintaining fast detection speed while improving accuracy through multi-parameter measurement that can distinguish target gases from impurities.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent uses multiple detection units exceeding the minimum single detection point, creating redundant measurement channels. This excessive action provides multiple data points for cross-validation and pattern recognition, enabling accurate identification of target gases even in complex mixtures, thereby improving detection accuracy without sacrificing speed.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables highly sensitive and selective detection of gas components at extremely low concentrations, improving accuracy and portability, and reducing the size of the detection apparatus, suitable for use in disaster or terrorism sites.

Implementation Method 1

a surface of a carbon nanostructure is surface modified with an organic substance or the like that selectively reacts with or adsorbs a specific substance

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

graphene field effect transistors (GFETs) and organic probes to output detection signals based on concentration changes

Methodology Applied
Scientific EffectField effect transistor sensing:

Data Source

PatentUS11353434B2Molecular detection apparatus and molecular detection method
Publication Date: 2022.06.07 KK TOSHIBA
  • US11353434B2 patent drawing
  • US11353434B2 patent drawing
  • US11353434B2 patent drawing

AI summary

A molecular detection apparatus according to a embodiment includes: a collection unit which collects detection target gases each containing molecule to be detected; a concentration adjusting unit which dilutes and/or concentrates the molecule, and generates a plurality of detection target gases having different concentrations of the molecule; a detection unit to which the plurality of detection target gases are sequentially introduced, and which includes a plurality of detection cells each outputting detection signals based on the concentrations of the molecule in the plurality of detection target gases; and a discrimination unit which discriminates the molecule by change tendencies of the detection signals based on the concentrations of the molecule.