Chemically Strengthened Glass Substrate with Low Potassium Ion Concentration

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional glass substrates for mobile terminal devices, such as cellular phones, face challenges in achieving high strength while maintaining a thin form factor due to the limitations of acrylic resin protective plates and existing glass strengthening methods, which often result in increased thickness and susceptibility to bending.

Innovation Solution

A chemically strengthened glass substrate with a compressive stress layer having a potassium ion concentration of 500 ppm or less, formed through an ion exchange process using molten salt, and subsequent removal of the ion exchange layer to prevent tensile stress formation, is developed. This process enhances the glass substrate's strength and allows for a thinner, more robust design.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a chemically strengthened glass substrate with a compressive stress layer is used, then the strength of the glass substrate is enhanced, but the standard deviation in breaking loads increases due to tensile stress formation

Engineering Contradiction:
Improvebreaking strengthVSAvoidstandard deviation in breaking loads
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent removes the ion exchange layer from the surface of the chemically strengthened glass substrate. This extraction eliminates the source of tensile stress that causes high standard deviation in breaking loads, while preserving the compressive stress layer beneath that provides high strength.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent creates a non-uniform ion concentration distribution where the surface layer has low potassium ion concentration (after removal) and the subsurface layer maintains high potassium ion concentration. This local differentiation allows the surface to be free of tensile stress while the subsurface provides compressive stress reinforcement.

Inventive Principle:
Principle #3Local quality

2Strength

If the mobile terminal device is designed with a wide distance between the protective plate and the display, then the acrylic resin protective plate can accommodate bending deflection, but the device thickness increases

Engineering Contradiction:
Improveresistance to bendingVSAvoiddevice thickness
Core Design Contradiction:
StrengthVSLength of stationary object

Solution Approach 1:

The patent changes the material parameters of the protective plate from acrylic resin to chemically strengthened glass with specific ion concentration distribution. This material transformation enables the plate to resist bending forces while maintaining a thin profile, eliminating the need for large spacing.

Inventive Principle:
Principle #35Parameter changes

3Length of stationary object

If a thin glass substrate is used, then the device can be thinned, but the glass substrate lacks sufficient strength to receive great external stress

Engineering Contradiction:
Improvesubstrate thicknessVSAvoidstrength to external stress
Core Design Contradiction:
Length of stationary objectVSStrength

Solution Approach 1:

The patent creates a composite structure within the glass substrate through chemical strengthening, forming a compressive stress layer beneath the surface. This internal composite structure provides high strength to thin substrates, enabling them to withstand great external stress despite minimal thickness.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves a glass substrate with significantly higher breaking strength and reduced standard deviation in breaking loads, even when formed in a thin shape, effectively addressing the need for high-strength, lightweight cover glasses for mobile terminal devices.

Implementation Method 1

chemically strengthening the glass substrate by immersing the glass substrate in heated molten salt such that ions of the glass substrate are ion-exchanged for ions of the molten salt

Methodology Applied
Scientific EffectIon exchange: Ion Exchange

Implementation Method 2

removing an ion exchange layer formed in an uppermost surface layer of a primary surface of the glass substrate in the step of chemically strengthening the glass substrate

Methodology Applied
Scientific EffectEtching: Ablation

Data Source

PatentEP2202208B1Glass substrate and method for manufacturing the same
Publication Date: 2017.06.21 HOYA CORPORATION
  • EP2202208B1 patent drawingFigure 1A~1B
  • EP2202208B1 patent drawingFigure 1C
  • EP2202208B1 patent drawingFigure 2

AI summary

A glass substrate chemically strengthened (1), includes a primary surface that has a compressive stress layer (1a) formed in an uppermost surface layer thereof. The compressive stress layer is configured to enhance strength of the glass substrate due to a compressive stress generated in the compressive stress layer. The compressive layer consists of a layer of a potassium ion concentration equal to or less than 5000 parts per million (ppm).