Graded Doping in OLED Hole Injection Layers for Crosstalk Control

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Solution Overview

Problem

Existing organic light emitting devices suffer from high voltage, low luminous efficiency, and instability due to poor charge transport characteristics and excessive doping material concentrations leading to crosstalk issues.

Innovation Solution

The organic light emitting device incorporates a hole injection layer with a graded doping concentration of a first doping material, decreasing away from the anode, and a hole transport layer with a graded doping concentration of a second doping material, both with doping ratios less than or equal to 6%, to improve charge transport and reduce power consumption, luminous efficiency, and alleviate crosstalk.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a uniform high doping concentration is used in the hole injection layer, then charge injection capability is improved, but crosstalk between adjacent pixels increases and luminous efficiency decreases

Engineering Contradiction:
Improvecharge injection capabilityVSAvoidcrosstalk
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies local quality by implementing a graded doping concentration profile in the hole injection layer, where the doping concentration varies continuously from the anode interface into the layer. This creates different local properties: high doping concentration near the anode for effective charge injection, and progressively lower concentration toward the organic light emitting layer to minimize crosstalk. The doping concentration is specifically designed to be 1-10 times higher at the anode interface than at the organic light emitting layer interface.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent changes the doping concentration parameter spatially within the hole injection layer, transitioning from uniform doping to non-uniform graded doping. The doping concentration is controlled to decrease continuously from the anode side, creating an optimal balance between charge injection capability and crosstalk suppression. This parameter change enables the layer to perform multiple functions simultaneously.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If a uniform high doping concentration is used in the hole injection layer, then charge transport is improved, but power consumption increases and luminous efficiency decreases

Engineering Contradiction:
Improvecharge transportVSAvoidpower consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The graded doping concentration profile creates local quality variations that optimize charge transport while reducing power consumption. The higher doping concentration near the anode ensures efficient charge injection and initial transport, while the progressively lower concentration reduces unnecessary energy consumption in regions where high doping is not needed, thereby improving overall luminous efficiency.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

By changing the doping concentration parameter from uniform to graded distribution, the patent optimizes the balance between charge transport capability and power consumption. The continuous decrease in doping concentration creates an energy-efficient charge transport pathway that maintains sufficient charge mobility while minimizing excess energy consumption associated with uniformly high doping.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If the doping ratio is increased to improve charge transport, then charge injection is enhanced, but crosstalk between adjacent pixels worsens

Engineering Contradiction:
Improvecharge injectionVSAvoidcrosstalk
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent implements local quality by creating spatially varying doping concentrations within the hole injection layer. The doping ratio is locally optimized to be high (1-10 times higher) near the anode interface for effective charge injection, while progressively decreasing toward the organic light emitting layer interface to suppress crosstalk. This local optimization allows the layer to achieve both charge injection enhancement and crosstalk reduction.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent changes the doping ratio parameter from a uniform value to a graded distribution that continuously decreases from the anode side. This parameter change enables the hole injection layer to maintain high doping ratio (optimal for charge injection) at the anode interface while reducing the doping ratio (minimizing crosstalk) at the organic light emitting layer interface, thus resolving the contradiction between charge injection enhancement and crosstalk suppression.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enhances charge transport characteristics, reduces power consumption, improves luminous efficiency and stability, and alleviates crosstalk, resulting in a more efficient and stable organic light emitting device.

Implementation Method 1

the hole injection layer includes a first host material and a first doping material doped in the first host material, a doping concentration of the first doping material gradually decreases in a direction away from the anode

Methodology Applied
Scientific EffectDoping: Dopants

Implementation Method 2

the hole transport layer may include a second host material and a second doping material doped in the second host material, a doping concentration of the second doping material may gradually decrease in the direction away from the anode

Methodology Applied
Scientific EffectDoping: Dopants

Data Source

PatentUS20250270686A1Method for preparing organic light emitting device, preparation system, storage medium and computer equipment
Publication Date: 2025.08.28 BOE TECHNOLOGY GROUP CO LTD
  • US20250270686A1 patent drawing
  • US20250270686A1 patent drawing
  • US20250270686A1 patent drawing

AI summary

The present disclosure relates to a method for preparing an organic light emitting device, a preparation system, a storage medium and a computer equipment. The method includes: forming a hole injection layer, a hole transport layer, an electron blocking layer, an organic light emitting layer, a hole blocking layer, an electron transport layer, and an electron injection layer, which are sequentially arranged in a stack on an anode of the organic light emitting device, wherein the hole injection layer comprises a first host material and a first doping material doped in the first host material, a doping concentration of the first doping material gradually decreases in a direction away from the anode, and a doping ratio of the first doping material in the hole injection layer is less than or equal to 6%.