Golf Ball Composition Using Ionomer and Polyethylene Blend

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Solution Overview

Problem

Current golf ball compositions primarily using ionomer resins face limitations in achieving further improvements in resilience and durability while maintaining initial velocity and softness.

Innovation Solution

A golf ball composition comprising an ionomer resin blend of olefin-unsaturated carboxylic acid random copolymers, polyethylene, and an organic peroxide, with specific melt flow rates and compounding ratios, which suppresses ion cluster formation and enhances compatibility between ionomer and polyethylene, thereby improving rebound and durability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If ionomer resins are used as the primary base resin in golf ball cover materials, then durability and scuff resistance are improved, but resilience and rebound properties are compromised

Engineering Contradiction:
ImprovedurabilityVSAvoidresilience
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent employs a composite material system combining ionomer resin with specific elastomers (polybutadiene or styrene-butadiene rubber) and polyethylene. This composite approach allows the golf ball cover to simultaneously achieve the durability and scuff resistance of ionomer resins while incorporating the resilience and rebound properties of elastomers, thereby resolving the technical contradiction between durability and resilience

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent utilizes peroxide-induced crosslinking to modify the physical and chemical parameters of the ionomer resin matrix. By controlling the crosslinking degree through peroxide content and processing conditions, the material achieves enhanced durability and heat resistance while maintaining adequate resilience through the elastomeric phase

Inventive Principle:
Principle #35Parameter changes

2Strength

If thermoplastic resins or thermoplastic elastomers are mixed into ionomer materials to improve moldability and resilience, then resilience and moldability are improved, but durability and scuff resistance deteriorate

Engineering Contradiction:
ImproveresilienceVSAvoidscuff resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent creates a multi-phase composite where ionomer resin forms the continuous matrix providing scuff resistance and durability, while dispersed elastomer particles provide resilience. The specific composition ranges (5-30 parts elastomer per 100 parts ionomer) are optimized to balance these competing properties, with the peroxide crosslinking further enhancing the ionomer matrix's protective characteristics

Inventive Principle:
Principle #40Composite materials

3Strength

If the compounding ratio of polyethylene to ionomer is increased to improve compatibility and suppress ion cluster formation, then resilience is improved, but durability may be compromised

Engineering Contradiction:
ImproveresilienceVSAvoiddurability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent optimizes the polyethylene content within specific ranges (3-20 parts per 100 parts ionomer) and controls the molecular weight distribution and melt flow characteristics of polyethylene to achieve optimal compatibility. This parameter optimization ensures sufficient resin compatibility and ion cluster suppression while maintaining the ionomer matrix's protective properties through controlled crosslinking

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition significantly increases durability and resilience of golf balls without compromising initial velocity, providing enhanced performance in terms of scuff resistance and crack resistance.

Implementation Method 1

compounding: (A) one or more ionomer selected from the group consisting of an olefin-unsaturated carboxylic acid random copolymer and/or an olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester random copolymer, and a metal ion neutralization product of an olefin-unsaturated carboxylic acid random copolymer and/or a metal ion neutralization product of an olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester random copolymer; (B) a polyethylene; and (C) an organic peroxide

Methodology Applied
Scientific EffectPeroxide crosslinking: Chemical Bonding

Data Source

PatentUS9095747B2Golf ball composition and golf ball
Publication Date: 2015.08.04 BRIDGESTONE SPORTS CO LTD

AI summary

The invention provides a golf ball composition containing an ionomer resin composition of: (A) one or more ionomer selected from the group consisting of an olefin-unsaturated carboxylic acid random copolymer and/or an olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester random copolymer, and a metal ion neutralization product of an olefin-unsaturated carboxylic acid random copolymer and/or a metal ion neutralization product of an olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester random copolymer; (B) a polyethylene; and (C) an organic peroxide.