Ethylene Glycol Dehydration Using Two-Stage Steam-Integrated Distillation

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Solution Overview

Problem

There is an ongoing need in the field of ethylene glycol manufacturing for improving the energy efficiency of the ethylene oxide and ethylene glycol process steps, particularly in reducing the import of external steam.

Innovation Solution

A two-step glycol dehydration process is implemented, involving a pre-dehydration step in a distillation column at low overhead pressure followed by a vacuum dehydration step, utilizing low-pressure steam generated from the first dehydrator to drive low-pressure steam consumers and integrate with the ethylene oxide section, reducing the need for external steam.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If a conventional single vacuum distillation step is used for glycol dehydration, then the dehydration process is simple, but external steam import is high and energy efficiency is low

Engineering Contradiction:
Improveenergy efficiencyVSAvoiddehydration process complexity
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The dehydration process is divided into two distinct steps: (1) pre-dehydration in a distillation column operating at low overhead pressure (0.3-3 barg) to remove free water, and (2) final dehydration under vacuum to achieve the required water content specification. This segmentation allows each step to operate under optimized conditions, with the first step producing usable low-pressure steam and the second step achieving complete dehydration, thereby improving overall energy efficiency while managing process complexity through systematic division of functions.

Inventive Principle:
Principle #1Segmentation

2Productivity

If multiple effect evaporators are used for water removal, then water is efficiently removed and returned to reactor, but the process requires significant external steam input

Engineering Contradiction:
Improvewater removal efficiencyVSAvoidexternal steam import
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The system generates its own low-pressure steam through the first dehydration column, which then serves multiple purposes: providing heat input to the multiple effect evaporators for water removal, supplying steam to steam consumers in both ethylene oxide and ethylene glycol sections, and enabling chilling operations. This self-service approach eliminates or reduces the need for external steam import while maintaining high water removal efficiency through the multiple effect evaporator system.

Inventive Principle:
Principle #25Self-service

3Loss of energy

If low-pressure steam is generated and utilized throughout the process, then external steam import is reduced, but process integration complexity increases

Engineering Contradiction:
Improveexternal steam importVSAvoidprocess integration complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The low-pressure steam generated in the first dehydration column serves multiple functions across different process sections: it provides heat input to multiple effect evaporators, supplies steam to various steam consumers in both ethylene oxide and ethylene glycol sections, and enables chilling operations through steam condensation. This multi-functional use of a single steam source maximizes energy utilization and reduces external steam requirements while managing integration complexity through systematic heat exchanger network design.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process achieves increased energy efficiency and reduced process costs by effectively utilizing low-pressure steam for various process steps, including chilling, thereby minimizing external steam import and optimizing heat integration.

Implementation Method 1

subjecting said aqueous stream comprising ethylene glycol to an evaporation step in a multiple-effect evaporator

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

subjecting said concentrated stream comprising ethylene glycol to a first dehydration step in a first dehydrator which is a distillation column

Methodology Applied
Scientific EffectDistillation: Distillation

Implementation Method 3

subjecting said partially dehydrated ethylene glycol stream to a second dehydration step in a second dehydrator operating under vacuum

Methodology Applied
Scientific EffectVacuum distillation: Vacuum Distillation

Implementation Method 4

the vaporous overhead from the last evaporator vessel in the multiple-effect evaporator is used as process steam, and wherein at least a portion of said process steam is used to provide heat to the first dehydrator

Methodology Applied
Scientific EffectCondensation: Condensation

Data Source

PatentEP3713905B2Processes for the production of ethylene oxide and ethylene glycol
Publication Date: 2026.02.11 SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ BV
  • EP3713905B2 patent drawingFigure 1
  • EP3713905B2 patent drawingFigure 2
  • EP3713905B2 patent drawingFigure 3

AI summary

A process for the recovery of ethylene glycol from an aqueous stream comprising ethylene glycol is disclosed. The process comprises (a) subjecting an aqueous stream 5 comprising ethylene glycol to an evaporation step in a multiple-effect evaporator to obtain a concentrated stream comprising ethylene glycol; (b)subjecting said concentrated stream comprising ethylene glycol to a first dehydration step in a first dehydrator 10 operating at an overhead pressure in the range of 0 barg (bar gauge) to 4 barg (bar gauge) to obtain a partially dehydrated ethylene glycol stream, and (c)subjecting said partially dehydrated ethylene glycol stream to a second dehydration step in a second dehydrator operating under 15 vacuum to obtain a dehydrated ethylene glycol stream.