Organometallic Gold OLED Emitter for Saturated Color Purity

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Solution Overview

Problem

Current organic light-emitting diode (OLED) technologies face challenges in achieving saturated color emission, particularly for red, green, and blue pixels, which are essential for full-color displays, as existing materials do not efficiently produce these colors with high purity and efficiency.

Innovation Solution

The development of an organometallic compound represented by Formula I, which includes specific monocyclic or polycyclic ring systems, substitution patterns, and ligands, is used in an OLED structure to enhance color emission properties, allowing for improved color purity and efficiency in OLED devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional organic materials are used in OLEDs, then the device structure can be simplified and manufacturing can be easier, but the color emission purity and saturation are insufficient

Engineering Contradiction:
Improvecolor emission purityVSAvoiddevice structure complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent changes the chemical composition parameters by introducing organometallic compounds with specific metal centers (Ir, Pt, Au) and tailored ligand structures. This enables precise control over emission wavelengths and color purity, achieving saturated red, green, and blue emissions that conventional organic materials cannot provide

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite organometallic compounds combining metal centers with organic ligands featuring specific ring systems (carbazole, triazole, pyridine) and substituent groups. This composite structure leverages both the optical properties of metal complexes and the tunability of organic moieties to achieve high color purity emission

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional organic materials are used, then material cost can be reduced, but emission efficiency and color saturation cannot be achieved

Engineering Contradiction:
Improveemission efficiencyVSAvoidmaterial cost
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent optimizes key parameters including metal center selection (Ir for phosphorescence, Pt for triplet state utilization), ligand field strength, and HOMO-LUMO energy gap to maximize emission efficiency. The specific molecular design enables high quantum yield and saturated color emission that conventional materials cannot achieve

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If white OLED with absorption filters is used, then device structure can be simplified, but color emission purity and saturation are lost

Engineering Contradiction:
Improvecolor emission saturationVSAvoidemissive layer structure
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent divides the white OLED approach into separate emissive components by designing distinct organometallic compounds for red, green, and blue emission. Each compound is optimized for its specific wavelength range, eliminating the need for absorption filters and achieving direct saturated color emission from each pixel type

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent adjusts molecular parameters including ligand substitution patterns, ring system size, and metal center selection to precisely control emission wavelengths. This enables direct emission of saturated colors from the emissive layer without requiring post-emission color filtering

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the organometallic compound in OLEDs results in enhanced color emission characteristics, achieving better color purity and efficiency, particularly in red, green, and blue emissions, suitable for high-performance full-color displays.

Implementation Method 1

OLEDs make use of thin organic films that emit light when voltage is applied across the device

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20240373742A1Organic electroluminescent materials and devices
Publication Date: 2024.11.07 UNIVERSAL DISPLAY CORP
  • US20240373742A1 patent drawing
  • US20240373742A1 patent drawing
  • US20240373742A1 patent drawing

AI summary

Provided are organometallic compounds containing a gold atom as the central metal atom which is coordinated by a tetradentate ligand comprising at least four monocyclic or fused polycyclic ring system as described herein. Also provided are formulations comprising these organometallic compounds. Further provided are organic light emitting devices (OLEDs) and related consumer products that utilize these organometallic compounds.