Gold Silver Nanoparticle Adsorbent for Pesticide Removal

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Solution Overview

Problem

Most water bodies are contaminated with organo-halogen and organo-sulphur pesticides, posing a significant financial burden and lacking effective systems for removing these contaminants, especially in developing countries, making pesticide-free drinking water inaccessible.

Innovation Solution

An adsorbent composition of silver and gold nanoparticles supported on activated alumina and magnesia, combined with activated carbon, is used to effectively remove common pesticides like chlorpyrifos and malathion from water, integrated into a device for on-line water decontamination.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If bare metal nanoparticles (silver, gold, iron, palladium) are used to degrade pesticides, then pesticide removal efficiency is improved, but the system complexity and cost increase

Engineering Contradiction:
Improvepesticide removal efficiencyVSAvoidsystem complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent uses composite materials by combining bare metal nanoparticles (silver, gold, iron, palladium) with porous substrates (alumina, silica, activated carbon). This composite structure maintains the high catalytic activity of the metal nanoparticles for pesticide degradation while using the porous substrate to provide mechanical support, increase surface area, and facilitate easy separation and system integration, thus reducing overall system complexity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The porous substrate acts as an intermediary carrier that supports the metal nanoparticles. This intermediary structure allows the nanoparticles to maintain their catalytic function while being easily separated from the water stream through filtration mechanisms, simplifying system operation and reducing complexity compared to using nanoparticles alone.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If nanoscale iron particles and palladized iron nanoparticles are used to degrade halogenated organic pollutants, then pesticide degradation capability is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvepesticide degradation capabilityVSAvoidmanufacturing complexity
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent employs inexpensive metal nanoparticles (particularly iron and palladium on carbon) that can be easily manufactured and replaced. These nanoparticles serve as effective catalysts for degrading halogenated organic pollutants and can be regenerated or replaced at low cost, simplifying the manufacturing process compared to using precious metals alone.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent modifies the physical and chemical parameters of iron particles by creating nanoscale structures and combining them with carbon supports. This parameter change (reducing size to nanoscale and adding carbon coating) dramatically improves the degradation capability of halogenated organics while maintaining ease of manufacture through standard nanoparticle synthesis methods.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If activated carbon powder and carbon block are used to remove sediments and pesticides, then pesticide removal is achieved, but adsorption capacity for diverse pesticides is limited

Engineering Contradiction:
Improvepesticide removalVSAvoidadsorption capacity for diverse pesticides
Core Design Contradiction:
ProductivityVSAdaptability or versatility

Solution Approach 1:

The patent creates composite materials by combining carbon-based adsorbents (activated carbon, carbon blocks) with metal nanoparticles (silver, gold, iron, palladium). This composite structure leverages the high adsorption capacity of carbon materials for diverse pesticides while the metal nanoparticles provide catalytic degradation pathways, together achieving both effective removal and broad adaptability across different pesticide types.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The composite system achieves universality by combining materials with different functions: carbon materials provide general adsorption for diverse pesticides, while metal nanoparticles provide catalytic degradation for various chemical structures. This multi-functional approach enables the system to effectively handle a wide range of pesticide contaminants that would be difficult to address with a single material type.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves efficient and sustained removal of chlorpyrifos and malathion from water, maintaining high efficiency over three months with minimal reduction, providing a cost-effective and widely applicable method for producing safe drinking water.

Implementation Method 1

allowing contaminated water to flow through a bed of silver/gold nanoparticles supported on activated alumina and/or magnesia or a combination of these materials with activated carbon to adsorb pesticides like chlorpyrifos, malathion or other organo halogen/sulphur pesticides

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

silver and gold nanoparticles supported on activated alumina and magnesia

Methodology Applied
Scientific EffectPhysical adsorption: Adsorption

Data Source

PatentUS7968493B2Method for the preparation of adsorption compositions including gold or silver nanoparticles
Publication Date: 2011.06.28 AQUAMALL WATER SOLUTIONS
  • US7968493B2 patent drawing
  • US7968493B2 patent drawing
  • US7968493B2 patent drawing

AI summary

This invention relates to novel adsorbent compositions for adsorbing pesticides like chlorpyrifos and malathion. This composition consists of nanoparticles of gold/silver supported on activated alumina or magnesia in powder or other forms. This invention includes a device and a method for decontaminating water contaminated with pesticides. This device consists of a housing provided with an inlet and an outlet. The housing is loaded with nanoparticles of gold/silver supported on activated magnesia. Contaminated water is allowed to pass through the housing while pesticides are adsorbed by the composition. Decontaminated water flows out through the outlet.