Glassy Solid-State Electrode Assembly for High Energy Density

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Solution Overview

Problem

Current solid-state battery technologies face limitations in achieving high power output, reduced charging time, and improved cycle life, particularly in terms of energy density and ion conductivity.

Innovation Solution

The development of a glassy embedded solid-state electrode assembly with a composite material structure comprising a porous electroactive network and a continuous Li ion conductive glassy sulfide medium, which provides a robust, stable, and ion-transparent interface for lithium solid-state battery cells, minimizing non-active material and enabling effective ion conduction.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If discretely fabricated component layers are used in stacked or wound construction, then manufacturing is easier, but energy density and ion conductivity are limited

Engineering Contradiction:
Improveease of manufactureVSAvoidenergy density
Core Design Contradiction:
Ease of manufactureVSQuantity of substance

Solution Approach 1:

The patent merges multiple discrete component layers into a single integrated glassy embedded electrode assembly where the glassy medium simultaneously serves as electrolyte, separator, and binder, eliminating the need for separate discrete layers and achieving higher energy density while maintaining manufacturability

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent employs a composite material structure consisting of a glassy sulfide medium embedded with electroactive material particles, creating a unified composite electrode assembly that achieves both high energy density and effective ion conduction while simplifying manufacturing processes

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If more non-active material is used in discrete layer construction, then structural stability is improved, but energy density decreases

Engineering Contradiction:
Improvestructural stabilityVSAvoidenergy density
Core Design Contradiction:
Stability of the object's compositionVSQuantity of substance

Solution Approach 1:

The glassy medium performs multiple functions simultaneously: it acts as electrolyte for ion conduction, separator for electrode isolation, binder for particle cohesion, and protective coating for stability, thereby achieving structural stability without requiring additional non-active materials that would reduce energy density

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The glassy medium is locally optimized to provide different properties in different regions: it forms a continuous phase for ion conduction, creates porous structures for electroactive material dispersion, and provides stable interfaces for electrode separation, all within a single material system

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution supports high areal ampere-hour capacity, minimizes inactive material, and provides effective ion conduction, leading to enhanced power output, reduced charging time, and improved cycle life in solid-state battery cells.

Implementation Method 1

a continuous glassy medium including a Li ion conducting sulfide glass

Methodology Applied
Scientific EffectIon conduction: Conduction (electrical)

Implementation Method 2

the glassy cover region is substantially devoid of crystalline particles (i.e., crystallites) that are not suitably conductive to Li ions

Methodology Applied
Scientific EffectChemical stability:

Data Source

PatentUS20230134479A1Glassy solid-state electrodes and methods of making glassy solid-state electrodes and battery cells thereof
Publication Date: 2023.05.04 POLYPLUS BATTERY CO INC
  • US20230134479A1 patent drawing
  • US20230134479A1 patent drawing
  • US20230134479A1 patent drawing

AI summary

Batteries, component structures and manufacturing methods, in particular including a glassy embedded battery electrode assembly having a composite material structure composed of interpenetrating material components including a porous electroactive network including a solid electroactive material, and a continuous glassy medium including a Li ion conducting sulfide glass, can achieve enhanced power output, reduced charging time and/or improved cycle life.