Gradient PDC Cutter Structure for Thermal Stress Relief

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Solution Overview

Problem

Polycrystalline diamond compact (PDC) cutters used in earth-boring drill bits face thermal stress issues due to coefficient of thermal expansion (CTE) mismatch between polycrystalline diamond and tungsten carbide substrates, leading to potential failure and reduced service lifetime.

Innovation Solution

Induced material segregation methods are employed to create a smooth compositional gradient in PDC cutters, using a solid-phase or fluid-phase binder to segregate polycrystalline diamond and tungsten carbide particulates, resulting in a unitary part with reduced CTE mismatch and localized stress concentrations, which is then sintered using a high-temperature high-pressure process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a PDC cutter is formed from polycrystalline diamond and tungsten carbide substrate with sintering aid, then the diamond-diamond bonds are formed during HTHP process, but the CTE mismatch among different material phases generates undesirably large stresses during temperature cycles

Engineering Contradiction:
Improvediamond-diamond bondsVSAvoidthermal stress
Core Design Contradiction:
StrengthVSStress or pressure

Solution Approach 1:

The patent applies local quality by creating a non-uniform distribution of materials within the PDC cutter. Specifically, it forms a gradient structure where the composition varies from the diamond table through the intermediate layer to the WC substrate, with each region having optimized material properties for its specific location, thereby reducing thermal stress while maintaining bond strength

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses composite materials by combining polycrystalline diamond, tungsten carbide, and sintering aid in a multi-layer gradient structure. This composite approach allows each material to contribute its beneficial properties while the gradient transition minimizes the harmful effects of CTE mismatch between the extreme materials

Inventive Principle:
Principle #40Composite materials

2Stress or pressure

If a leaching process is performed to remove residual cobalt or other sintering aid materials, then the undesirable effects of CTE mismatch are reduced, but the service lifetime may be adversely affected due to potential failure modes

Engineering Contradiction:
ImproveCTE mismatch stressVSAvoidservice lifetime
Core Design Contradiction:
Stress or pressureVSReliability

Solution Approach 1:

The patent applies preliminary action by pre-forming the gradient structure during the HTHP sintering process itself, rather than requiring a subsequent leaching step. The sintering aid is strategically positioned in the intermediate layer from the beginning, creating the stress-reducing gradient structure proactively before the cutter enters service

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses the sintering aid as an intermediary material positioned in the intermediate layer between the diamond table and WC substrate. This intermediary layer acts as a transition zone that mediates the thermal expansion mismatch between the two extreme materials, reducing stress without requiring removal of the catalyst

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enhances thermal stability and service lifetime of PDC cutters, leading to increased hydrocarbon production rates and reduced non-productive time for drilling equipment.

Implementation Method 1

subjecting the compacted material to a high-temperature high-pressure process to transform the carbon and the metal to a desired polymorph

Methodology Applied
Scientific EffectPhase transformation: Phase Change

Implementation Method 2

performing a high-temperature high-pressure (HTHP) sintering process on the green-state material to form the PDC cutter

Methodology Applied
Scientific EffectSintering: Sintering

Implementation Method 3

Induced material segregation methods are employed to create a smooth compositional gradient in PDC cutters, using a solid-phase or fluid-phase binder to segregate polycrystalline diamond and tungsten carbide particulates

Methodology Applied
Scientific EffectMaterial segregation:

Implementation Method 4

consolidating the segregated mixture to form a green-state material, including the binder immobilizing the polycrystalline diamond particulate and the substrate particulate in the green-state material

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 5

applying sintering process conditions to eliminate the binder during the HTHP sintering process

Methodology Applied
Scientific EffectDecomposition: Decomposition (biological)

Implementation Method 6

applying sintering process conditions to eliminate the binder during the HTHP sintering process

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS10920303B2Induced material segregation methods of manufacturing a polycrystalline diamond tool
Publication Date: 2021.02.16 HALLIBURTON ENERGY SERVICES INC
  • US10920303B2 patent drawing
  • US10920303B2 patent drawing
  • US10920303B2 patent drawing

AI summary

Induced material segregation methods of manufacturing a polycrystalline diamond compact (PDC) cutter result in formation of a polycrystalline diamond/tungsten carbide (WC) composite material having a smooth compositional gradient from maximum WC concentration at one face to maximum diamond concentration at another face. Because the compositional gradient is smooth, very little or no mismatch of coefficient of thermal expansion occurs, which improves a service lifetime of the PDC cutter.