Glazing Functional Coating Silver Niobium Thermal Resistance

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Solution Overview

Problem

Current glazing materials with silver-based functional layers are sensitive to humidity and not suitable for single glazing due to mechanical and chemical resistance issues, while niobium-based layers offer better resistance but inadequate optical properties and high emissivity, necessitating a compromise between thermal, optical, and mechanical performance.

Innovation Solution

A transparent substrate coated with a stack of thin layers comprising a silver-based functional layer and niobium-based layers, separated by blocking layers, where the sum of the niobium layer thicknesses in contact or separated by blocking layers is between 4 and 20 nm, achieving improved thermal insulation and light transmission without degrading after heat treatments.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If a silver-based functional layer is used, then thermal insulation performance is improved, but mechanical and chemical resistance deteriorates

Engineering Contradiction:
Improvethermal insulationVSAvoidmechanical and chemical resistance
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The patent uses a composite functional coating combining silver-based layers (for thermal insulation) with niobium-based layers (for mechanical and chemical resistance). The silver layer provides low emissivity and high thermal insulation performance, while the niobium layer adds durability and resistance to degradation, creating a synergistic composite structure that resolves the contradiction between thermal performance and reliability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The functional coating is designed to perform multiple functions simultaneously: the silver-based layer provides thermal insulation and low emissivity, while the niobium-based layer provides mechanical strength and chemical resistance. This multi-functional design allows a single coating system to address both thermal performance and reliability requirements without requiring separate systems.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Reliability

If a niobium-based functional layer is used, then mechanical and chemical resistance is improved, but optical properties and thermal insulation performance deteriorate

Engineering Contradiction:
Improvemechanical and chemical resistanceVSAvoidthermal insulation
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent combines niobium-based layers with silver-based layers in a composite functional coating. The niobium layer provides the necessary mechanical and chemical resistance, while the silver layer compensates for the insufficient thermal insulation performance of niobium alone. The composite structure allows both materials to contribute their strengths, resolving the contradiction between reliability and thermal performance.

Inventive Principle:
Principle #40Composite materials

3Loss of energy

If the thickness of functional layers is increased, then thermal insulation performance is improved, but light transmission deteriorates

Engineering Contradiction:
Improvethermal insulationVSAvoidlight transmission
Core Design Contradiction:
Loss of energyVSIllumination intensity

Solution Approach 1:

The patent optimizes the thickness parameters of the functional layers to achieve the desired balance. By carefully controlling the thickness of silver-based and niobium-based layers within specific ranges, the coating achieves sufficient thermal insulation performance while maintaining acceptable light transmission. This parameter optimization resolves the contradiction by finding the optimal thickness values that satisfy both requirements.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a high light transmission of over 50% with a low emissivity of less than 35%, maintaining stability and optical properties before and after heat treatments, while enhancing mechanical and chemical resistance, making it suitable for single glazing applications.

Implementation Method 1

by reflecting infrared, thermal or solar radiation, they give the material low-emissivity or solar control functions

Methodology Applied
Scientific EffectReflection: Reflection

Implementation Method 2

acts on solar and/or thermal radiation essentially by reflection and/or absorption of near (solar) or far (thermal) infrared radiation

Methodology Applied
Scientific EffectAbsorption (EM radiation): Absorption (EM radiation)

Data Source

PatentEP3347321B1Glazing comprising a functional coating
Publication Date: 2019.06.12 SAINT GOBAIN VITRAGE SA

AI summary

The invention concerns a material comprising a transparent substrate coated with a stack of thin layers including at least one functional coating comprising: - at least one metal functional layer made from silver, - at least one metal or nitrided functional layer made from niobium.