Hollow Glass Microsphere Polymer Composite With Stronger Interfacial Bonding

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Solution Overview

Problem

Current composite materials made with polymers and inorganic particles lack tunable density, low toxicity, and enhanced mechanical and physical properties, particularly in terms of elasticity and pliability, and do not effectively achieve true composite properties due to limited van der Waals interactions between the particulate and polymer.

Innovation Solution

A composite material is developed by combining hollow glass microspheres with a polymer, where the particle size distribution, molecular weight, and processing conditions are optimized to create a unique van der Waals bonding, enhancing the composite's density, surface characteristics, and viscoelastic properties, using interfacial modifiers to promote close association between the polymer and particulate.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If hollow glass microspheres are combined with polymer to reduce density, then density is reduced and toxicity is lowered, but mechanical properties such as strength and stiffness deteriorate

Engineering Contradiction:
ImprovedensityVSAvoidmechanical strength
Core Design Contradiction:
Quantity of substanceVSStrength

Solution Approach 1:

The patent creates a true composite material by combining hollow glass microspheres with polymer through optimized van der Waals interactions. The specific particle size distribution (0.5-5 μm) and interfacial modifiers create strong interfacial bonding that allows the composite to achieve both reduced density and maintained mechanical strength, resolving the contradiction between lightweighting and strength retention

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent systematically optimizes multiple parameters including particle size (0.5-5 μm range), particle size distribution, polymer molecular weight, and interfacial modifier concentration to achieve the optimal balance between density reduction and mechanical property retention. This multi-parameter optimization enables the composite to simultaneously achieve low density and high strength

Inventive Principle:
Principle #35Parameter changes

2Strength

If inorganic particles are added to polymer composite, then density and mechanical properties improve, but van der Waals interactions remain limited and true composite properties are not achieved

Engineering Contradiction:
Improvemechanical propertiesVSAvoidvan der Waals interactions
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent introduces interfacial modifiers as intermediary substances that enhance van der Waals interactions between hollow glass microspheres and polymer matrix. These modifiers create optimized interfacial bonding that transforms the weak physical adsorption into strong composite bonding, achieving true composite properties with reliable interfacial strength

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent optimizes the particle size parameter to 0.5-5 μm range, which maximizes the surface area to volume ratio and enhances van der Waals interactions. This parameter optimization, combined with interfacial modifiers, creates strong interfacial bonding and achieves true composite properties

Inventive Principle:
Principle #35Parameter changes

3Area of stationary object

If particle size is reduced to enhance surface characteristics, then surface area increases and surface characteristics improve, but particle strength decreases and processing difficulty increases

Engineering Contradiction:
Improvesurface areaVSAvoidprocessing difficulty
Core Design Contradiction:
Area of stationary objectVSEase of manufacture

Solution Approach 1:

The patent optimizes particle size to the 0.5-5 μm range, which provides sufficient surface area for enhanced surface characteristics while maintaining adequate particle strength for processing. This specific parameter range balances surface area maximization with processing feasibility, avoiding the pitfalls of both larger and smaller particle sizes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses interfacial modifiers as intermediaries that facilitate the handling and processing of fine hollow glass microsphere particles. These modifiers improve particle-polymer compatibility and reduce processing difficulties associated with small particle sizes, enabling effective manufacturing

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting composite exhibits improved density, reduced toxicity, increased malleability, and enhanced viscoelastic properties, including tensile modulus and elongation, while maintaining electrical and magnetic resistance, and is suitable for various applications such as tire components and structural members.

Implementation Method 1

create a unique van der Waals bonding, enhancing the composite's density, surface characteristics, and viscoelastic properties

Methodology Applied
Scientific Effectvan der Waals bonding: Van der Waals Force

Data Source

PatentUS11767409B2Reduced density hollow glass microsphere polymer composite
Publication Date: 2023.09.26 MORGAN FRED
  • US11767409B2 patent drawing
  • US11767409B2 patent drawing
  • US11767409B2 patent drawing

AI summary

The invention relates to a hollow glass microsphere and polymer composite having enhanced viscoelastic and rheological properties.