GLDA-Enhanced Antimicrobial Cleaning Agents

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Solution Overview

Problem

Existing antimicrobially active washing and cleaning agents, particularly those containing biocidal quaternary ammonium compounds, exhibit poor activity against gram-negative bacteria and other microorganisms, especially at low temperatures and in moist environments, leading to inadequate sterilization of textiles and surfaces.

Innovation Solution

Incorporating tetracarboxylic acids or their salts, such as glutamic acid diacetic acid, into washing or cleaning agents enhances the antimicrobial activity of quaternary ammonium compounds, achieving a synergistic effect that rivals the hygiene performance of bleach-containing agents at higher temperatures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If quaternary ammonium compounds are used as antimicrobial agents in washing agents, then antimicrobial activity is provided, but the activity level is poor especially against gram-negative bacteria at low temperatures

Engineering Contradiction:
Improveantimicrobial activityVSAvoidsterilization effectiveness
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent changes the chemical parameters of the washing agent by introducing tetracarboxylic acids or their salts as synergistic components. This chemical parameter change enhances the antimicrobial activity of quaternary ammonium compounds, particularly against gram-negative bacteria, enabling effective sterilization at low temperatures without requiring high temperature washing processes.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite antimicrobial system by combining quaternary ammonium compounds with tetracarboxylic acids or their salts. This composite formulation produces a synergistic effect where the combination of substances achieves superior antimicrobial activity compared to the individual components, especially against difficult-to-eliminate gram-negative bacteria.

Inventive Principle:
Principle #40Composite materials

2Strength

If washing temperature is reduced to 30 or 40°C to protect delicate textiles, then textile damage is prevented, but microorganisms are not safely killed off

Engineering Contradiction:
Improvetextile integrityVSAvoidmicrobial elimination
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the washing agent by incorporating tetracarboxylic acids or their salts, which enable effective microbial elimination at low temperatures. This allows the use of gentle washing temperatures (30-40°C) that protect delicate textiles while still achieving reliable microbial sterilization through the enhanced antimicrobial action of the modified detergent formulation.

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If liquid washing agents free of bleaching agents are used, then textile damage and odor problems are reduced, but antimicrobial activity is insufficient

Engineering Contradiction:
Improvetextile damage and odorsVSAvoidantimicrobial effectiveness
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent develops a composite antimicrobial system combining quaternary ammonium compounds with tetracarboxylic acids or their salts, creating a formulation that provides sufficient antimicrobial activity without requiring bleaching agents. This composite approach enables the use of gentle, bleach-free liquid washing agents that protect textiles from damage and prevent odor formation while maintaining effective microbial elimination.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The combination of tetracarboxylic acids or their salts with quaternary ammonium compounds in washing agents significantly improves antimicrobial efficacy, effectively reducing microorganisms on textiles and hard surfaces even at low temperatures, comparable to bleach-containing agents at higher temperatures.

Implementation Method 1

Surprisingly, it has been shown that an improved antimicrobial effect of the quaternary ammonium compounds can be achieved by means of tetracarboxylic acids or salts thereof, although tetracarboxylic acids or salts thereof are not antimicrobially active themselves. Surprisingly, a synergistic effect has been found between the quaternary ammonium compounds and tetracarboxylic acids or salts thereof.

Methodology Applied
Scientific EffectSynergistic effect:

Data Source

PatentUS10487291B2Detergent or cleaning agent having GLDA-enhanced antimicrobial effect
Publication Date: 2019.11.26 HENKEL KGAA
  • US10487291B2 patent drawing
  • US10487291B2 patent drawing
  • US10487291B2 patent drawing

AI summary

A detergent or cleaning agent that has an antimicrobial effect and includes at least one tetracarboxylic acid or the salts thereof in combination with at least one biocidal quaternary ammonium compound.