Gold Silver Nanoparticle Adsorbent for Pesticide Removal
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Solution Overview
Problem
Most water bodies are contaminated with organo-halogen and organo-sulphur pesticides, posing a significant financial burden and lacking effective systems for removing these contaminants, especially in developing countries, making pesticide-free drinking water inaccessible.
Innovation Solution
An adsorbent composition of silver and gold nanoparticles supported on activated alumina and magnesia, combined with activated carbon, is used to effectively remove common pesticides like chlorpyrifos and malathion from water, integrated into a device for on-line water decontamination.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Productivity
If bare metal nanoparticles (silver, gold, iron, palladium) are used to degrade pesticides, then pesticide removal efficiency is improved, but the system complexity and cost increase
Solution Approach 1:
The patent uses composite materials by combining bare metal nanoparticles (silver, gold, iron, palladium) with porous substrates (alumina, silica, activated carbon). This composite structure maintains the high catalytic activity of the metal nanoparticles for pesticide degradation while using the porous substrate to provide mechanical support, increase surface area, and facilitate easy separation and system integration, thus reducing overall system complexity.
Solution Approach 2:
The porous substrate acts as an intermediary carrier that supports the metal nanoparticles. This intermediary structure allows the nanoparticles to maintain their catalytic function while being easily separated from the water stream through filtration mechanisms, simplifying system operation and reducing complexity compared to using nanoparticles alone.
2Productivity
If nanoscale iron particles and palladized iron nanoparticles are used to degrade halogenated organic pollutants, then pesticide degradation capability is improved, but manufacturing complexity increases
Solution Approach 1:
The patent employs inexpensive metal nanoparticles (particularly iron and palladium on carbon) that can be easily manufactured and replaced. These nanoparticles serve as effective catalysts for degrading halogenated organic pollutants and can be regenerated or replaced at low cost, simplifying the manufacturing process compared to using precious metals alone.
Solution Approach 2:
The patent modifies the physical and chemical parameters of iron particles by creating nanoscale structures and combining them with carbon supports. This parameter change (reducing size to nanoscale and adding carbon coating) dramatically improves the degradation capability of halogenated organics while maintaining ease of manufacture through standard nanoparticle synthesis methods.
3Productivity
If activated carbon powder and carbon block are used to remove sediments and pesticides, then pesticide removal is achieved, but adsorption capacity for diverse pesticides is limited
Solution Approach 1:
The patent creates composite materials by combining carbon-based adsorbents (activated carbon, carbon blocks) with metal nanoparticles (silver, gold, iron, palladium). This composite structure leverages the high adsorption capacity of carbon materials for diverse pesticides while the metal nanoparticles provide catalytic degradation pathways, together achieving both effective removal and broad adaptability across different pesticide types.
Solution Approach 2:
The composite system achieves universality by combining materials with different functions: carbon materials provide general adsorption for diverse pesticides, while metal nanoparticles provide catalytic degradation for various chemical structures. This multi-functional approach enables the system to effectively handle a wide range of pesticide contaminants that would be difficult to address with a single material type.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The solution achieves efficient and sustained removal of chlorpyrifos and malathion from water, maintaining high efficiency over three months with minimal reduction, providing a cost-effective and widely applicable method for producing safe drinking water.
Implementation Method 1
allowing contaminated water to flow through a bed of silver/gold nanoparticles supported on activated alumina and/or magnesia or a combination of these materials with activated carbon to adsorb pesticides like chlorpyrifos, malathion or other organo halogen/sulphur pesticides
Implementation Method 2
silver and gold nanoparticles supported on activated alumina and magnesia
Data Source
AI summary
This invention relates to novel adsorbent compositions for adsorbing pesticides like chlorpyrifos and malathion. This composition consists of nanoparticles of gold/silver supported on activated alumina or magnesia in powder or other forms. This invention includes a device and a method for decontaminating water contaminated with pesticides. This device consists of a housing provided with an inlet and an outlet. The housing is loaded with nanoparticles of gold/silver supported on activated magnesia. Contaminated water is allowed to pass through the housing while pesticides are adsorbed by the composition. Decontaminated water flows out through the outlet.


