Glow Plug Heating Coil Grain Boundary Diffusion Barrier

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Solution Overview

Problem

In glow plugs with heating coils made of tungsten or molybdenum, metal diffusion from the sheath tube into the heating coil can lead to reduced melting points, grain boundary embrittlement, and decreased durability due to excessive temperature increases, causing potential disconnection.

Innovation Solution

Incorporating additional elements like potassium, aluminum, silicon, lanthanum, thorium, and cerium at the crystal grain boundaries of the heating coil, along with a sheath tube made of nickel or iron, to inhibit metal diffusion and maintain the melting point of the heating coil, and using an insulator to prevent excessive adhesion and thermal stress.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the heating coil is made of tungsten or molybdenum to increase the melting point, then the durability is improved, but metal diffusion from the sheath tube into the heating coil causes grain boundary embrittlement and local melting point reduction

Engineering Contradiction:
ImprovedurabilityVSAvoidcomposition stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

A coating layer is applied to the heating coil as an intermediary barrier between the sheath tube and the heating coil. This coating prevents direct contact and diffusion between the nickel or iron from the sheath tube and the tungsten or molybdenum heating coil, thereby maintaining compositional stability while allowing the high-melting-point material to provide durability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The heating coil is constructed as a composite structure with a core material (tungsten or molybdenum) and an outer coating layer. This composite approach allows the inner core to provide high-temperature durability while the outer coating prevents harmful diffusion from the sheath tube, resolving the contradiction between reliability and compositional stability.

Inventive Principle:
Principle #40Composite materials

2Temperature

If the heating coil is made of tungsten or molybdenum to resist high temperatures, then the heat resistance is improved, but metal diffusion leads to local melting point reduction to below 1500°C

Engineering Contradiction:
Improveheat resistanceVSAvoidmetal diffusion
Core Design Contradiction:
TemperatureVSObject-affected harmful factors

Solution Approach 1:

The coating layer serves as a protective intermediary that blocks the diffusion path of nickel or iron atoms from the sheath tube to the heating coil. This prevents the formation of low-melting-point eutectic structures at the interface, maintaining the high heat resistance of the tungsten or molybdenum core even during prolonged high-temperature operation.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The heating coil is designed with non-uniform composition: the inner core maintains pure tungsten or molybdenum for high heat resistance, while the outer surface has a protective coating layer. This local differentiation allows the bulk material to provide heat resistance while the surface layer prevents harmful diffusion.

Inventive Principle:
Principle #3Local quality

3Power

If the heating coil operates at high temperatures to provide heating function, then the heating performance is improved, but grain boundary embrittlement increases leading to disconnection

Engineering Contradiction:
Improveheating performanceVSAvoidstrength
Core Design Contradiction:
PowerVSStrength

Solution Approach 1:

The coating layer acts as a protective barrier that prevents metal diffusion during high-temperature operation. By blocking the diffusion of sheath tube metal into the heating coil, it prevents grain boundary embrittlement that would otherwise occur during prolonged heating cycles, thereby maintaining strength while allowing high heating performance.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The coating layer is applied beforehand to the heating coil to provide protective cushioning against future diffusion damage. This preventive measure ensures that even during extended high-temperature heating operations, the heating coil remains protected from embrittlement and maintains its mechanical strength.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the durability of the glow plug by preventing metal diffusion and grain boundary embrittlement, ensuring the heating coil remains connected and functional under high temperatures, thereby improving the overall performance and longevity of the glow plug.

Implementation Method 1

a heating coil that is located in the sheath tube and that generates heat as a result of transmission of electricity

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Implementation Method 2

the diffusion of the metal of which the sheath tube is composed into the heating coil progresses mainly at a crystal grain boundary of the metal of which the heating coil is composed

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentEP3260779B1Glow plug
Publication Date: 2019.11.27 NITERRA CO LTD
  • EP3260779B1 patent drawingFigure 1
  • EP3260779B1 patent drawingFigure 2
  • EP3260779B1 patent drawingFigure 3

AI summary

[Object] To inhibit a metal of which a sheath tube is composed from diffusing into a heating coil. [Solution] A heater (800) included in a glow plug (10) includes a sheath tube (810) and a heating coil (820). The heating coil contains at least one selected from tungsten (W) and molybdenum (Mo) as a main component and contains at least one additional element selected from potassium (K), aluminum (Al), silicon (Si), lanthanum (La), thorium (Th), and cerium (Ce). The sheath tube contains at least one metal selected from nickel (Ni) and iron (Fe). A melt portion (816) that is in contact with an outer surface of a front-end portion of the heating coil is formed at a front-end portion of the sheath tube. The additional element exists at a crystal grain boundary of the main component at least in a surface layer (825) of the front-end portion of the heating coil.